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Water-based one-coating UV-cured epoxy acrylate coating and preparation method thereof

A technology of epoxy acrylate and epoxy acrylic acid, which is applied in the field of coatings, can solve the problems of volatile organic compound emissions, poor impact resistance, poor flexibility, etc., to improve adhesion and mechanical properties, and fully cross-link and cure the coating film , Improve the effect of light curing efficiency

Active Publication Date: 2020-06-09
GUANGDONG RITOP FINE CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The main disadvantages of this traditional paint ratio and construction process are: 1. The paint is wasted a lot, and the statistics are not complete. Only about 20% of the paint is effectively retained on the coated workpiece in the traditional spraying method, and the rest is in the paint. Splashing outside the workpiece during the spraying process, even if the paint on the workpiece, most of the solvent will evaporate in the end, leaving only about 20% of the effective part, causing great waste
2. Since most of the traditional spraying paints are organic solvents, the volatilization of solvents causes a large amount of volatile organic compounds (VOCs) emissions, causing serious pollution
5. The cured film is ultra-thin
[0004] Epoxy acrylate resin is a water-based UV curable resin widely used at present. The cured coating film has the advantages of high hardness, good gloss, corrosion resistance and good heat resistance, but epoxy acrylate resin has High viscosity, after UV curing, the paint film has the disadvantages of high hardness, poor flexibility, poor impact resistance, etc.

Method used

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  • Water-based one-coating UV-cured epoxy acrylate coating and preparation method thereof
  • Water-based one-coating UV-cured epoxy acrylate coating and preparation method thereof
  • Water-based one-coating UV-cured epoxy acrylate coating and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] A kind of water-based one coating UV curing epoxy acrylate paint of the present embodiment comprises following components by mass parts:

[0031]

[0032]

[0033] The epoxy acrylic resin of this example is prepared by the following method: heat and stir 100 parts by mass of E-51 epoxy resin to 50°C, then add 5 parts by mass of acrylic acid, 0.05 parts by mass of acrylate quaternary ammonium salt catalyst and 0.05 parts by mass of Inhibitor N-nitrosobenzene aluminum salt, and then heated to 90 ° C for 8 hours to obtain epoxy acrylic resin.

[0034] Described acrylate quaternary ammonium salt, it is prepared by following method:

[0035] Dissolve 90 parts by mass of acrylic acid in ethyl acetate, then dropwise add 1 part by mass of epoxypropyltrimethylammonium chloride (dissolved with 10 parts by mass of acrylic acid in advance), remove ethyl acetate after the reaction is complete, and obtain acrylate quaternary ammonium salt. The usage amount of acrylate quatern...

Embodiment 2

[0039] A kind of water-based one coating UV curing epoxy acrylate paint of the present embodiment comprises following components by mass parts:

[0040]

[0041] The epoxy acrylic resin of this example is prepared by the following method: heat and stir 100 parts by mass of E-44 epoxy resin to 90°C, then add 70 parts by mass of acrylic acid, 3 parts by mass of acrylate quaternary ammonium salt catalyst and 2 parts by mass of Inhibitor N-nitrosobenzene aluminum salt, and then raise the temperature to 150 ° C for 2 hours to obtain epoxy acrylic resin.

[0042] Described acrylate quaternary ammonium salt, it is prepared by following method:

[0043]Dissolve 80 parts by mass of acrylic acid in ethyl acetate, then dropwise add 15 parts by mass of epoxypropyltrimethylammonium chloride (dissolved with 20 parts by mass of acrylic acid in advance), and cool down in an ice-water bath during the reaction to prevent gelation. After the reaction is complete, ethyl acetate is removed to ...

Embodiment 3

[0047] A kind of water-based one coating UV curing epoxy acrylate paint of the present embodiment comprises following components by mass parts:

[0048]

[0049] The epoxy acrylic resin of this example is prepared by the following method: heat and stir 100 parts by mass of F-51 epoxy resin to 70°C, then add 20 parts by mass of acrylic acid, 1 part by mass of acrylate quaternary ammonium salt catalyst and 0.2 parts by mass of Inhibitor N-nitrosobenzene aluminum salt, and then raise the temperature to 100 ° C for 4 hours to obtain epoxy acrylic resin.

[0050] Described acrylate quaternary ammonium salt, it is prepared by following method:

[0051] Dissolve 90 parts by mass of acrylic acid in ethyl acetate, then dropwise add 5 parts by mass of epoxypropyltrimethylammonium chloride (dissolved with 10 parts by mass of acrylic acid in advance), remove ethyl acetate after the reaction is complete, and obtain acrylate quaternary ammonium salt. The usage amount of acrylate quater...

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PUM

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Abstract

The invention belongs to the technical field of coatings, and discloses a water-based one-coating UV-cured epoxy acrylate coating and a preparation method thereof. The coating comprises the followingcomponents in percentage by mass: 25%-50% of epoxy acrylic resin, 10%-20% of a hydrophilic active monomer, 0.1%-3% of a water-based photoinitiator, 1%-7% of water-based silver paste, 1%-3% of water-based color paste, 0.5%-2% of a water-based additive and the balance of water, totaling 100%. By adopting a specific catalyst and a polymerization inhibitor, a paint film can be quickly cured at one time, and the cross-linking curing of the paint film is more sufficient; and a specific hydrophilic functional monomer is adopted, so that the stability of the water-based paint is further improved.

Description

technical field [0001] The invention relates to the technical field of coatings, in particular to a water-based one-coat UV curing epoxy acrylate coating and a preparation method thereof. Background technique [0002] At present, the vast majority of plastic paints are sprayed using the two-coat method or even the three-coat method of primer + topcoat. The primer meets the color system requirements, and the topcoat provides performance requirements. The main disadvantages of this traditional paint ratio and construction process are: 1. The paint is wasted a lot, and the statistics are not complete. Only about 20% of the paint is effectively retained on the coated workpiece in the traditional spraying method, and the rest is in the paint. Splashing outside the workpiece during the spraying process, even if it is the paint on the workpiece, most of the solvent evaporates in the end, leaving only about 20% of the effective part, causing great waste. 2. Since most of the paints...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D163/10C09D171/02C09D7/62C08G59/17
CPCC08G59/1466C09D163/10C09D7/62C09D7/70C08L71/02C08K9/10C08K7/00
Inventor 杨胜廷杨秀维
Owner GUANGDONG RITOP FINE CHEM
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