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99results about How to "Low coefficient of linear thermal expansion" patented technology

Protective sealing door for underground refuge chamber

The invention discloses a protective sealing door for an underground refuge chamber. The protective sealing door comprises a door frame and a door plate, wherein the door plate is arranged on the door frame through a rotation shaft; a locking mechanism for locking the door plate on the door frame is arranged on the door plate, a plurality of first reinforcing ribs for reinforcing the strength of the door plate are arranged in the door plate; heat-insulating materials, namely aerogel heat-insulating felts are filled among the reinforcing ribs; at least two annular sealing rings, namely flame-resisting sealing rings are arranged at the joint of the door plate and the door frame; and the periphery of the door plate is locked by the locking mechanism. According to the protective sealing door, the aerogel heat-insulating felts which can bear the temperature of 1,400 DEG C to the maximum are filled in the door plate, so that the door plate can resist high temperature generated during explosion, and the high temperature is insulated out of the refuge chamber; at least two sealing rings which are made of flame-resisting, anti-static, high temperature-resisting and oil-resisting materials are arranged on the contact surface of the door plate and the door frame, so that the protective sealing door has a good sealing effect.
Owner:CCTEG CHINA COAL RES INST

Preparation method for low-dielectric-constant ordered porous polyimide thin film

The invention discloses a preparation method for a low-dielectric-constant ordered porous polyimide thin film. The method comprises the steps that amino-modified silicon dioxide microspheres are prepared, then, polyimide is grafted onto the surfaces of the amino-modified silicon dioxide microspheres in the form of chemical bonds, a polyimide compound thin film is prepared, silicon dioxide is etched away in a hydrofluoric acid etchant, washing and drying are conducted, and then the low-dielectric-constant ordered porous polyimide thin film is obtained. According to the method, air holes which have the hole diameters ranging from 30 nm to 200 n, are uniform in size distribution and are uniformly distributed in the thin film are introduced into the polyimide thin film, the dielectric constant of the polyimide thin film is lowered, and meanwhile due to the fact that the hole diameters are small, and distribution of the air holes inside the thin film is uniform, the polyimide thin film keeps the high mechanical property and breakdown voltage. The preparation method has the advantages of being low in dielectric constant, high in breakdown voltage, good in mechanical property and capable of lowering the thermal expansion coefficient, and has potential application value and good application prospects in a high-frequency, high-speed and high-density integrated circuit.
Owner:HANGZHOU FIRST APPLIED MATERIAL CO LTD

Low-dielectric-constant polyimide composite resin as well as preparation method and application thereof

The invention discloses low-dielectric-constant polyimide composite resin as well as a preparation method and application thereof. The polyimide composite resin is prepared from a polyimide resin unitand a polymethylenimine resin unit through blending and copolymerization. A net-shaped structure is formed in a copolymer structure, so that the gaps among macromolecular chains are increased. By introducing the polymethylenimine resin, the dipole moment of a polyimide molecular chain is decreased; meanwhile, fluorine-containing monomers are adopted during the polymerization, so that the dielectric constant of the polyimide composite resin is commonly decreased. By designing a flexible polyimide molecular chain through the type of monomers, a high-rigid polymethylenimine molecular chain is balanced, and the rigidity-flexibility of a molecular chain section in the final polyimide composite resin reaches a relatively good balance point, so that the polyimide composite resin has relatively good mechanical property, controllable linear thermal expansion coefficient and good application prospects in the products of flexible copper-clad plates, light-sensitive covering films and circuit board products.
Owner:HANGZHOU FIRST ELECTRONIC MATERIAL CO LTD

Preparation method of non-curling high-adhesiveness glue-free flexible copper-clad plate

The invention discloses a direct coating method for preparing a non-curling high-adhesiveness glue-free flexible copper-clad plate. The method comprises the following steps: firstly, dissolving an aromatic diamine monomer containing a benzoxazole structure, an aromatic diamine monomer containing a keto ether structure, an aromatic diamine monomer containing a full-ether link structure and an aromatic dianhydride monomer in an aprotic polar solvent to prepare a polyamic acid glue solution by a polymerization; then, coating the polyamic acid glue solution on a copper foil with the thickness of 6-35 microns; baking at 50-150 DEG C for 5-180 minutes; then, arranging in a vacuum oven or a high-temperature drying tunnel in nitrogen atmosphere for phasic thermocuring respectively at 80 DEG C, 120 DEG C, 180 DEG C, 220-280 DEG C and 320-380 DEG C, wherein each thermocuring phase keeps 10-90 minutes. The glue-free flexible copper-clad plate prepared by the method not only has high adhesiveness, no curling and high peeling strength, but also has excellent chemical performance, heat resistance, favorable bending resistance and lower water-absorbing rate. The method has once coating molding, simple preparation process and lower production cost.
Owner:SICHUAN UNIV

Preparation method of hexagonal boron nitride/polymer blocky composite material with high filling amount

ActiveCN111423699AStrong dense connection structureHigh compressive strengthCompression moldingPolymer science
The invention relates to a preparation method of a hexagonal boron nitride / polymer blocky composite material with high filling amount, wherein the method comprises the steps: step 1, adding hexagonalboron nitride and a polymer matrix into a mortar, grinding uniformly, and mixing to obtain a hexagonal boron nitride-polymer matrix mixture, wherein the polymer matrix is in a liquid state at normal temperature and normal pressure, and can be cured under the condition of changing temperature and / or pressure; step 2, putting the mixture obtained in the step 1 into a ball milling tank, and carryingout uniform ball milling to obtain a mixture obtained by further mixing and uniformly carrying out a reaction on hexagonal boron nitride and the polymer matrix; step 3, putting the mixture obtained inthe step 2 into a mold, and carrying out compression molding to obtain a blocky molded prototype of the polymer composite material; and step 4, polymerizing and curing the blocky forming prototype ofthe polymer composite material obtained in the step 3 to obtain the blocky material of the hexagonal boron nitride / polymer composite material with high filling amount. The composite material has ultrahigh mechanical properties and huge thermal management application potential.
Owner:HEBEI UNIV OF TECH

PP (polypropylene) composite for thin-walled automobile bumper and preparation method of PP composite

The invention discloses a PP (polypropylene) composite for a thin-walled automobile bumper and a preparation method of the PP composite. The PP composite is mainly prepared from 10-30 parts of novel talcum powder subjected to surface modification with an ultrafine silane dispersant and having high regularity and large diameter-thickness ratio, 50-80 parts of conventional PP, 8-20 parts of an elastomer, 0.1-1 part of an antioxidant and 0-3 parts of other auxiliaries. The modified special talcum powder which is subjected to surface modification with the ultrafine silane functional dispersant and has the large diameter-thickness ratio and high lamella integrity is adopted as a filling modification component of the PP composite and is subjected to extrusion pelletization with PP, the elastomer, the antioxidant, an illumination auxiliary and the like by a double-screw extruder, and the PP composite is prepared accordingly. According to the prepared composite, liquidity of the composite is greatly improved while impact toughness and rigidity of the composite are improved, linear thermal expansion coefficient and shrinking percentage of the composite are reduced and dimensional stability and corresponding mechanical properties of a thin-walled bumper sample piece are guaranteed.
Owner:SHANGHAI PRET COMPOSITES +4

Antistatic spray-free polypropylene composite material with low linear thermal expansion coefficient and preparation method of antistatic spray-free polypropylene composite material

ActiveCN110408120AIncreased crystallinity and crystallization speedReduced after contractionAntioxidantWhiskers
The invention discloses an antistatic spray-free polypropylene composite material with low linear thermal expansion coefficient and a preparation method of the antistatic spray-free polypropylene composite material. The antistatic spray-free polypropylene composite material is prepared by mixing and extruding polypropylene, mineral filling, a toughening agent, a functional assistant, a metal pigment, a coupling agent, an antioxidant, a lubricant and a light stabilizer. The functional assistant is prepared by compounding wollastonite whisker and glyceryl monostearyl ester according to the mixing mass ratio of 1:1 to 4:1. According to the antistatic spray-free polypropylene composite material, the polypropylene is compounded with the mineral filling and the toughening agent, the strength, rigidity and toughness of the composite material are ensured, in addition, the crystallization velocity is shortened and the degree of crystallization of the material is increased by adding the functional assistant, the post shrinkage of the product is lowered, the forming period of the product is shortened, meanwhile a conductive network is formed in the material, the material has a certain conductive performance, the surface antistatic property of the material is improved, and thus the modified polypropylene composite material can be widely used in spray-free products.
Owner:HEFEI GENIUS NEW MATERIALS

A kind of preparation method of low dielectric constant ordered porous polyimide film

The invention discloses a preparation method for a low-dielectric-constant ordered porous polyimide thin film. The method comprises the steps that amino-modified silicon dioxide microspheres are prepared, then, polyimide is grafted onto the surfaces of the amino-modified silicon dioxide microspheres in the form of chemical bonds, a polyimide compound thin film is prepared, silicon dioxide is etched away in a hydrofluoric acid etchant, washing and drying are conducted, and then the low-dielectric-constant ordered porous polyimide thin film is obtained. According to the method, air holes which have the hole diameters ranging from 30 nm to 200 n, are uniform in size distribution and are uniformly distributed in the thin film are introduced into the polyimide thin film, the dielectric constant of the polyimide thin film is lowered, and meanwhile due to the fact that the hole diameters are small, and distribution of the air holes inside the thin film is uniform, the polyimide thin film keeps the high mechanical property and breakdown voltage. The preparation method has the advantages of being low in dielectric constant, high in breakdown voltage, good in mechanical property and capable of lowering the thermal expansion coefficient, and has potential application value and good application prospects in a high-frequency, high-speed and high-density integrated circuit.
Owner:HANGZHOU FIRST APPLIED MATERIAL CO LTD
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