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Low-thermal conductivity composite foam material and preparation method thereof

A technology of composite foam and low thermal conductivity, which is applied in the field of preparation of composite foam materials with low thermal conductivity, can solve the problems of poor dimensional stability of aerogel materials, limited operability and application, low mechanical strength, etc., and achieves good insulation. Thermal insulation properties and mechanical properties, improved mechanical properties, the effect of uniform porosity

Inactive Publication Date: 2020-06-26
GONG YI VAN-RES INNOVATION COMPOSITE MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the low mechanical strength and poor toughness of pure airgel, this leads to poor dimensional stability of airgel materials, which limits its operability and application in construction.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] A composite foam material with low thermal conductivity, consisting of a resin-based foam matrix and aerogel, wherein the ratio of the mass parts of the resin-based foam matrix to the aerogel is 1:0.5, and the aerogel is silica aerogel .

[0033] The method for preparing the composite foam material with low thermal conductivity is characterized in that it comprises the following specific steps:

[0034] (1) Resin, hollow microspheres, thermally expanded microspheres, curing agent, accelerator, coupling agent, toughening agent, and flame retardant are 100:20:2:4:2:1:3 in mass parts: Mix evenly at a ratio of 5 to obtain a mixed slurry;

[0035] (2) Filling the mixed slurry into a mold for molding, and curing to obtain a resin-based foam matrix;

[0036] (3) Mix the silicon source, ethanol, water, and catalyst uniformly to obtain a silica sol, wherein the molar ratio of the silicon source, ethanol, water, and catalyst is 1:5:5:0.003;

[0037] (4) The silica sol prepared in step (3...

Embodiment 2

[0046] A composite foam material with low thermal conductivity, composed of a resin-based foam matrix and aerogel, wherein the mass ratio of the resin-based foam matrix to the aerogel is 1:1, and the aerogel is silica aerogel .

[0047] The preparation method of the aforementioned low thermal conductivity composite foam material includes the following specific steps:

[0048] (1) Resin, hollow microspheres, thermal expansion microspheres, curing agent, accelerator, coupling agent, toughening agent, and flame retardant are 100:30:5:10:3:2:5 in mass parts: Mix evenly at a ratio of 10 to obtain a mixed slurry;

[0049] (2) Filling the mixed slurry into a mold for molding, and curing to obtain a resin-based foam matrix;

[0050] (3) Mix the silicon source, ethanol, water, and the catalyst to obtain a silica sol, wherein the molar ratio of the silicon source, ethanol, water and the catalyst is 1:10:5:0.004;

[0051] (4) The silica sol prepared in step (3) is impregnated with the resin-base...

Embodiment 3

[0060] A composite foam material with low thermal conductivity, composed of a resin-based foam matrix and aerogel, wherein the ratio of the mass parts of the resin-based foam matrix to aerogel is 1:5, and the aerogel is silica aerogel .

[0061] The preparation method of the aforementioned low thermal conductivity composite foam material includes the following specific steps:

[0062] (1) Resin, hollow microspheres, thermally expandable microspheres, curing agent, accelerator, coupling agent, toughening agent, and flame retardant are 100:40:1:4:2:2:3 in mass parts: Mix evenly at a ratio of 20 to obtain a mixed slurry;

[0063] (2) Filling the mixed slurry into a mold for molding, and curing to obtain a resin-based foam matrix;

[0064] (3) Mix the silicon source, ethanol, water, and the catalyst to obtain a silica sol, wherein the molar ratio of the silicon source, ethanol, water, and catalyst is 1:7:9:0.0015;

[0065] (4) The silica sol prepared in step (3) is impregnated with the re...

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PUM

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Abstract

The invention discloses a low-thermal conductivity composite foam material, which is prepared by the following steps: uniformly mixing resin, hollow microspheres, thermal expansion microspheres, a curing agent, an accelerant, a coupling agent, a toughening agent and a flame retardant in proportion, and filling a mold with the mixed slurry for molding and curing to obtain a resin-based foam matrix;and uniformly mixing a silicon source, ethanol, water and a catalyst to obtain silica sol, impregnating the resin-based foam matrix with the silica sol, and carrying out gelatinization treatment, aging and drying to obtain the low-thermal conductivity composite foam material. By adding the hollow microspheres, the problems that traditional aerogel is low in mechanical strength and poor in toughness are solved, the operability of the aerogel serving as a thermal insulation material in construction application is improved, and the mechanical properties of the aerogel material are greatly improved. The prepared low-thermal conductivity composite foam material has good heat insulation and sound insulation characteristics and mechanical properties, is simple in forming process and convenient to operate, and can be widely applied to the requirements of industries, buildings and aerospace for heat insulation and heat preservation components.

Description

Technical field [0001] The invention belongs to the technical field of foam material preparation, and specifically relates to a preparation method of a low thermal conductivity composite foam material. Background technique [0002] With the progress of society and economic development, the consumption of energy resources has increased substantially, and people’s awareness of energy conservation and environmental protection has increased. As a high-efficiency energy consumption reduction, thermal insulation materials have been paid more and more attention and are widely used. Used in industry, construction, aviation, aerospace and other fields. At present, thermal insulation materials mainly include: ceramic fiber cotton board, glass fiber cotton board, rock wool board, polystyrene foam board, foamed cement, new expanded perlite insulation system and polystyrene particle insulation slurry. With the further development of technology, thermal insulation material technology is devel...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J9/40C08J9/14C08L63/00C08L63/04C08L81/04C08L9/02C08L9/00C08L71/00C08L77/00C08K13/04C08K7/28C08K5/544C08K3/32C08K7/26C08K5/5435C08K5/523C08K7/24C08K5/03C08K3/22C08K5/06
CPCC08J9/40C08J9/32C08J9/141C08J9/0061C08J9/0066C08J9/0038C08J9/0042C08J9/0019C08J9/0023C08J2203/22C08J2205/026C08J2203/14C08K2003/323C08K13/04C08K7/28C08K5/544C08K7/26C08K5/5435C08K5/523C08J2363/00C08J2363/04C08J2481/04C08J2409/02C08J2409/00C08J2471/00C08J2477/00C08K7/24C08K5/03C08K2003/2224C08K5/06
Inventor 董会娜龚祥明姚栋嘉吕多军曹二伟王红伟张继承张东生
Owner GONG YI VAN-RES INNOVATION COMPOSITE MATERIAL CO LTD
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