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Clean production and preparation method of hydrotalcite for plastic processing

A clean production and hydrotalcite technology, which is applied in the direction of hydrotalcite, chemical instruments and methods, aluminum compounds, etc., can solve the problems that the output of hydrotalcite cannot reach plastic processing users, the cost of downstream users is unacceptable, and the pollution of manufacturers is achieved. Improve production safety, save equipment investment, and save energy

Active Publication Date: 2020-09-01
陈豫镇 +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

As a result, the investment cost is high, the amount of three wastes to be treated is large, the pollution of the manufacturer is difficult to deal with, the cost of downstream users is unacceptable, and the output of hydrotalcite cannot meet the needs of plastic processing users.

Method used

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  • Clean production and preparation method of hydrotalcite for plastic processing
  • Clean production and preparation method of hydrotalcite for plastic processing
  • Clean production and preparation method of hydrotalcite for plastic processing

Examples

Experimental program
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Effect test

Embodiment 1

[0027] A clean production preparation method of hydrotalcite for plastic processing. In this embodiment, aluminum hydroxide is selected as the aluminum source, sodium carbonate is selected as the carbonate, and magnesium oxide is selected as the magnesium source, including the following steps:

[0028] (1) Take 39 grams of commercially available aluminum source and 21 grams of carbonate, stir and mix, add 20-80 mL of water to make a paste, and react at room temperature for 1 hour to obtain aluminum salt.

[0029] (2) Add 50 grams of magnesium source and an appropriate amount of molecular sieve catalyst (the catalyst accounts for 0.1-0.3% of the total solid mass) to the above-mentioned aluminum salt, slowly add 10-80 mL of water depending on the dryness, and react for 30-80 minutes under stirring Put it aside, and then carry out surface activation treatment. The activator is PETS modifier. After activation, it is left to age for more than 12 hours;

[0030] (3) The aging produc...

Embodiment 2

[0032] A clean production preparation method of hydrotalcite for plastic processing. In this embodiment, aluminum hydroxide is selected as the aluminum source, sodium carbonate is selected as the carbonate, and magnesium oxide is selected as the magnesium source, including the following steps:

[0033] (1) Put 355 grams of commercially available aluminum source and 190 grams of soluble carbonate into the mixer and start mixing, slowly add 200-600 mL of water, stir and react at room temperature for half an hour, and leave it for 1 hour to make aluminum salt .

[0034] (2) Gradually add 455 grams of commercially available magnesium source and appropriate amount of molecular sieve catalyst (catalyst accounts for 0.1-0.3% of the total solid mass) to the above-mentioned aluminum salt, slowly add 80-300 mL of water and appropriate amount of modifier PETS, and stir to react 1 hour, leave to age until block;

[0035] (3) Dry, mash, and grind the lumps to make hydrotalcite, a stabiliz...

Embodiment 3

[0040] A clean production preparation method of hydrotalcite for plastic processing. In this embodiment, aluminum hydroxide is selected as the aluminum source, sodium carbonate is selected as the carbonate, and magnesium oxide is selected as the magnesium source, including the following steps:

[0041] (1) Mix 39 kg of commercially available aluminum source and 21 kg of commercially available carbonate in a blender, slowly add 40-100 kg of water, and stir for 1 hour to obtain pasty aluminum salt.

[0042] (2) Slowly add 20 kg of commercially available magnesium source and appropriate amount of molecular sieve catalyst (catalyst accounts for 0.1~0.3% of the total mass of the solid) to the above aluminum salt, and after stirring for 10 minutes, slowly add 40-60 kg of water , react under stirring for 20-40 minutes, add a small amount of dispersant according to the situation during the reaction, stir until it becomes a uniform paste, and leave it to age into a block.

[0043] 3. T...

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Abstract

The invention discloses a clean production and preparation method of hydrotalcite for plastic processing, and belongs to the technical field of hydrotalcite synthesis. The preparation method comprisesthe following steps: 1, preparing raw materials; the preparation method comprises the following steps: mixing and stirring an aluminum source, a magnesium source and carbonate, adding water under theaction of a catalyst to react into paste, and reacting at the temperature of 0-90 DEG C, the molar ratio of the magnesium source to the aluminum source to the carbonate is (3-6): 2: 1, the catalyst accounts for 0.1-0.3% of the total mass of solids, and the water accounts for 0.8-30 times of the total weight of the solids; the preparation method comprises the following steps: firstly, adding the hydrotalcite into a reaction kettle, then placing reactants for aging for not more than 20 hours, then drying the aged product, mashing and grinding until the fineness is 800 meshes or above, and packaging to obtain the hydrotalcite for plastic processing. The method disclosed by the invention has the advantages of low manufacturing cost, no need of high-temperature and high-pressure hydrolysis, simple production equipment, simplicity in operation and the like, and is a clean production process without discharging three wastes.

Description

technical field [0001] The invention belongs to the technical field of hydrotalcite synthesis, and in particular relates to a clean production preparation method of hydrotalcite for plastic processing. Background technique [0002] The hydrotalcite product is originally a layered basic aluminum magnesium carbonate composite hydrate used as a catalyst carrier. Due to the complex production process, the price is expensive and the output is limited. Later, it was found that hydrotalcite can be used as a plastic processing aid. The quality requirements have declined and the dosage has continued to expand, but the production process has not changed much. The representative ones are the production processes of Kyowa Chemical Co., Ltd. of Japan and Shinwon Chemical Co., Ltd. of Korea. The production processes of these two companies follow the production process of magnesium salt and aluminum salt being neutralized with strong alkali after being hydrolyzed under high temperature ...

Claims

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Application Information

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IPC IPC(8): C01F7/00C08K3/26C08L27/06
CPCC08K3/26C08L27/06C01P2004/03C01F7/785
Inventor 陈豫镇陈锋高霞
Owner 陈豫镇