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A positive electrode conductive coating that reduces the extension of rolled pole pieces and its preparation method

A conductive coating and positive electrode technology, which is applied in the field of positive electrode conductive coating and its preparation to reduce the extension of the rolled pole piece, can solve the problems of no improvement in the roll pressure of the positive pole piece, achieve industrial operation, suppress deformation of aluminum foil, and strengthen anti-corrosion The effect of shapeshifting ability

Active Publication Date: 2022-03-29
江苏海基新能源股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Chinese patent CN 108511689A discloses a lithium-ion battery positive electrode sheet containing a conductive coating and its preparation method. In this invention, a special conductive coating is coated on the current collector, and the conductive coating is cured by conductive paste. Its conductive paste includes: composite carbon source, binder, dispersant, organic solvent, and its conductive coating can greatly improve the adhesion of the pole piece and enhance the conductivity, but it does not improve the roll pressure of the positive pole piece.

Method used

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  • A positive electrode conductive coating that reduces the extension of rolled pole pieces and its preparation method
  • A positive electrode conductive coating that reduces the extension of rolled pole pieces and its preparation method
  • A positive electrode conductive coating that reduces the extension of rolled pole pieces and its preparation method

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Embodiment 1

[0032] A positive electrode conductive coating that reduces the extension of rolled pole pieces, the conductive coating is cured by conductive paste, and the conductive paste includes conductive graphite KS-6, single-wall carbon nanotubes, Ketjen black, PVAc Emulsion, PTFE emulsion and deionized water are prepared.

[0033] Wherein, the amount of conductive graphite KS-6 is 1wt% of the solvent amount.

[0034] Ketjen black consumption is 1wt% of solvent consumption.

[0035] The solid content of the single-walled carbon nanotube aqueous dispersion is 1 wt%, and the dosage is 3 wt% of the solvent dosage.

[0036] The solid content of the PTFE emulsion is 20wt%, and the consumption is 30wt% of the solvent consumption.

[0037] The solid content of the PVAc emulsion is 54wt%, and the consumption is 10wt% of the solvent consumption.

[0038] A method for preparing a positive electrode conductive coating that alleviates the extension of rolled pole pieces, comprising the followi...

Embodiment 2

[0046] A positive electrode conductive coating that reduces the extension of the rolled pole piece, the conductive coating is solidified by a conductive paste, and the conductive paste includes graphene, single-walled carbon nanotubes, Ketjen black, PVAc emulsion, PTFE emulsion and deionized water.

[0047] Wherein, graphene consumption is 1wt% of solvent consumption.

[0048] Ketjen black consumption is 1.5wt% of solvent consumption.

[0049] The solid content of the single-walled carbon nanotube water dispersion is 1wt%, and the dosage is 1wt% of the solvent dosage.

[0050] The solid content of the PTFE emulsion is 20wt%, and the consumption is 50wt% of the solvent consumption.

[0051] The solid content of the PVAc emulsion is 54wt%, and the consumption is 15wt% of the solvent consumption.

[0052] A method for preparing a positive electrode conductive coating that alleviates the extension of rolled pole pieces, comprising the following steps:

[0053] (1) Add 1.5Kg of...

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Abstract

The invention relates to a positive conductive coating for reducing the extension of a rolled pole piece and a preparation method thereof. The conductive coating is formed by curing a conductive paste, and the conductive paste includes a conductive agent, a binder, and a solvent. The conductive Agent is the mixture of any one in conductive graphite KS-6, graphene and Ketjen black, single-walled carbon nanotubes, and described binding agent is the mixture of polytetrafluoroethylene emulsion and polyvinyl acetate emulsion, and described The solvent is deionized water. The positive electrode conductive coating of the present invention can reduce the extension of the pole piece when the positive pole is rolled, and improve the problem of the pole pieces being broken during the rolling process of the positive pole and during the pinch stretching process after rolling.

Description

technical field [0001] The invention belongs to the technical field of lithium ion batteries, and in particular relates to a positive electrode conductive coating for reducing the extension of rolled pole pieces and a preparation method thereof. Background technique [0002] In recent years, lithium iron phosphate power batteries have been favored by lithium battery experts around the world due to their absolute safety and reliability, long cycle life, and stable discharge platform, and have achieved rapid development. However, lithium iron phosphate as the positive active material The conductivity is poor, so when preparing the positive electrode sheet, a layer of 1-2 μm conductive coating is generally pre-coated on the surface of the aluminum foil current collector to promote electronic conduction between the active material coating and the aluminum foil current collector. [0003] The existing positive electrode primer conductive coating is generally composed of an organi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/62H01M4/04H01M4/136H01M4/1397H01M10/0525
CPCH01M4/625H01M4/622H01M4/623H01M4/0404H01M4/0471H01M4/1397H01M4/136H01M10/0525Y02E60/10
Inventor 王云鹏祝捷乔志鹏
Owner 江苏海基新能源股份有限公司