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Low-VOC and antistatic polypropylene material as well as preparation method and application thereof

A polypropylene material and antistatic technology, applied in the field of polymer materials, can solve the problems of reducing the impact performance of polypropylene modified materials, not being able to effectively avoid VOC volatilization, and other performance degradation of materials, achieving low VOC, broad market prospects and Excellent application value and tactile effect

Active Publication Date: 2020-08-14
中广核俊尔(浙江)新材料有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] This application can suppress the volatilization of VOC to a certain extent, but the addition of nano-active zeolite and other adsorption materials increases the production cost, and the polypropylene products produced by the polypropylene composite material are still used after long-term use or in high-temperature environments. Can not effectively avoid the volatilization of VOC
[0006] CN108485075A discloses a special modified polypropylene for low-VOC automotive interior parts, including the following components: polypropylene, talcum powder, glass beads, release agent, antioxidant, lubricant, light stabilizer, low molecular weight Organic matter repellent, in which glass microspheres are used as gas adsorbents, which can adsorb fine molecular organic substances by controlling the partial rupture of glass microspheres, but the specific surface area of ​​glass microspheres is small, even if they are all broken, they can absorb low molecular weight The amount is also very small. In addition, the addition of glass beads will reduce the impact performance and rigidity of polypropylene modified materials. Usually, automotive interior materials also require excellent mechanical properties.
[0007] Similarly, automotive interior materials are also faced with the requirements of dustproof materials and good antistatic properties. In the prior art, antistatic properties are given to low-VOC polypropylene composite materials, usually by adding antistatic additives, but this will cause Increase the cost of raw materials, while the addition of antistatic agents may lead to a decline in other properties of the material

Method used

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  • Low-VOC and antistatic polypropylene material as well as preparation method and application thereof
  • Low-VOC and antistatic polypropylene material as well as preparation method and application thereof
  • Low-VOC and antistatic polypropylene material as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~5 and comparative example 1~3

[0049] Polypropylene, epoxy resin, talcum powder, compatibilizer, lubricant, composite light and heat stabilizer (using antioxidant 1010, antioxidant 168 and light stabilizer 770, light stabilizer 944) Composite), and add coloring agent, after high-speed mixing 2min in high-speed mixer, add in the twin-screw extruder from main feeding feeder, carbon aerogel and the talc powder that account for 10% of talc gross mass mix at high speed After 3 minutes, feed into the twin-screw extruder from the side feeding feeder; the temperature of the twin-screw extruder from the feeding section to the die head is as follows: 190°C, 220°C, 220°C, 220°C, 220°C, 220°C ℃, 220℃, 220℃, the temperature of the die head is 220℃, after 4 hours of double vacuum extraction, head extrusion, drawing, air cooling, pelletizing, and hot blast circulation, it is packaged after drying to obtain low VOC , Antistatic black automotive polypropylene material.

[0050] The component prescription of table 2 embodim...

Embodiment 4

[0054] After the compatibilizer is added in Example 4, the rigidity of the material is improved, and the TVOC still meets the standard requirements. In Example 5, a polar epoxy resin is added, and it can be clearly seen that the surface resistivity of polypropylene after the epoxy resin is added increases. , TVOC decreases, it can be seen that there is a strong affinity between carbon airgel and epoxy resin, which can more effectively disperse carbon airgel in polypropylene resin and enhance the adhesion of the two-phase interface. Improve the performance of materials in all aspects.

[0055] The addition of carbon airgel in the present invention not only maintains the mechanical properties of the material, but also maintains its better TVOC performance and permanent antistatic performance without significantly increasing the density. While the mechanical properties of the material are further improved after adding epoxy resin, the TVOC performance is better.

[0056] Table 3...

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Abstract

The invention relates to the technical field of high polymer materials, and discloses a low-VOC and antistatic polypropylene material as well as a preparation method and an application of the low-VOCand antistatic polypropylene material. 5-20% of an inorganic filler; 2 to 10 % of carbon aerogel; 1-5% of epoxy resin; 1-5% of a compatilizer; 0.1-2% of a composite photo-thermal stabilizer; 0.1-2% ofa colorant; 0.1-2% of a lubricant are melted and mixed to obtain the low-VOC and antistatic polypropylene material; the carbon aerogel is applied to plastic, the characteristics of the carbon aerogelare utilized, and the carbon aerogel, the epoxy resin and the compatilizer are reasonably proportioned to obtain the polypropylene composite material with excellent mechanical properties, VOC emission properties and antistatic properties, and the polypropylene composite material can be applied to parts of interior and exterior decorations of automobiles, and is excellent in touch and long-actingin dust prevention.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a low-VOC, antistatic polypropylene material and its preparation method and application. Background technique [0002] Polypropylene is a general-purpose thermoplastic with excellent comprehensive properties. It has the characteristics of low price, light weight, solvent resistance, easy recycling, and non-toxicity. It is the most important lightweight material for automobiles. It can reduce the weight of auto parts by about 40%. Quality, has been widely used in automotive interior parts, such as dashboards, door panels, pillars, bumpers, etc. [0003] In the prior art, the polypropylene material routinely sold in the market has an unpleasant smell when heated, and even emits an unpleasant smell at room temperature. It contains some additives, which may seep or gasify, affecting the health of users, especially black Polypropylene modified material. Since many black pa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L63/00C08L51/06C08K13/04C08K7/24C08K3/34C08K5/098
CPCC08L23/12C08L2201/04C08K2201/017C08K2201/006C08K2201/005C08L2205/025C08L2205/035C08L2205/03C08L63/00C08K13/04C08K7/24C08K3/34C08K5/098C08L51/06
Inventor 李俊陈晓敏安孝善孙心克周云国郑云磊陈永波田际波
Owner 中广核俊尔(浙江)新材料有限公司
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