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Composition for electron transport layer, electron transport layer and photoelectric device

A technology of electron transport layer and optoelectronic device, which is applied in the direction of electric solid-state devices, electrical components, semiconductor devices, etc., can solve the problems of interface damage, easy aging of electronic materials, fast brightness decay, etc., and achieve lower injection barrier and driving voltage , Improve luminous efficiency and lifespan, and improve the effect of short lifespan

Active Publication Date: 2020-10-30
JILIN OPTICAL & ELECTRONICS MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

With the development of OLED materials, organic materials that meet the performance requirements of OLED display panels tend to be electron-transporting. At room temperature, electron injection materials have no obvious impact on life, but at high temperatures, electron injection is slower than electron migration, resulting in electron transport. There is accumulation on the cathode side, and the electronic materials are easy to age, resulting in a shortened life of the OLED display panel
[0004] In addition, the light-emitting region of the device structure is close to the interface between the light-emitting layer and the hole, which is biased towards the electronic system. During the aging process of the life, the excitons have a greater impact on the interface on the HT side, resulting in damage to the interface, which affects the carrier injection. Affect the recombination of excitons, the efficiency is reduced, the brightness decays faster, and finally the life is poor
At present, an electron transport (ET) material and 8-hydroxyquinoline-lithium (Liq) doping technology are mostly used to solve the problem of electron injection and transport. The advantage of this structure is that the structure is relatively simple, but it has high requirements for ET materials and has high Electron mobility is conducive to improving device efficiency but leads to poor life. Although low electron mobility can guarantee life, it will lead to low device efficiency and rapid life decay at high temperatures.

Method used

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  • Composition for electron transport layer, electron transport layer and photoelectric device
  • Composition for electron transport layer, electron transport layer and photoelectric device
  • Composition for electron transport layer, electron transport layer and photoelectric device

Examples

Experimental program
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Effect test

Embodiment 1

[0034] This embodiment provides 17 kinds of electron transport materials, the structural formulas of which are formula ET-1 ~ formula ET-17, as follows:

[0035]

[0036]

[0037] Electron mobility tests are performed on the electron transport materials whose structural formulas are formula ET-1 to formula ET-17 respectively, and the test method is as follows:

[0038] Vacuum evaporation equipment is used to carry out vacuum evaporation on the ITO substrate. Since the material to be tested is an electron transport material, a layer of electron blocking material is first evaporated, with a thickness of 5nm. On this basis, the evaporation is carried out. The test material and Liq, the thickness is 50nm, after the material to be tested is evaporated, the material with electron injection is evaporated, the thickness is 2nm, and finally a layer of cathode is evaporated, which can be Ag, etc., and finally the SCLC space charge control current method is used for simulation. Cal...

Embodiment 1

[0042] This embodiment provides a kind of optoelectronic device, its preparation method comprises the following steps:

[0043]S1. Put the ITO / Ag / ITO thin film (ITO thickness is 14nm, Ag thickness is 150nm) on the glass substrate (150nm) of the OLED device for 2 times in distilled water, ultrasonic cleaning for 30 minutes, and repeated cleaning 2 times with distilled water , Ultrasonic cleaning for 10 minutes, after distilled water cleaning, solvents such as isopropanol, acetone, methanol, etc. are ultrasonically washed in sequence, dried, transferred to a plasma cleaner, washed for 5 minutes, and sent to an evaporation machine.

[0044] S2, compound N, N'-diphenyl-N, N'-di(2-naphthyl)-1,1'-biphenyl-4,4'-diamine (NPB) and 2,3,5 , 6-tetrafluoro-7,7',8,8'-tetracyanoquinone-dimethylmethane (F4-TCNQ) is introduced into the small chamber of the vacuum vapor deposition equipment according to the doping ratio of 97:3, and then the equipment The pressure in the chamber is controlled ...

Embodiment 2

[0055] This embodiment provides a photoelectric device, which is prepared according to the preparation method provided in the above device embodiment 1, the only difference is that the material ET-1 / ET-2 of the electron transport layer is replaced with the material in embodiment 1 ET-1 / ET-5.

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Abstract

The invention discloses a composition for an electron transport layer, the electron transport layer and a photoelectric device, and belongs to the technical field of display, the composition comprises8-hydroxyquinoline-lithium and a composite material; the composite material comprises at least two electron transport materials of which the LUMO energy levels are -2.95eV to -2.70eV; and the mass percentage content of the 8-hydroxyquinoline-lithium in the composition is 40%-60%. The photoelectric device containing the composition enables electron injection to be faster at high temperature and current carrier recombination to be more balanced, so that the problem of short service life at high temperature is solved. Moreover, the electron transport material with a reasonable energy level structure is adopted, so that the energy level in each layer of the photoelectric device can form a stepped barrier, the injection barrier and the driving voltage can be reduced, and meanwhile, the reasonable carrier mobility is matched, so that the carrier recombination is more balanced, and the luminous efficiency and the service life of the device can be effectively improved.

Description

technical field [0001] The invention relates to the field of display technology, in particular to a composition for an electron transport layer, an electron transport layer and a photoelectric device. Background technique [0002] Organic Light Emitting Diode (OLED) display panel is a self-luminous display panel. OLED display panel has the advantages of thinness, high brightness, low power consumption, wide viewing angle, high response speed and wide operating temperature range. It is increasingly used in various high-performance display fields. Optoelectronic devices such as organic electroluminescent devices generally have a multi-layer structure. Various auxiliary functional layers besides the light-emitting layer also play a vital role in device performance. A reasonable device structure can effectively improve the performance of the device. Electron injection Layers, electron-transporting layers, hole-blocking layers, light-emitting layers, electron-blocking layers, ho...

Claims

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Application Information

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IPC IPC(8): H01L51/50H01L51/54
CPCH10K85/00H10K50/11H10K2101/40H10K50/16
Inventor 王铁邱镇姚明明王伟哲刘长伟杨勇马晓宇
Owner JILIN OPTICAL & ELECTRONICS MATERIALS
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