Electric-conduction ink for micro gravure printing, and preparation method thereof

A conductive ink and micro-concave technology, used in inks, applications, household appliances, etc., can solve the problems of decomposition failure, limit the high temperature resistance of ink, loss of electrical conductivity, etc., to improve fullness, improve conductivity and uniformity, and color fullness Effect

Inactive Publication Date: 2019-12-31
SUZHOU SHIHUA NEW MATERIAL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Better conductivity and solubility of organic solvents can be applied to conductive ink systems, but after ink coating, in order to completely evaporate the solvent, a higher baking temperature is required. For some 3C products, high temperature treatment is required on the printing layer. The doped polyaniline prepared by this method will decompose and fail after high-temperature baking, and the excellent electrical conductivity will be lost, which limits the application of the ink in high temperature resistance
[0006] With the improvement of 3C product performance requirements, the printing layer is required to be thinner and thinner, the appearance is fine and uniform, and the conductivity is getting better and better. Now the general conductive ink and coating method can no longer meet the requirements.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Camphorsulfonic acid and aniline in polyaniline were added to the planetary ball mill at a molar ratio of 0.6:1, the ball milling temperature was 220°C, the ball milling time was 6h, the ball mill speed was 1500RPM, and the sanding medium used zirconium beads with a certain proportion and particle size gradient. Among them, the proportion and particle size of zirconium beads are 10%: 0.4~0.6µm, 20%: 0.6~0.8µm, 20%: 0.8~1.0µm, 20%: 1.0~1.2µm, 20%: 1.2~1.4µm, 10 %: 1.4~1.6µm; wash with alcohol three times repeatedly, then dissolve with xylene, filter, spin distill the filtrate, and dry to obtain camphorsulfonic acid doped polyaniline.

[0031] The electrical conductivity of gained camphorsulfonic acid-doped polyaniline is 25S / cm, and solubility in ketone solvent is 52g / 100g, and solubility in ester solvent is 52g / 100g, and solubility in benzene solvent is 59g / 100g; Thermal stability is 280°C.

[0032] Take 100g camphorsulfonic acid doped polyaniline, 80g polyester resin ...

Embodiment 2

[0034]Benzoic acid and aniline in polyaniline are added to the planetary ball mill at a molar ratio of 0.5:1, the ball milling temperature is 200°C, the ball milling time is 6h, the ball mill speed is 1000RPM, and the sand milling medium uses zirconium beads with a certain proportion and particle size gradient. The proportion and particle size of zirconium beads are 10%: 0.4~0.6µm, 20%: 0.6~0.8µm, 20%: 0.8~1.0µm, 20%: 1.0~1.2µm, 20%: 1.2~1.4µm, 10% : 1.4~1.6µm; wash with alcohol three times repeatedly, then dissolve in xylene, filter, spin distill the filtrate, and dry to obtain benzoic acid-doped polyaniline.

[0035] The electrical conductivity of gained benzoic acid-doped polyaniline is 23S / cm, and solubility in ketone solvent is 50g / 100g, and solubility in ester solvent is 53g / 100g, and solubility in benzene solvent is 61g / 100g; Thermal stability is 300g. ℃.

[0036] Take 100g of benzoic acid-doped polyaniline, 80g of polyester resin Vylon 240, 140g of amino resin MAR-532...

Embodiment 3

[0038] Polystyrene sulfonic acid and aniline in polyaniline are added to the planetary ball mill at a molar ratio of 0.55:1, the ball milling temperature is 180°C, the ball milling time is 5h, the ball mill speed is 1400RPM, and the sanding medium uses zirconium with a certain proportion and particle size gradient Beads, the proportion and particle size of zirconium beads are 10%: 0.4~0.6µm, 20%: 0.6~0.8µm, 20%: 0.8~1.0µm, 20%: 1.0~1.2µm, 20%: 1.2~1.4µm , 10%: 1.4~1.6µm; washed with alcohol three times repeatedly, then dissolved in xylene, filtered, and the filtrate was rotary distilled, and dried to obtain polystyrene sulfonic acid doped polyaniline.

[0039] The conductivity of the obtained polystyrenesulfonic acid-doped polyaniline is 20S / cm, the solubility in ketone solvents is 51g / 100g, the solubility in ester solvents is 56g / 100g, and the solubility in benzene solvents is 58g / 100g; thermally stable The temperature is 290°C.

[0040] Take 100g polystyrene sulfonic acid d...

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Abstract

The invention discloses electric-conduction ink for micro gravure printing, wherein the electric-conduction ink comprises, by mass, 5-10 wt% of protonic acid doped polyaniline, 20-30 wt% of a mixed resin, 50-55 wt% of a mixed solvent, 1.0-2.0 wt% of an auxiliary agent and 14-21 wt% of electric-conduction carbon black. The invention further discloses a preparation method of the ink, wherein the preparation method comprises: (1) preparing protonic acid doped polyaniline; (2) uniformly dispersing electric-conduction ink components; and (3) adding into a sand mill, and sanding to obtain the electric-conduction ink. According to the invention, the obtained electric-conduction ink can solve the problems of poor heat storage stability, non-uniform resistance distribution, low solvent selectivityand the like of the electric-conduction ink in the prior art, has characteristics of low viscosity and small fineness, and is suitable for micro gravure printing, wherein the printed product has characteristics of thin thickness, uniform and fine in appearance and excellent electrical conductivity, wherein the thickness of the printed layer is 2-30 [mu]m, and the horizontal resistance is smaller than 200 m[omega].

Description

technical field [0001] The invention relates to conductive ink, in particular to a conductive ink suitable for dimple printing and a preparation method thereof. Background technique [0002] Conductive ink is a special ink that allows current to flow. It is composed of dispersed fine conductive particles or conductive polymers. After printing on the substrate, it can act as a wire or an antenna. [0003] At present, the commonly used conductive ink has high viscosity, and the conductive ink is usually transferred to the substrate by doctor blade coating or screen printing. The thickness of the conductive printing layer of doctor blade coating and screen printing is large and uneven, and the appearance is not delicate enough. The conductive printing layer is usually used as the appearance surface of the product, which directly affects the quality of the conductive product. In addition, from the existing research and reports on conductive inks, the most common way to improve ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D11/52C09D11/03C09D11/104C09D11/102C09D11/107
CPCC09D11/52C09D11/03C09D11/104C09D11/102C09D11/107
Inventor 顾正青王开吉计建荣
Owner SUZHOU SHIHUA NEW MATERIAL TECH
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