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Composite material preparation method, battery positive electrode, battery and preparation method thereof

A composite material and cathode technology, which is applied in the field of batteries, can solve the problems of low specific energy of lithium-ion batteries, complex production process of cathode materials, and strict production conditions, and achieve the effects of simple manufacturing, improved cruising range, and low cost

Active Publication Date: 2021-02-26
ZHEJIANG GEELY HLDG GRP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The technical problem to be solved by the present invention is that the specific energy of the existing lithium-ion battery is low, the production process of the positive electrode material of the lithium-ion battery is complicated, and the production conditions are strict.

Method used

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  • Composite material preparation method, battery positive electrode, battery and preparation method thereof
  • Composite material preparation method, battery positive electrode, battery and preparation method thereof
  • Composite material preparation method, battery positive electrode, battery and preparation method thereof

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Effect test

Embodiment 1

[0043] Such as figure 1 Shown, a kind of lithium-rich-nickel-cobalt lithium manganese oxide composite material preparation method, described lithium-rich-nickel cobalt lithium manganate composite material preparation method, comprises the following steps:

[0044] The lithium-rich material accounting for 50% by mass and the nickel-cobalt-lithium manganese oxide material accounting for 50% by mass are mixed with a double planetary mixer, the speed of the double planetary mixer is 20r / min-60r / min, and the stirring time is 1h-3h ; Preferably, the speed of the double planetary mixer is set to 40r / min, and the stirring time is 2h.

[0045] The lithium-rich material and the nickel-cobalt-lithium-manganese-oxide material are dry-based materials. The direct mixing of dry-based materials saves the preparation of solution gel process steps, and at the same time can more accurately control the lithium content of the introduced materials, the process is simpler, and the material quality ...

Embodiment 2

[0057] combine figure 1 , a positive electrode of a lithium ion battery, the positive electrode of the battery comprises the following components in mass percentage: 95%-97% of lithium-rich-nickel-cobalt lithium manganese oxide, 0.5%-3% of a conductive agent and 1%-2% of a binder ;

[0058] Wherein, the lithium-rich-nickel-cobalt lithium manganese oxide is adopted such as figure 1 The preparation method of the lithium-rich-nickel-cobalt lithium manganese oxide composite material is shown.

[0059] Specifically, the conductive agent includes 0.5%-2% of Super-P and 0-1% of carbon nanotubes, and the binder is polyvinylidene fluoride.

[0060] A method for making a positive electrode of a lithium ion battery, comprising the following steps:

[0061] Weigh active material particles rich in lithium-nickel cobalt lithium manganate 95%, Super-P conductive agent 2%, carbon nanotube conductive agent 1% and binding agent polyvinylidene fluoride 2% by the mass percentage of each materi...

Embodiment 3

[0068] combine figure 1 , a lithium-ion battery, including a positive electrode and a negative electrode, the positive electrode of the battery includes the following components in mass percentage: 95-97% of lithium-rich-nickel-cobalt lithium manganese oxide, 0.5%-3% of conductive agent, and binder 1 %-2%;

[0069] Wherein, the lithium-rich-nickel-cobalt lithium manganate is adopted figure 1 The preparation method of the composite material is obtained.

[0070] Such as figure 2 and image 3 Shown, a kind of preparation method of lithium ion battery comprises the following steps:

[0071] Weigh 95% of active material particles rich in lithium-nickel cobalt lithium manganese oxide, 2% of Super-P conductive agent, 1% of carbon nanotube conductive agent and 2% of binder polyvinylidene fluoride according to the mass percentage of each substance; prepare positive electrode Slurry and make battery positive electrode sheet;

[0072] Weigh 62% of graphite, 30% of silicon carbon ...

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Abstract

The invention relates to the field of batteries, in particular to a method for preparing a composite material, a positive electrode of a battery, a battery and a preparation method thereof. The preparation method of the composite material, the positive electrode of the battery, the battery and the preparation method thereof comprise the following steps: mixing a lithium-rich material with a nickel-cobalt lithium manganese oxide material to obtain a mixture, wherein the lithium-rich material accounts for 50%-80% by mass , the mass of the nickel-cobalt lithium manganese oxide material accounts for 20%-50%; nitric acid is added to the mixture, heated and kept warm; citric acid is added and allowed to stand; dried; sintered in sections to obtain the lithium-rich-nickel Lithium cobalt manganate composite material. The present invention adopts the composite technology of lithium-rich material and nickel-cobalt-lithium manganese oxide material. After the two materials are composited, the advantages of the two materials are combined, and the manufactured power battery has high specific energy and good cycle life; the composite used in the present invention Material preparation method The preparation environment does not need to be very harsh, and the production is simpler.

Description

technical field [0001] The invention relates to the field of batteries, in particular to a method for preparing a composite material, a positive electrode of a battery, a battery and a preparation method thereof. Background technique [0002] Power lithium-ion battery is the heart of electric vehicles, and its development plays a key role in the performance of electric vehicles. my country's new energy vehicle industry is developing rapidly, but the cost and specific energy of power lithium-ion batteries have become a bottleneck restricting the promotion and popularization of new energy production capacity. [0003] At present, the power lithium-ion batteries commonly used in the field of passenger vehicles are mostly nickel-cobalt lithium manganese oxide power batteries or nickel-cobalt lithium aluminate power lithium battery products. Due to the high content of nickel and cobalt in this material, the material cost is relatively expensive, and the use cost is relatively hi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/36H01M4/505H01M4/525H01M4/1391H01M10/0525H01M10/058
CPCH01M4/1391H01M4/362H01M4/505H01M4/525H01M10/0525H01M10/058H01M2220/20Y02E60/10Y02P70/50
Inventor 许海涛刘夺张小兵田丰
Owner ZHEJIANG GEELY HLDG GRP CO LTD