Electric-conduction ink for micro gravure printing, and preparation method thereof
A conductive ink and micro-concave technology, used in inks, applications, household appliances, etc., can solve the problems of decomposition failure, limit the high temperature resistance of ink, loss of electrical conductivity, etc., to improve fullness, improve conductivity and uniformity, and color fullness Effect
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Embodiment 1
[0030] Camphorsulfonic acid and aniline in polyaniline were added to the planetary ball mill at a molar ratio of 0.6:1, the ball milling temperature was 220°C, the ball milling time was 6h, the ball mill speed was 1500RPM, and the sanding medium used zirconium beads with a certain proportion and particle size gradient. Among them, the proportion and particle size of zirconium beads are 10%: 0.4~0.6µm, 20%: 0.6~0.8µm, 20%: 0.8~1.0µm, 20%: 1.0~1.2µm, 20%: 1.2~1.4µm, 10 %: 1.4~1.6µm; wash with alcohol three times repeatedly, then dissolve with xylene, filter, spin distill the filtrate, and dry to obtain camphorsulfonic acid doped polyaniline.
[0031] The electrical conductivity of gained camphorsulfonic acid-doped polyaniline is 25S / cm, and solubility in ketone solvent is 52g / 100g, and solubility in ester solvent is 52g / 100g, and solubility in benzene solvent is 59g / 100g; Thermal stability is 280°C.
[0032] Take 100g camphorsulfonic acid doped polyaniline, 80g polyester resin ...
Embodiment 2
[0034]Benzoic acid and aniline in polyaniline are added to the planetary ball mill at a molar ratio of 0.5:1, the ball milling temperature is 200°C, the ball milling time is 6h, the ball mill speed is 1000RPM, and the sand milling medium uses zirconium beads with a certain proportion and particle size gradient. The proportion and particle size of zirconium beads are 10%: 0.4~0.6µm, 20%: 0.6~0.8µm, 20%: 0.8~1.0µm, 20%: 1.0~1.2µm, 20%: 1.2~1.4µm, 10% : 1.4~1.6µm; wash with alcohol three times repeatedly, then dissolve in xylene, filter, spin distill the filtrate, and dry to obtain benzoic acid-doped polyaniline.
[0035] The electrical conductivity of gained benzoic acid-doped polyaniline is 23S / cm, and solubility in ketone solvent is 50g / 100g, and solubility in ester solvent is 53g / 100g, and solubility in benzene solvent is 61g / 100g; Thermal stability is 300g. ℃.
[0036] Take 100g of benzoic acid-doped polyaniline, 80g of polyester resin Vylon 240, 140g of amino resin MAR-532...
Embodiment 3
[0038] Polystyrene sulfonic acid and aniline in polyaniline are added to the planetary ball mill at a molar ratio of 0.55:1, the ball milling temperature is 180°C, the ball milling time is 5h, the ball mill speed is 1400RPM, and the sanding medium uses zirconium with a certain proportion and particle size gradient Beads, the proportion and particle size of zirconium beads are 10%: 0.4~0.6µm, 20%: 0.6~0.8µm, 20%: 0.8~1.0µm, 20%: 1.0~1.2µm, 20%: 1.2~1.4µm , 10%: 1.4~1.6µm; washed with alcohol three times repeatedly, then dissolved in xylene, filtered, and the filtrate was rotary distilled, and dried to obtain polystyrene sulfonic acid doped polyaniline.
[0039] The conductivity of the obtained polystyrenesulfonic acid-doped polyaniline is 20S / cm, the solubility in ketone solvents is 51g / 100g, the solubility in ester solvents is 56g / 100g, and the solubility in benzene solvents is 58g / 100g; thermally stable The temperature is 290°C.
[0040] Take 100g polystyrene sulfonic acid d...
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