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Formaldehyde removal catalyst and preparation method and application thereof

A catalyst and formaldehyde technology, applied in the field of formaldehyde removal catalysts and its preparation, can solve the problems of limited practical use value, high cost of noble metal catalysts, activity, stability, and the removal of aldehydes is not as good as noble metal catalysts.

Inactive Publication Date: 2020-07-24
GREE ELECTRIC APPLIANCES INC OF ZHUHAI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the commonly used catalysts on the market are noble metal catalysts, which have excellent aldehyde removal performance, but under low temperature conditions, the aldehyde removal effect is not good
Although it has been reported that the porous structure modified by tetrabutyl titanate and silane coupling agent was used as a carrier at room temperature, and Ag x -The core-grain structure of Pt is a low-temperature noble metal catalyst as the active component. The modification in this technology can effectively improve the hydrophobicity of the porous carrier and prevent the deactivation of the catalyst caused by the desorption of water on the catalyst. There is a synergistic effect between them, resulting in higher activity so that the reaction can be carried out at a lower temperature and the performance is stable, but the cost of the noble metal catalyst is higher, and the cost of replacing the filter screen is higher, which limits its actual use value
If non-precious metal catalysts can be used, the cost can be greatly reduced, but their activity, stability and aldehyde removal effect at low temperature are generally inferior to noble metal catalysts

Method used

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  • Formaldehyde removal catalyst and preparation method and application thereof
  • Formaldehyde removal catalyst and preparation method and application thereof
  • Formaldehyde removal catalyst and preparation method and application thereof

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preparation example Construction

[0039] According to another embodiment of the present application, a method for preparing the catalyst for removing formaldehyde as described above, when the catalyst material is manganese oxide, comprises the following steps:

[0040] In the solution impregnated by the porous carrier, an oxidant containing manganese is added, and then a reducing agent is added, and the reaction is completed on the surface of the porous carrier to generate manganese oxide.

[0041] Manganese-containing oxidant and reducing agent are sequentially added to the solution impregnated with the porous carrier, and the reduction reaction of the manganese-containing oxidant is used to generate manganese oxide, which is directly deposited on the surface of the porous carrier, so that the manganese oxide can be loaded in a wide range. On the surface of the porous carrier, it is beneficial to the catalytic oxidation of formaldehyde.

[0042] In some embodiments, the solution in which the porous carrier is...

Embodiment 1

[0056] The method for preparing described formaldehyde removal catalyst is as follows:

[0057] Immerse 0.5g of ZSM-5 (Si / Al=120) molecular sieve in NaOH solution with a concentration of 0.05mol / L, stir for 20 minutes, and KMnO 4 Dissolve in 100ml of water, after completely dissolved, add it into the mixed solution, heat and stir it, the temperature of the solution rises to 80°C, slowly add an appropriate amount of anhydrous glucose to the solution, and fully react for 8 hours in a water bath at 80°C, The reaction product was centrifuged, washed three times with deionized water, dried at 105°C for 24 hours, and the dried sample was ground, pressed into tablets and sieved. MnO 2 / ZSM-5, MnO 2 The loading was 45 wt%. The aldehyde removal efficiency, XRD pattern and SEM pattern of the obtained catalyst are shown in the accompanying drawings.

[0058] figure 1 is the prepared MnO 2 / ZSM-5 and the XRD spectrum of ZSM-5 molecular sieve, it can be seen that the pure phase ZSM-5...

Embodiment 2

[0062] Immerse 0.5g of ZSM-5 (Si / Al=120) molecular sieve in 0.05mol / L NaOH solution and stir for 20 minutes. KMnO 4 Dissolve in 100ml of water, after completely dissolved, add it to the mixed solution, the temperature of the solution rises to 80°C, heat and stir it, slowly add an appropriate amount of anhydrous glucose to the solution, fully react in a water bath at 80°C for 8 hours, The reaction product was centrifuged, washed three times with deionized water, dried at 105°C for 24h, and the dried sample was placed in a muffle furnace, roasted at 100°C for 4h, then ground, pressed into tablets and sieved. MnO 2 / ZSM-5, MnO 2 The loading was 76 wt%. The aldehyde removal efficiency of the obtained catalyst is shown in attached table 1.

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Abstract

The invention provides a formaldehyde removal catalyst as well as a preparation method and application thereof. The formaldehyde removal catalyst comprises a catalyst material and a porous carrier, wherein the catalyst material is nanoscale particles and can be used for catalytic oxidation of formaldehyde at room temperature, and the catalyst material is loaded on the surface of the porous carrier. The catalyst material is loaded on the porous carrier, so that the specific surface area of the catalyst material is increased, catalytic oxidation of formaldehyde is facilitated, formaldehyde staysin the porous material for a long time, and complete catalytic decomposition of formaldehyde is facilitated.

Description

technical field [0001] The application belongs to the technical field of catalysts, and in particular relates to a catalyst for removing formaldehyde and its preparation method and application. Background technique [0002] As interior decoration becomes the fashion of people's life, the problem of indoor air pollution becomes more and more serious. Formaldehyde is one of the air pollutants, which is highly toxic and irritating to mucous membranes, and is recognized as a carcinogen and teratogenic substance by the World Health Organization. The concentration of formaldehyde in most of the newly decorated rooms exceeds the hygienic standard, which has caused great harm to the human body. Long-term inhalation can cause nasal cavity, mouth, throat cancer, digestive system cancer, lung cancer, skin cancer, and leukemia. Indoor furniture, paint, and interior decoration all volatilize a large amount of formaldehyde, which lasts for several years and endangers people's health and ...

Claims

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Application Information

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IPC IPC(8): B01J29/48B01J29/04B01J29/03B01J23/34B01J35/10B01J37/16B01J37/02B01J37/08B01D53/86B01D53/72
CPCB01J29/48B01J29/045B01J29/0341B01J23/34B01J23/002B01J37/16B01J37/0201B01J37/0213B01J37/08B01D53/8668B01J2229/186B01J2229/40B01J35/61B01J35/60B01J35/643B01J35/40B01J35/647
Inventor 穆杨陈晓陈韬张威刘智亮
Owner GREE ELECTRIC APPLIANCES INC OF ZHUHAI
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