Preparation method of white carbon black/natural rubber composite material

A technology of natural rubber and composite materials, applied in the field of silica/natural rubber composite material preparation, can solve problems such as affecting the health of operators, affecting the performance of rubber products, affecting the performance of rubber products, etc. Performance and dynamic mechanical properties improvement, the effect of solving the effect of additives and filler residues

Inactive Publication Date: 2020-05-19
QINGDAO UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The study found that although the wet mixing process can improve the microscopic dispersion of fillers, because the flocculation and drying methods are mostly chemical means such as acid flocculation, it will affect the performance of rubber products.
The acidic flocculation method has irreversible defects, which will not only affect the health of the operators, but also corrode the equipment. The long-term drying after flocculation is likely to produce acid gas that affects the environment. If the strong acid is not cleaned, it will also affect the subsequent vulcanization time, and , in the acidic environment, the vulcanization time of the rubber compound will produce hysteresis, which will easily cause overvulcanization and affect the performance of rubber products.

Method used

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  • Preparation method of white carbon black/natural rubber composite material
  • Preparation method of white carbon black/natural rubber composite material
  • Preparation method of white carbon black/natural rubber composite material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] The preparation method of the silica / natural rubber composite material involved in this embodiment is the self-gel method, and the process includes four steps of preparing an aqueous solution of silica, preparing an aqueous solution of auxiliary agents, preparing self-gel and dehydrating and drying:

[0019] (1) Preparation of white carbon black aqueous solution: add 40 parts by mass of SiO in No. 1 beaker 2 (silicon dioxide), 5 parts by mass of liquid Si69 (silane coupling agent) solution and deionized water are mixed with 25wt% white carbon black aqueous solution, and the white carbon black aqueous solution is placed in an ultrasonic oscillator with a frequency of 1000 Hz for ultrasonic 10min, Stir once at 5 minutes, and place it in a planetary ball mill for secondary crushing and grinding for 4 hours;

[0020] (2) Preparation of auxiliary agent aqueous solution: add 20 parts by mass of SiO in No. 2 beaker 2 (silicon dioxide), 2 parts by mass of 4020 (antiaging agent...

Embodiment 2

[0024]This embodiment relates to the comprehensive performance test of the silica / natural rubber composite vulcanized rubber. The silica / natural rubber composite prepared by the dry method, the acid flocculation method and the self-gelling method are prepared into the rubber, wherein , the preparation process of the self-gelling rubber compound is as follows: put the silica / natural rubber composite material in an internal mixer at a temperature of 100°C and mix it at a speed of 90r / min for 6min30s, and then mix it at a temperature of 145°C The rubber is discharged to obtain the mixed rubber, and the mixed rubber is placed in an open mill, and at the same time, 1 mass part of S (sulfur) and 1.2 mass parts of CZ (N-cyclohexyl-2-benzothiazole sulfenamide) are added Start the training to obtain the rubber material; carry out the mechanical performance test on the three rubber materials respectively, and the results are as follows: the results are as follows:

[0025]

[0026] ...

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Abstract

The invention belongs to the technical field of natural rubber wet mixing, and relates to a preparation method of a white carbon black/natural rubber composite material. Wet mixing process is adopted,the preparation method comprises the following steps: respectively preparing white carbon black and an auxiliary agent into uniform micron-sized dispersion solutions through mechanical grinding; mixing with natural latex, slowly stirring to enable the natural latex to be in full contact with the white carbon black and the auxiliary to reduce the stability of natural latex, continuously stirring to flocculate into a gel; and carrying out extrusion to realize dehydration and drying of the gel to prepare the white carbon black/natural rubber composite material. The advantages that the quality ofa prepared rubber compound is uniform, the physical property and the dynamic mechanical property are obviously improved compared with those of the traditional mixing process, the production period isalso shortened, andmicrocosmic dispersion effect of the white carbon black in the natural rubber is achieved are achieved; the principle is scientific and reliable, the problem ofauxiliary agent andfiller residues caused by acid flocculation can be solved, the rubber internal mixing time is shortened, the problem of flying of rubber assistants is avoided, and the rubber production efficiency isimproved.

Description

Technical field: [0001] The invention belongs to the technical field of natural rubber wet mixing, and relates to a preparation method of white carbon black / natural rubber composite material, which has the advantages of environmental protection and low energy consumption, can shorten the production cycle, and makes white carbon black in natural rubber Achieve microscopic dispersion and improve rubber performance. Background technique: [0002] Mixing is the most critical process in the processing of rubber products. The purpose is to fully mix the rubber additives in the formula with the rubber, and to disperse the rubber additives as evenly as possible. Rather than saying that the quality of the mixing result directly determines the rubber The performance and service life of the product, rather than the degree of dispersion and distribution of rubber additives in rubber determine the performance and service life of rubber products, so how to improve the dispersion of rubber...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L7/00C08K9/06C08K7/26C08K5/09C08K3/22C08K3/36C08K13/06C08J3/205
CPCC08J3/2053C08J2307/00C08K3/22C08K3/36C08K5/09C08K7/26C08K9/06C08K13/06C08K2003/2296C08L7/00
Inventor 边慧光朱东林汪传生肖瑶宋凤鹏
Owner QINGDAO UNIV OF SCI & TECH
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