Antifogging crosslinked thermal shrinkage film and preparation method thereof
A heat-shrinkable film and anti-fog technology, applied in other household appliances and other directions, can solve the problem of low light transmittance of packaging materials, achieve long-term anti-fog, reduce water vapor, and improve the effect of cross-linking
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[0026] The present invention proposes a preparation method of an anti-fog cross-linked heat-shrinkable film, comprising the following steps:
[0027] The outer layer, core layer and inner layer raw materials are mixed evenly, and then added to the extrusion equipment to melt, and after melting, the composite melt is obtained by co-extruding the layer;
[0028] The composite melt is inflated once, and the bubble after the first inflation is cooled and shaped to form a tube film;
[0029] The tube membrane is pulled to the electron irradiation cross-linking device, and the linear molecular chains of the tube membrane are cross-linked by electron irradiation;
[0030] Preheat the cross-linked tube film, after the preheating is completed, perform secondary inflation and simultaneous biaxial stretching to form a composite film;
[0031] The composite film is shaped after post-treatment, and the anti-fog cross-linked heat-shrinkable film is obtained by trimming and winding.
[003...
Embodiment 1
[0048] Outer material by weight percentage: 95% polyethylene, 4% silicone anti-blocking agent, 1% erucamide smooth agent, core material: 80% polyethylene, 5% erucamide slip agent Slip agent, 5% silicon-containing surfactant anti-fog agent, 5% N,N-methylenebisacrylamide crosslinking initiator and 5% nano-titanium dioxide slow-release agent, inner layer raw material: 93% poly Ethylene, 4% silicone anti-blocking agent, 1% erucamide slip agent and 2% anti-fogging and dripping agent were mixed evenly, and then added to the extrusion equipment to melt. The three heating zones of the extruder The temperature of the section is: feeding section 160°C, melting section 165°C, homogenizing section 180°C, the temperature of the four heating sections of the co-extrusion die is 185°C, the lip gap of the co-extrusion die is 1.5mm, Finally, the composite melt is obtained by co-extruding the layer;
[0049] The composite melt is inflated once, and the bubble after the first inflation is cooled...
Embodiment 2
[0054] Outer material by weight percentage: 90% polyethylene, 3% silicone anti-blocking agent, 7% erucamide slip agent, core layer material: 72% polyethylene, 4% erucamide slip agent Slip agent, 8% boron-containing surfactant anti-fog agent, 6% N,N-methylenebisacrylamide crosslinking initiator and 10% nano-titanium dioxide slow-release agent, inner layer raw material: 84% poly Ethylene, 8% silicone anti-blocking agent, 3% erucamide slip agent and 5% anti-fogging and dripping agent were mixed evenly, and then added to the extrusion equipment for melting. The three heating zones of the extruder The temperature of the section is: 170°C in the feeding section, 180°C in the melting section, and 185°C in the homogenization section. Composite melt obtained by co-extrusion layer;
[0055] The composite melt is inflated once, and the bubble after the first inflation is cooled and shaped to form a tube film;
[0056] The tube membrane is pulled to the electron accelerator. The irradia...
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