High-solid-content amino sulfonate water-based spraying polyurethane and preparation method thereof
A technology of spraying polyurethane and water-based polyurethane, which is applied in the direction of polyurea/polyurethane coatings and coatings, can solve the problems of decreased physical properties of leather products, high production and transportation costs, and influence on promotion, and achieve low production costs, large production volume, and high physical properties. Improved effect
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Embodiment 1
[0046]Step 1: Pump 240kg of polytetrahydrofuran ether and 120kg of polypropylene glycol into the dehydration reaction kettle, seal and draw a vacuum, and perform dehydration operation under the conditions of negative pressure of -0.08MPa and temperature of 120°C for 1.5h;
[0047] Step 2: After the dehydration is completed, transfer the mixture to the prepolymerization reactor, lower the temperature to below 65°C, extract 84kg of toluene diisocyanate and 5kg of hexamethylene diisocyanate into the prepolymerization reactor, raise the temperature to 85°C and start timing for the first One-step prepolymerization reaction, reaction 2.5h;
[0048] Step 3: After reacting for 2.5 hours, cool down to 55°C and put in 1.6kg of neopentyl glycol, 1.2kg of trimethylolpropane, 18kg of dimethylolpropionic acid and 25g of catalyst stannous octoate, add 35kg of acetone, and heat up to 76°C Carry out the second step of chain extension prepolymerization reaction, react for 1h, add 10kg of aceton...
Embodiment 2
[0058] Step 1: Pump 324kg of polytetrahydrofuran ether and 36kg of polypropylene glycol into the dehydration reaction kettle, seal and draw a vacuum, and carry out dehydration operation under the conditions of negative pressure of -0.08MPa and temperature of 120°C for 1.5h;
[0059] Step 2: After the dehydration is completed, transfer the mixture to the prepolymerization reactor, lower the temperature to below 65°C, extract 93kg of toluene diisocyanate and 5kg of hexamethylene diisocyanate into the prepolymerization reactor, raise the temperature to 85°C and start timing for the second One-step prepolymerization reaction, reaction 2.5h;
[0060] Step 3: After reacting for 2.5 hours, lower the temperature to 55°C, and put 6kg of trimethylpentanediol, 1.5kg of trimethylolpropane, 8.9kg of dimethylol propionic acid, 18.9kg of dimethylol propionic acid and 30g of suboctanoic acid into the prepolymerization reactor. Tin, add 45kg of acetone, raise the temperature to 78°C for the se...
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