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Self-migration type surface hydrophilic finishing agent as well as preparation method and application thereof

A finishing agent, migration-type technology, applied in pavement details, pavement paved with prefabricated blocks, coatings, etc., can solve the problems of affecting the visual effect of imitation stone, dull surface, impermeability, etc., which is conducive to fogging Chemical spraying, high hydrophilicity, fast migration effect

Active Publication Date: 2020-10-16
武汉开思新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

There is a large color difference in dry and wet conditions, especially when the surface is dry, the surface is dull and obviously white, which seriously affects the visual effect of imitation stone
Although the usual finish sprayed on the surface can improve the gloss and reduce the color difference between dry and wet on the surface, it usually makes the internal pores of the PC imitation stone permeable brick become hydrophobic, making it impermeable.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A self-migrating surface hydrophilic coating agent, including A component and B component, the A component is an epoxy resin composition, and the B component is a curing agent composition;

[0024] The A component includes the following parts by weight: 50 parts of liquid epoxy resin, 3 parts of reactive diluent, 0.3 part of ultraviolet absorber, 0.5 part of antioxidant and 25 parts of water-oil amphiphilic surfactant , wherein the HLB value of the water-oil amphiphilic surfactant is 7; specifically, the liquid epoxy resin includes bisphenol A type epoxy resin and / or bisphenol F type epoxy resin, and in this embodiment, the liquid epoxy resin The resin is bisphenol A type epoxy resin;

[0025] The reactive diluent includes one or more of polyethylene glycol diglycidyl ether, cyclohexanediol diglycidyl ether, and pentaerythritol glycidyl ether. In this embodiment, the reactive diluent is selected from cyclohexanediol diglycidyl ether. Glyceryl ether;

[0026] UV absorb...

Embodiment 2

[0037] A self-migrating surface hydrophilic coating agent, including A component and B component, the A component is an epoxy resin composition, and the B component is a curing agent composition;

[0038] The A component includes the following parts by weight: 60 parts of liquid epoxy resin, 9 parts of reactive diluent, 0.6 part of ultraviolet absorber, 0.8 part of antioxidant and 30 parts of water-oil amphiphilic surfactant , wherein the HLB value of the water-oil amphiphilic surfactant is 7; the specific water-oil amphiphilic surfactant includes at least one of propylene glycol butyl ether, dipropylene glycol butyl ether, and ethylene glycol butyl ether. In this embodiment The water-oil amphiphilic surfactant adopts dipropylene glycol butyl ether;

[0039] Component B includes 65 parts by weight of polyamine curing agent, 15 parts of highly hydrophilic surfactant and 1.5 parts of amino coupling agent.

[0040] Wherein, the liquid epoxy resin includes bisphenol A type epoxy ...

Embodiment 3

[0052] A self-migrating surface hydrophilic coating agent, including A component and B component, the A component is an epoxy resin composition, and the B component is a curing agent composition;

[0053] The A component includes the following parts by weight: 70 parts of liquid epoxy resin, 10 parts of reactive diluent, 0.9 part of ultraviolet absorber, 1 part of antioxidant and 30 parts of water-oil amphiphilic surfactant , wherein the HLB value of the water-oil amphiphilic surfactant is 8; specifically, the water-oil amphiphilic surfactant includes at least one of propylene glycol butyl ether, dipropylene glycol butyl ether, and ethylene glycol butyl ether. The water-oil amphiphilic surfactant adopts ethylene glycol butyl ether;

[0054] Component B includes 70 parts by weight of polyamine curing agent, 20 parts of highly hydrophilic surfactant and 2 parts of amino coupling agent.

[0055] Wherein, liquid epoxy resin comprises bisphenol A type epoxy resin and / or bisphenol ...

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PUM

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Abstract

The invention provides a self-migration type surface hydrophilic finishing agent as well as a preparation method and application thereof. According to the finishing agent, a finishing agent matrix composed of a hydrophobic epoxy resin composition and a hydrophilic curing agent composition is utilized; the hydrophobicity in the system is gradually increased in the reaction curing process of the resin composition and the curing agent; a water-oil amphiphilic surfactant is introduced into the finishing agent, the HLB value of the finishing agent ranges from 7 to 9, the finishing agent can be compatible with resin and a part of water, viscosity can be effectively reduced in the system, atomization spraying is facilitated, and meanwhile certain hydrophilicity is provided for the system. Meanwhile, a high-hydrophilicity surfactant is introduced, the compatibility of the high-hydrophilicity surfactant and the matrix becomes poor and begins to migrate to the surface along with gradual increaseof hydrophobicity in the system in the curing process, and due to the fact that the compatibility is poor, migration is fast, more high-hydrophilicity surfactant is enriched in the surface area of the finishing agent, excellent hydrophilicity is provided for the surface.

Description

technical field [0001] The invention relates to the technical field of resin-bonded sand-based permeable building materials, in particular, the invention relates to a self-migrating surface hydrophilic coating agent and its preparation method and application. Background technique [0002] At present, the hardened and permeable ground pavement for the construction of sponge cities is widely used. Among them, the use of PC imitation stone permeable bricks is often used for municipal and residential permeable pavements due to their advantages of imitating granite, good water permeability, and high cost performance. However, the PC imitation stone permeable brick mainly uses cement as the cementitious material, so a layer of cement hydrate is inevitably wrapped on the surface of the sand fine aggregate, which blocks the true color of the colored sand to a certain extent. There is a large color difference in the dry and wet state, especially when the surface is dry, the surface i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D163/02C08G59/50E01C5/06E01C11/22
CPCC08G59/5006C08G59/5026C08G59/5033C08G59/5073C08L2205/025C09D163/00E01C5/06E01C5/065E01C11/225C08K5/00C08K5/3492C08K5/3475C08K5/1545C08K5/526C08K5/544C08L63/00
Inventor 吴杰
Owner 武汉开思新材料有限公司
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