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High-solid-content amino sulfonate water-based spraying polyurethane and preparation method thereof

A technology of spraying polyurethane and water-based polyurethane, which is applied in the direction of polyurea/polyurethane coatings and coatings, can solve the problems of decreased physical properties of leather products, high production and transportation costs, and influence on promotion, and achieve low production costs, large production volume, and high physical properties. Improved effect

Inactive Publication Date: 2020-03-27
SHANDONG TIANQING TECH DEV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the products widely used in the market generally have a low solid content, generally below 20% solid content. There are differences in the compatibility of water-based polyurethanes supplied by various manufacturers, which may easily cause a decline in the physical properties of leather products.
In addition, when water-based polyurethane companies produce spray products, due to the relationship between product selling price and cost, the production and transportation costs are relatively high, which greatly affects market promotion.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046]Step 1: Pump 240kg of polytetrahydrofuran ether and 120kg of polypropylene glycol into the dehydration reaction kettle, seal and draw a vacuum, and perform dehydration operation under the conditions of negative pressure of -0.08MPa and temperature of 120°C for 1.5h;

[0047] Step 2: After the dehydration is completed, transfer the mixture to the prepolymerization reactor, lower the temperature to below 65°C, extract 84kg of toluene diisocyanate and 5kg of hexamethylene diisocyanate into the prepolymerization reactor, raise the temperature to 85°C and start timing for the first One-step prepolymerization reaction, reaction 2.5h;

[0048] Step 3: After reacting for 2.5 hours, cool down to 55°C and put in 1.6kg of neopentyl glycol, 1.2kg of trimethylolpropane, 18kg of dimethylolpropionic acid and 25g of catalyst stannous octoate, add 35kg of acetone, and heat up to 76°C Carry out the second step of chain extension prepolymerization reaction, react for 1h, add 10kg of aceton...

Embodiment 2

[0058] Step 1: Pump 324kg of polytetrahydrofuran ether and 36kg of polypropylene glycol into the dehydration reaction kettle, seal and draw a vacuum, and carry out dehydration operation under the conditions of negative pressure of -0.08MPa and temperature of 120°C for 1.5h;

[0059] Step 2: After the dehydration is completed, transfer the mixture to the prepolymerization reactor, lower the temperature to below 65°C, extract 93kg of toluene diisocyanate and 5kg of hexamethylene diisocyanate into the prepolymerization reactor, raise the temperature to 85°C and start timing for the second One-step prepolymerization reaction, reaction 2.5h;

[0060] Step 3: After reacting for 2.5 hours, lower the temperature to 55°C, and put 6kg of trimethylpentanediol, 1.5kg of trimethylolpropane, 8.9kg of dimethylol propionic acid, 18.9kg of dimethylol propionic acid and 30g of suboctanoic acid into the prepolymerization reactor. Tin, add 45kg of acetone, raise the temperature to 78°C for the se...

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PUM

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Abstract

The invention discloses high-solid-content amino sulfonate water-based spraying polyurethane and a preparation method thereof, and belongs to the technical field of leather spraying adhesives. The high-solid-content amino sulfonate water-based spraying polyurethane comprises the following substances in parts by weight: 240 to 324 parts of polytetrahydrofuran ether, 240 to 36 parts of polypropyleneglycol, 89 to 98 parts of a diisocyanate compound, 2.8 to 7.5 parts of a plasticizer, 0.025 to 0.030 part of a catalyst, 18 to 18.9 parts of dimethylolpropionic acid, 11.5 to 11.7 parts of a neutralizer, 2 to 4 parts of an amino sulfonate chain extender, 45 parts of acetone and 220 to 310 parts of deionized water. The obtained high-solid-content amino sulfonate water-based spraying polyurethane has the advantages that the production process operation is simple, the production cost is low and the production capacity is large; when the high-solid-content amino sulfonate water-based spraying polyurethane is applied to leather spraying products, a base coating product is required to have a certain adhesive force and is required to have the characteristic of no stickiness in the static processof a drying bracket, a floating coat product is required to have relatively high compatibility, top coating is required to have an effect of improving physical properties, and scratch resistance andfolding resistance are generally required.

Description

technical field [0001] The invention belongs to the field of leather spraying adhesives, in particular to a water-based spraying polyurethane with high solid content of sulfamate and a preparation method thereof. Background technique [0002] The spraying process of leather tanneries generally adopts the production process of primer, middle coat and top coat, among which the base coat and top coat products have the characteristics of large consumption. At present, the solid content of the products widely used in the market is generally low, generally less than 20% solid content. The compatibility of water-based polyurethane supplied by various manufacturers is different, which may easily cause the decline of the physical properties of leather products. In addition, when water-based polyurethane companies produce spray products, due to the relationship between product selling price and cost, the production and transportation costs are relatively high, which greatly affects ma...

Claims

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Application Information

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IPC IPC(8): C09D175/08C08G18/12C08G18/34C08G18/48C08G18/66C08G18/32
CPCC08G18/12C08G18/348C08G18/4808C08G18/4825C08G18/4854C08G18/6692C09D175/08C08G18/3855
Inventor 徐旭东刘娅林宁继鑫张留生郭翠娟陈玉国陈建栋赵继光郑萍高云峰
Owner SHANDONG TIANQING TECH DEV
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