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Modified nano-silica and its modification method, anti-corrosion paint and coating

A technology of nano-silica and anti-corrosion coatings, applied in anti-corrosion coatings, epoxy resin coatings, chemical instruments and methods, etc., can solve the problems of inability to achieve long-term anti-corrosion, insufficient hydrophobicity and dispersibility, poor anti-corrosion performance of anti-corrosion coatings, etc. question

Active Publication Date: 2021-09-14
BC P INC CHINA NAT PETROLEUM CORP +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The use of nano-silica in coatings can significantly improve the comprehensive anti-corrosion performance of coatings. At present, the application of nano-silica in coatings has technical problems of insufficient hydrophobicity and dispersibility, resulting in the anti-corrosion performance of anti-corrosion coatings prepared by it. It is poor and cannot meet the requirements of long-term anticorrosion in harsh corrosive environments such as high temperature, high pressure and acidity. Therefore, it is necessary to modify nano-silicon dioxide to improve its hydrophobicity and dispersibility, thereby improving the anti-corrosion properties produced by it. Anti-corrosion properties of coatings

Method used

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  • Modified nano-silica and its modification method, anti-corrosion paint and coating

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Experimental program
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Effect test

Embodiment 1

[0054] An embodiment of the present invention provides a method for modifying nano-silica, comprising:

[0055] Mix nano silicon dioxide with water for a reaction to obtain a reactant;

[0056] Take hexamethyldisilazane and hexamethyldisiloxane and mix them with absolute ethanol to obtain a mixed solution;

[0057] The first reactant is mixed with the mixed solution to perform a secondary reaction to obtain modified nano silicon dioxide.

[0058] Specifically, the molar ratio of hexamethyldisilazane to hexamethyldisiloxane is 1:1.

[0059] Specifically, the total mass of the hexamethyldisilazane and hexamethyldisiloxane is 20% of the mass of the nano-silica.

[0060] Specifically, the mass of the water is 6% of the mass of the nano silicon dioxide.

[0061] Specifically, the first reactant is mixed with the mixed solution to perform a secondary reaction to obtain modified nano-silica, including:

[0062] The first reactant is mixed with the mixed solution, the second reactio...

Embodiment 2

[0066] An embodiment of the present invention provides a method for modifying nano-silica, comprising:

[0067] Mix nano silicon dioxide with water for a reaction to obtain a reactant;

[0068] Take hexamethyldisilazane and hexamethyldisiloxane and mix them with anhydrous methyl ether to obtain a mixed solution;

[0069] The first reactant is mixed with the mixed solution to perform a secondary reaction to obtain modified nano silicon dioxide.

[0070] Specifically, the molar ratio of hexamethyldisilazane to hexamethyldisiloxane is 1:1.

[0071] Specifically, the total mass of the hexamethyldisilazane and hexamethyldisiloxane is 15%-25% of the mass of the nano-silica.

[0072] Specifically, the mass of the water is 5% of the mass of the nano silicon dioxide.

[0073] Specifically, the first reactant is mixed with the mixed solution to perform a secondary reaction to obtain modified nano-silica, including:

[0074] The first reactant is mixed with the mixed solution, the se...

Embodiment 3

[0078] An embodiment of the present invention provides a method for modifying nano-silica, comprising:

[0079] Mix nano silicon dioxide with water for a reaction to obtain a reactant;

[0080] Get hexamethyldisilazane and hexamethyldisiloxane and mix them with anhydrous acetone to obtain a mixed solution;

[0081] The first reactant is mixed with the mixed solution to perform a secondary reaction to obtain modified nano silicon dioxide.

[0082] Specifically, the thickness ratio of the hexamethyldisilazane to hexamethyldisiloxane is 1:1.

[0083] Specifically, the total mass of the hexamethyldisilazane and hexamethyldisiloxane is 15%-25% of the mass of the nano-silica.

[0084] Specifically, the mass of the water is 10% of the mass of the nano silicon dioxide.

[0085] Specifically, the first reactant is mixed with the mixed solution to perform a secondary reaction to obtain modified nano-silica, including:

[0086] The first reactant is mixed with the mixed solution, the...

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Abstract

The present invention specifically relates to a modified nano-silica and its modification method, anti-corrosion coating and coating, and belongs to the technical field of anti-corrosion coatings. The method for modifying nano-silica provided by the invention includes: Silicon oxide is mixed with water to perform a reaction to obtain a primary reactant; take hexamethyldisilazane and hexamethyldisiloxane and mix them with an anhydrous solvent to obtain a mixed solution; mix the first reactant with The mixed solution is mixed, and a secondary reaction is carried out to obtain modified nano-silica; the modified nano-silica prepared by the method of modifying nano-silica provided in the embodiment of the present invention has excellent dispersibility And hydrophobicity, good dispersibility in various organic solvents, after spraying on the surface of carbon steel, the surface of the coating is smooth, which improves the corrosion resistance of the ceramic surface.

Description

technical field [0001] The invention belongs to the technical field of anti-corrosion coatings, and in particular relates to a modified nano silicon dioxide and a modification method thereof, anti-corrosion coatings and coatings. Background technique [0002] Nano-silica is an inorganic chemical material, commonly known as white carbon black, with a particle size range of 1-100 nanometers, a spherical microstructure, and a quasi-granular structure of floc and network. The use of nano-silica in coatings can significantly improve the comprehensive anti-corrosion performance of coatings. At present, the application of nano-silica in coatings has technical problems of insufficient hydrophobicity and dispersibility, resulting in the anti-corrosion performance of anti-corrosion coatings prepared by it. It is poor and cannot meet the requirements of long-term anticorrosion in harsh corrosive environments such as high temperature, high pressure and acidity. Therefore, it is necessar...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09C1/30C09C3/06C09C3/12C09D163/00C09D5/08C09D7/62
CPCC08K2201/011C09C1/3045C09C1/3081C09C1/309C09C3/006C09C3/06C09C3/12C09D5/08C09D163/00C09D7/62C08K9/06C08K3/36
Inventor 张红磊李玲杰杨耀辉林竹张彦军韩文礼王志涛王伟娄亮杰张盈盈周冰赵玉飞郭继银刘苒苏碧煌李海宁
Owner BC P INC CHINA NAT PETROLEUM CORP