Solid fluorescent carbon dot, and preparation method and application thereof
A technology of fluorescent carbon dots and solids, applied in the field of carbon dots, can solve the problems of few solid fluorescent carbon dots, complex preparation and purification methods, etc., and achieve the effect of low price, abundant raw materials, and simple methods
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
preparation example Construction
[0033] The invention provides a method for preparing solid fluorescent carbon dots, comprising the following steps:
[0034] Mix rosin-like resin acid, water and ethylenediamine for hydrothermal reaction to obtain solid fluorescent carbon dots.
[0035] In the present invention, unless otherwise specified, the required preparation materials are commercially available products well known to those skilled in the art.
[0036] In the present invention, the abietic resin acid is preferably a resin acid having a tricyclic phenanthrene skeleton structure, more preferably one or more of abietic acid type resin acids, pimaric acid type resin acids and isopimaric acid type resin acids. kind.
[0037] In the present invention, the structural formula of described abietic acid type resin acid is preferably:
[0038]
[0039]
[0040] In the present invention, the structural formula of described pimaric acid type resin acid is as follows:
[0041]
[0042] In the present invent...
Embodiment 1
[0063] Mix and disperse 0.4g rosin (abietic acid) with 70mL deionized water evenly, pour it into a 100mL hydrothermal reaction kettle, and add 1mL ethylenediamine, after mixing evenly, carry out hydrothermal reaction at 200°C for 5h, and the obtained material After naturally cooling to room temperature, centrifuging, the obtained solution was freeze-dried to obtain a crude product; after adding the crude product to anhydrous ethanol for dissolution, the insoluble matter was separated by filtration, and the obtained insoluble matter was dried in an oven to obtain water-soluble carbon dots (product I); The resulting filtrate was concentrated and filtered, and dried in vacuo to obtain solid fluorescent carbon dots (product II).
[0064] It was determined that the solid fluorescent carbon dots (product II) had yellow fluorescence under the irradiation of a 365nm ultraviolet lamp, and the aqueous solution of the water-soluble carbon dots (product I) exhibited blue fluorescence emiss...
Embodiment 2
[0075] Mix 0.4g of dehydroabietic acid (dehydroabietic acid) with 70mL of deionized water and disperse evenly, pour it into a 100mL hydrothermal reaction kettle, add 1mL of ethylenediamine, mix well, and conduct a hydrothermal reaction at 200°C for 5h , after the obtained material is naturally cooled to room temperature, centrifuged, the obtained solution is freeze-dried to obtain a crude product, after the crude product is dissolved in absolute ethanol, the insoluble matter is separated by filtration, and the gained insoluble matter is vacuum-dried to obtain a water-soluble carbon point ( Product I); the resulting filtrate was concentrated and filtered, and dried in vacuo to obtain solid fluorescent carbon dots (product II).
[0076] It has been determined that the solid fluorescent carbon dots (product II) have yellow-green fluorescence under the irradiation of a 365nm ultraviolet lamp, and the aqueous solution of the water-soluble carbon dots (product I) emits blue fluoresce...
PUM
Property | Measurement | Unit |
---|---|---|
pore size | aaaaa | aaaaa |
particle diameter | aaaaa | aaaaa |
particle diameter | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com