The invention relates to soaping compound enzyme and an application method thereof. The soaping compound enzyme comprises laccase, persulfate and PVP (polyvinylpyrrolidone), and sodium citrate is also added in the soaping compound enzyme. The soaping compound enzyme comprises the following compositions in percentage by mass: 55-80 of the laccase, 15-30 % of the persulfate, 4-10 % of the PVP, and 1-5 % of the sodium citrate. In the soaping compound enzyme disclosed in the invention, cooperative anxoaction can be generated between the sodium citrate and the laccase as well as between the persulfate and the PVP, and thus the whole soaping effect of the soaping compound enzyme is greatly increased. Compared with the traditional soaping technology, according to the soaping compound enzyme disclosed by the invention, the absorbance of raffinate after soaping is obviously reduced, the clarity is increased, and thus the treating difficulty of sewage is reduced; the fastness to wet rubbing of a cloth sample after soaping in increased by 0.5-1 level, and the soaping fastness is increased by 0.5 level; and three washing procedures are saved, 30% of the water consumption is saved, 30% of the procedure time is saved, the production cost is greatly reduced, and the environment pollution is reduced.