The invention discloses a
silane-terminated reactive
phosphate flame retardant, a preparation method thereof and application of the
silane-terminated reactive
phosphate flame retardant in building external wall
thermal insulation polyurethane, and belongs to the technical field of macromolecular
flame-retardant materials. The structure of the flame retardant is (RO) 3Si-Z-NH-COO-[X-NH-COO] n-Y-O-P (= O) (OCH3) CH3, Z is a C2-C6 alkylene group, X is a C4-C12 alkylene group, n is 1-5, and Y is a C2-C6 hydroxyl-substituted alkylene group, so that not only is good compatibility considered, but also the cohesiveness with a building base material is greatly improved, and the flame retardant can be applied to the field of building materials. A
phosphorus-based flame-retardant source, a long-chain flexible spacer group and a hydrolyzable
silane end group integrated in a molecular structure serve as
polyol components to directly participate in
polyurethane reaction, so that the flame-retardant grade and the heat preservation property of the foam are greatly improved.