Ultraviolet light cross-linked high flame-retardant low-smoke halogen-free polyolefin cable material and preparation method thereof

A polyolefin cable material and ultraviolet light technology, applied in the field of low-smoke halogen-free flame retardant cable material, can solve the problems of uneven cross-linking degree, high cost of irradiation equipment, unfavorable cost control, etc., to promote mechanical properties, improve Mechanical properties, the effect of improving mechanical properties

Pending Publication Date: 2020-02-04
JIANGSU SHANGSHANG CABLE GRP NEW MATERIAL CO LTD
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The irradiation crosslinking process is to form free radicals through the electron current irradiated by the sensitizer to cause crosslinking. During the irradiation crosslinking process, due to the large fluctuation of the electron current, it is easy to cause crosslinking. The degree is not uniform, and the cost of irradiation equipment is high, which is not conducive to cost control

Method used

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  • Ultraviolet light cross-linked high flame-retardant low-smoke halogen-free polyolefin cable material and preparation method thereof

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Embodiment 1

[0021] The raw material components of UV-crosslinked high flame-retardant low-smoke halogen-free polyolefin cable compound include: base material (ethylene-vinyl acetate (Yangzi BASF, 6110MC): ethylene-octene copolymer (Mitsui, DF840): low linearity Density polyethylene (Sinopec, 7042): maleic anhydride grafted polyethylene (JCP1000) with a mass ratio of 60:15:15:10) 100 parts, low-smoke halogen-free flame retardant (magnesium hydroxide (Aiteke, 10FG): aluminum hydroxide (Yabao, 104LEO) with a mass ratio of 2:1 mixture) 120 parts, multi-walled carbon nanotube synergistic flame retardant (Chengdu Organic Chemistry, TNIM1) 10 parts, Cationic initiator (dimethyliodonium salt (Shanghai Yuli Chemical): a mixture of triarylsulfonium salt (TCI) with a mass ratio of 1:1) 1 part, free radical initiator (2-hydroxy-2-methyl Base-1-phenyl-1-propanone (Huateng): benzophenone (Kunshan Wanjie) with a mass ratio of 1:1 mixture) 1 part, co-crosslinking agent triallyl isocyanurate (Hunan Minhe...

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Abstract

The invention discloses an ultraviolet light cross-linked high flame-retardant low-smoke halogen-free polyolefin cable material and a preparation method thereof. The ultraviolet light cross-linked high flame-retardant low-smoke halogen-free polyolefin cable material comprises the following raw material components in parts by mass: 100 parts of a base material, 100-130 parts of a low-smoke halogen-free flame retardant, 5-15 parts of a synergistic flame retardant, 1-3 parts of a cationic initiator, 1-3 parts of a free radical initiator, 1-5 parts of an assistant crosslinking agent, 0.5-1.5 partsof a compound antioxidant, and 1-3 parts of a lubricant. The combination of two different photo-initiation mechanisms is utilized, the crosslinking efficiency is significantly improved, and wire andcable products have shorter production cycle, and more stable heat resistance and mechanical properties. At the same time, the low-smoke halogen-free flame retardant and the flame-retardant synergistare used, so that relatively good flame retardancy can be obtained and the mechanical properties of the material can be improved in the case of a relatively small total amount of the flame retardant.The base material with a specific composition and the lubricant with a specific composition are selected, so that the mechanical properties of the cable material are further improved, the processing performance of the material is improved, and the preparation efficiency is improved.

Description

technical field [0001] The invention relates to an ultraviolet light cross-linked highly flame-retardant low-smoke halogen-free polyolefin cable material and a preparation method thereof, belonging to the field of low-smoke, halogen-free flame-retardant cable materials. Background technique [0002] In recent years, with the development of society, the application occasions of wires and cables have become more and more extensive. At the same time, the requirements for flame retardancy, mechanical properties, electrical properties and environmental protection of wires and cables have also gradually increased. As a substitute for halogen-containing flame-retardant cable materials, low-smoke halogen-free cable materials have a wider range of applications and are more environmentally friendly, but their flame-retardant and mechanical properties face greater challenges. [0003] In the use of general low-smoke halogen-free polyolefin cable materials, due to the low melting point ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08L51/06C08L23/06C08L83/04C08K13/02C08K3/04C08K5/098C08K3/22C08J3/28C08J3/24
CPCC08J3/24C08J3/28C08J2323/08C08J2423/06C08J2423/08C08J2451/06C08J2483/04C08K2003/2224C08K2003/2227C08K2201/011C08L23/0853C08L2201/02C08L2201/22C08L2203/202C08L2205/035C08L2312/06C08L23/0815C08L51/06C08L23/06C08L83/04C08K13/02C08K3/041C08K5/098C08K3/22
Inventor 陶圣熹刘雄军
Owner JIANGSU SHANGSHANG CABLE GRP NEW MATERIAL CO LTD
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