Resin composition
A technology of resin composition and compound, applied in the direction of epoxy resin coating, coating, etc., can solve the problems of cost and productivity, and achieve the effect of low linear thermal expansion coefficient and excellent flexibility
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[0148] Examples of solvents usable for the preparation of component (C) include N,N-dimethylacetamide, N,N-diethylacetamide, N,N-dimethylformamide, N-methyl -Amide-based solvents such as 2-pyrrolidone; ketone-based solvents such as acetone, methyl ethyl ketone (MEK) and cyclohexanone; ester-based solvents such as γ-butyrolactone; hydrocarbon-based solvents such as cyclohexane and methylcyclohexane solvent. Moreover, in preparation of (C)component, an imidization catalyst, an azeotropic dehydration solvent, an acid catalyst, etc. can be used as needed. Examples of imidization catalysts include triethylamine, triisopropylamine, triethylenediamine, N-methylpyrrolidine, N-ethylpyrrolidine, N,N-dimethyl-4 - Tertiary amines such as aminopyridine and pyridine. Examples of the azeotropic dehydration solvent include toluene, xylene, ethylcyclohexane and the like. As an acid catalyst, acetic anhydride etc. are mentioned, for example. The usage-amount of an imidization catalyst, an a...
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[0250] Hereinafter, the present invention will be specifically described by way of examples. The present invention is not limited by these examples. In addition, hereinafter, "parts" and "%" indicating amounts represent "parts by mass" and "% by mass", respectively, unless otherwise specified.
Synthetic example 1
[0251]
[0252] Drop into 5-amino-1,1'-biphenyl-2-yl ester of 4-aminobenzoic acid (compound of formula (1 '')) 9.13g ( 30 mmol), 4,4'-(4,4'-isopropylidene diphenoxy) diphthalic dianhydride 15.61g (30 mmol), N-methyl-2-pyrrolidone 94.64g , 0.47 g (6 mmol) of pyridine, 10 g of toluene, under a nitrogen atmosphere, at 180 ° C, while discharging toluene to the outside of the system in the middle, carry out imidization reaction for 4 hours, thus obtaining polyimide containing Polyimide solution of resin 1 (20 mass % of non-volatile components). In the polyimide solution, precipitation of the synthesized polyimide resin 1 was not observed.
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