A kind of treatment method of metal tailings
A technology for metal tailings and a treatment method, which is applied in the field of solid waste recycling, can solve the problems of complex element composition, high content of heavy metals, aggravating the difficulty of recycling useful elements, etc., and achieves the effect of efficient utilization and maintenance of ecological environment stability.
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Embodiment 1
[0054] This embodiment deals with Xilin lead-zinc tailings, which contains elements such as zinc, lead, copper, cadmium, iron, silicon (muscovite, quartz), aluminum (gross garnet). The process is as follows:
[0055] Step a: Grinding the lead-zinc tailings to 200 mesh lead-zinc tailings powder.
[0056] Step b: Add water, NaOH, and quicklime to the lead-zinc tailings powder to make a slurry, so that the molar amount of sodium hydroxide in the slurry: the sum of the molar amounts of alumina+iron oxide+silica is equal to 2:1.1; the molar amount of calcium oxide is equal to 2:1.1; Quantity: The molar quantity of silicon oxide is equal to 1:1.1.
[0057] Step c: drying the slurry outside the kiln, and sintering the dried raw materials at 1150° C. for 4 hours to obtain sintered clinker.
[0058] Step d: Using a sodium carbonate solution with a concentration of 20 g / L, leaching under constant stirring at room temperature for 5 hours to obtain an aluminum-containing solution, that ...
Embodiment 2
[0066] This embodiment deals with Dexing copper tailings, which contain Zn, Pb, Al, Si, Fe and other elements. The process is as follows:
[0067] Step a: Grinding the copper tailings to 200 mesh copper tailings powder.
[0068] Step b: Add water, NaOH, and quicklime to the copper tailings powder to make a slurry, so that the molar amount of sodium hydroxide in the slurry: the sum of the molar amounts of alumina+iron oxide+silica equals 2:1; the molar amount of calcium oxide : The molar weight of silicon oxide is equal to 1:1.
[0069] Step c: drying outside the kiln, and sintering the dried raw materials at 1150° C. for 4 hours to obtain sintered clinker.
[0070] Step d: Using a sodium carbonate solution with a concentration of 25 g / L, leaching under constant stirring at room temperature for 5 hours to obtain a sodium metaaluminate solution, and separating the solid and liquid to obtain a solid slag.
[0071] Step e: drying the solid slag and crushing it into 200-mesh min...
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