Anti-freezing viscous flame-retardant conductive polymer gel as well as preparation method and application thereof

A conductive polymer and gel technology, which is applied in conductive materials, conductive materials, circuits, etc., can solve the problems of molecular chain movement, intermolecular interaction obstacles, gel self-repair difficulties, etc., to improve mechanical properties and easily self-repair , Good self-healing performance

Active Publication Date: 2020-11-03
NORTH CHINA INST OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, under low temperature conditions, the movement of molecular chains and various interactions between molecules will be hindered, which makes gel self-healing under low temperature conditions very difficult.

Method used

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  • Anti-freezing viscous flame-retardant conductive polymer gel as well as preparation method and application thereof
  • Anti-freezing viscous flame-retardant conductive polymer gel as well as preparation method and application thereof
  • Anti-freezing viscous flame-retardant conductive polymer gel as well as preparation method and application thereof

Examples

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Effect test

preparation example Construction

[0039] A preparation method of antifreeze viscous flame-retardant conductive polymer gel, comprising the following steps:

[0040] (1) dissolving acrylamide monomer and imidazole monomer in a solvent, then adding an initiator, and reacting at 50-80°C for 20-30 minutes to obtain a viscous solution;

[0041] (2) adding conductive polymer monomer or salt thereof to the viscous solution of step (1);

[0042] (3) Then add the iron salt into the solution of (2), stir vigorously for 3-5 minutes to obtain a pre-gel, and leave the pre-gel for more than 3 hours to obtain the final conductive polymer gel.

Embodiment 1

[0045] A kind of antifreeze viscous flame-retardant conductive polymer gel, prepared from the following raw materials in mass percentage: water 50%, acrylamide monomer 10%, 1-allyl-3-methyl imidazole chloride 5%, aniline 15% % and ferric chloride 19.5% and ammonium persulfate 0.5%.

[0046] A preparation method of antifreeze viscous flame-retardant conductive polymer gel, comprising the following steps:

[0047] (1) dissolving acrylamide monomer and imidazole monomer in a solvent, then adding ammonium persulfate, and reacting at 60° C. for 20 minutes to obtain a viscous solution;

[0048] (2) adding aniline to the viscous solution of step (1);

[0049] (3) Then add ferric chloride into the solution of (2), stir vigorously for 3 minutes to obtain a pre-gel, and leave the pre-gel for more than 3 hours to obtain the final conductive polymer gel.

[0050] The conductive polymer gel prepared in Example 1 is tested by cyclic voltammetry, and the CV curve of the conductive polymer ...

Embodiment 2

[0056] A kind of antifreeze viscous flame-retardant conductive polymer gel, prepared from the following raw materials in mass percentage: solvent 45%, acrylamide monomer 15%, 1-allyl imidazole 5%, pyrrole 14.9%, iron sulfate 20% and Potassium persulfate 0.1%, the solvent is a mixed solution of water and ethylene glycol, the volume ratio of water and ethylene glycol is 1:1.

[0057] The preparation method of the antifreeze viscous flame-retardant conductive polymer gel comprises the following steps:

[0058] (1) dissolving acrylamide monomer and imidazole monomer in a solvent, then adding potassium persulfate, and reacting at 50°C for 30 minutes to obtain a viscous solution;

[0059] (2) pyrrole is added in the viscous solution of step (1);

[0060] (3) Then add ferric sulfate into the solution of (2), stir vigorously for 5 minutes to obtain a pre-gel, and leave the pre-gel for more than 3 hours to obtain the final conductive polymer gel.

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Abstract

The invention provides anti-freezing viscous flame-retardant conductive polymer gel as well as a preparation method and application thereof. The conductive polymer gel is prepared from the following raw materials in percentage by mass: 20-60% of solvent, 3-20% of acrylamide monomer, 2-10% of imidazole monomer, 5-30% of conductive polymer monomer or salt thereof, 10-30% of ferric salt and 0.1-1% ofinitiator. The conductive polymer gel disclosed by the invention has anti-freezing viscosity and also has environment resistance, self-repairing performance and flame retardance, and the gel can be widely applied to the fields of electronic conductive adhesives, electrode materials, electronic wires, wearable devices and the like.

Description

technical field [0001] The invention relates to the technical field of adhesive polymers, in particular to a freeze-resistant viscous flame-retardant conductive polymer gel and its preparation method and application. Background technique [0002] Due to its unique three-dimensional network structure, the double-network gel often has excellent mechanical properties such as high scalability, adjustable strength and flexibility due to polymer chain entanglement and multiple cross-linking mechanisms. , self-healing and other properties, it has a wide range of applications in wearable devices, biomedical materials, adhesives, clean energy and other fields. However, the mechanical properties of many hydrogels drop sharply below the freezing point of water, because the solidified crystals significantly inhibit the fluidity of the hydrogel network, thus making the material brittle. In addition, due to the highly confined polymer chains, the conductivity and adhesion of hydrogels ar...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L79/02C08L33/26C08L79/04C08L65/00C08L39/04C08K3/16C08K3/30C08K3/28C08J3/075C08J3/24H01G11/48H01B1/12H01B7/295
CPCC08J3/075C08J3/246H01G11/48H01B7/295H01B1/127H01B1/128C08J2379/02C08J2333/26C08J2479/04C08J2365/00C08J2439/04C08K3/16C08K2003/3072C08K3/28Y02E60/13
Inventor 王昊柴志华高明王彦霞周旋
Owner NORTH CHINA INST OF SCI & TECH
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