The invention discloses an antistatic spray-free polypropylene composite material with low linear thermal expansion coefficient and a preparation method of the antistatic spray-free polypropylene composite material. The antistatic spray-free polypropylene composite material is prepared by mixing and extruding polypropylene, mineral filling, a toughening agent, a functional assistant, a metal pigment, a coupling agent, an antioxidant, a lubricant and a light stabilizer. The functional assistant is prepared by compounding wollastonite whisker and glyceryl monostearyl ester according to the mixing mass ratio of 1:1 to 4:1. According to the antistatic spray-free polypropylene composite material, the polypropylene is compounded with the mineral filling and the toughening agent, the strength, rigidity and toughness of the composite material are ensured, in addition, the crystallization velocity is shortened and the degree of crystallization of the material is increased by adding the functional assistant, the post shrinkage of the product is lowered, the forming period of the product is shortened, meanwhile a conductive network is formed in the material, the material has a certain conductive performance, the surface antistatic property of the material is improved, and thus the modified polypropylene composite material can be widely used in spray-free products.