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Solid fluorescent carbon dot, and preparation method and application thereof

A technology of fluorescent carbon dots and solids, applied in the field of carbon dots, can solve the problems of few solid fluorescent carbon dots, complex preparation and purification methods, etc., and achieve the effect of low price, abundant raw materials, and simple methods

Active Publication Date: 2020-01-10
NORTHEAST FORESTRY UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, most of the solid fluorescent carbon dots prepared by the existing methods emit three primary colors (blue, green, red) fluorescence, and there are relatively few studies on directly obtaining yellow or yellow-green solid fluorescence emission, especially the solid fluorescence with water resistance. Carbon dots are relatively less
And the preparation and purification methods are relatively complicated (such as multiple synthesis, secondary surface structure modification, multiple centrifugal dialysis, etc.)

Method used

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  • Solid fluorescent carbon dot, and preparation method and application thereof
  • Solid fluorescent carbon dot, and preparation method and application thereof
  • Solid fluorescent carbon dot, and preparation method and application thereof

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preparation example Construction

[0033] The invention provides a method for preparing solid fluorescent carbon dots, comprising the following steps:

[0034] Mix rosin-like resin acid, water and ethylenediamine for hydrothermal reaction to obtain solid fluorescent carbon dots.

[0035] In the present invention, unless otherwise specified, the required preparation materials are commercially available products well known to those skilled in the art.

[0036] In the present invention, the abietic resin acid is preferably a resin acid having a tricyclic phenanthrene skeleton structure, more preferably one or more of abietic acid type resin acids, pimaric acid type resin acids and isopimaric acid type resin acids. kind.

[0037] In the present invention, the structural formula of described abietic acid type resin acid is preferably:

[0038]

[0039]

[0040] In the present invention, the structural formula of described pimaric acid type resin acid is as follows:

[0041]

[0042] In the present invent...

Embodiment 1

[0063] Mix and disperse 0.4g rosin (abietic acid) with 70mL deionized water evenly, pour it into a 100mL hydrothermal reaction kettle, and add 1mL ethylenediamine, after mixing evenly, carry out hydrothermal reaction at 200°C for 5h, and the obtained material After naturally cooling to room temperature, centrifuging, the obtained solution was freeze-dried to obtain a crude product; after adding the crude product to anhydrous ethanol for dissolution, the insoluble matter was separated by filtration, and the obtained insoluble matter was dried in an oven to obtain water-soluble carbon dots (product I); The resulting filtrate was concentrated and filtered, and dried in vacuo to obtain solid fluorescent carbon dots (product II).

[0064] It was determined that the solid fluorescent carbon dots (product II) had yellow fluorescence under the irradiation of a 365nm ultraviolet lamp, and the aqueous solution of the water-soluble carbon dots (product I) exhibited blue fluorescence emiss...

Embodiment 2

[0075] Mix 0.4g of dehydroabietic acid (dehydroabietic acid) with 70mL of deionized water and disperse evenly, pour it into a 100mL hydrothermal reaction kettle, add 1mL of ethylenediamine, mix well, and conduct a hydrothermal reaction at 200°C for 5h , after the obtained material is naturally cooled to room temperature, centrifuged, the obtained solution is freeze-dried to obtain a crude product, after the crude product is dissolved in absolute ethanol, the insoluble matter is separated by filtration, and the gained insoluble matter is vacuum-dried to obtain a water-soluble carbon point ( Product I); the resulting filtrate was concentrated and filtered, and dried in vacuo to obtain solid fluorescent carbon dots (product II).

[0076] It has been determined that the solid fluorescent carbon dots (product II) have yellow-green fluorescence under the irradiation of a 365nm ultraviolet lamp, and the aqueous solution of the water-soluble carbon dots (product I) emits blue fluoresce...

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Abstract

The invention belongs to the technical field of carbon dots, and particularly relates to a solid fluorescent carbon dot, and a preparation method and an application thereof. A natural biomass resource-rosin resin acid with a tricyclic phenanthrene skeleton structure is used as a raw material, and the prepared solid fluorescent carbon dot is difficult to be dissolved in water, has adjustable fluorescence and emits yellow (or yellow green) fluorescence. The preparation method which adopts a one-step hydrothermal synthesis process has the advantages of no complex synthesis, separation or purification, simplicity and high yield; and the prepared solid fluorescent carbon dots can be used for successfully preparing white light emitting diodes (WLED) emitting warm white light, pure white light and cold white light, and can also be applied to the fields of waterproof ink printing and cell imaging.

Description

technical field [0001] The invention relates to the technical field of carbon dots, in particular to a solid fluorescent carbon dot and its preparation method and application. Background technique [0002] Phosphor-based white light-emitting diodes (WLEDs) have been widely used due to their low energy consumption, long lifetime, and environmental protection. In recent years, solid fluorescent carbon dots (SF-CDs) have attracted extensive attention in the field of white light-emitting diodes due to their advantages of low cost, tunable fluorescence, and environmental friendliness. At present, most of the solid fluorescent carbon dots prepared by the existing methods emit three primary colors (blue, green, red) fluorescence, and there are relatively few studies on directly obtaining yellow or yellow-green solid fluorescence emission, especially the solid fluorescence with water resistance. There are also relatively few carbon dots. And the preparation and purification method...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K11/65B82Y20/00B82Y40/00H01L33/50G01N21/64C09D11/03
CPCB82Y20/00B82Y40/00C09D11/03C09K11/65G01N21/6428H01L33/504
Inventor 韩世岩葛敏韩有奇李淑君陈志俊于海鹏
Owner NORTHEAST FORESTRY UNIVERSITY
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