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Antibacterial easily-degradable plastic bottle cap and preparation method thereof

A technology of easily degradable plastics and bottle caps, applied in the field of antibacterial and easily degradable plastic bottle caps and their preparation, can solve problems such as difficulty in recycling plastic bottle caps, food and drug pollution, separation of plastic bottle caps, etc., and achieve good environmental benefits , The effect of less environmental pollution, improved fluidity and friction resistance

Pending Publication Date: 2020-11-17
焦作可屹隆瓶业有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the relatively small size of the plastic bottle cap, the phenomenon of separation of the plastic bottle cap and the plastic bottle usually occurs, which also makes it difficult to recycle the plastic bottle cap
In addition, for some plastic bottles containing beverages or food, the caps can protect the beverages and food in the plastic bottles, and the plastic caps are especially prone to bacteria breeding when exposed to the air for a long time, causing pollution to food and medicine.

Method used

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  • Antibacterial easily-degradable plastic bottle cap and preparation method thereof
  • Antibacterial easily-degradable plastic bottle cap and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] Sl, first weighed 3 g silyl quaternary ammonium salt, and then sprayed through the atomizer into 1000 ml three-neck flask with a propeller stirrer with nitrogen in advance with 10 gram of the porous titania in the three-necked flask, starting stirring propeller, sufficiently stirred after a uniform, 10 g of citric acid, mix well;

[0041] S2, stand for 1 hour, filtered off with suction, and dried in vacuo to give after trituration organosilicon quaternary ammonium antibacterial agent powder;

[0042] S3, the polylactic acid 50 g, 10 g of polypropylene, 5 grams of silicon ester, 1 g phthalate, hydroquinone twelve (beta] a-hydroxyethyl) ether, 6 g melted and uniformly mixed, and then the silicone organic antibacterial powder is added; after uniformly mixed, at 170 ℃ ~ 230 ℃ by compression molding injection molding machine, to prepare readily degradable antibacterial plastic bottle caps.

Embodiment 2

[0044] Sl, first weighed 8 g of silicon quaternary ammonium salt, and then sprayed onto 1000 ml three-neck flask with a propeller stirrer with nitrogen protected by a nebulizer, previously added 15 g of titanium dioxide in the porous three-necked flask, starting stirring propeller, sufficiently stirred uniformly, adding 15 grams of citric acid, mix well;

[0045] S2, standing for 2 hours, filtered off with suction, and dried in vacuo to give after trituration organosilicon quaternary ammonium antibacterial agent powder;

[0046] S3, the 70 g of polylactic acid, polypropylene, 20 grams, 10 grams oleic acid amide, a plasticizer, 3 g, 10 g chain extender melted and uniformly mixed, and then the organic antibacterial silicone powder is added; mixing the homogeneous after compression molding by an injection molding machine at 170 ℃ ~ 230 ℃ was prepared readily degradable antibacterial plastic bottle caps.

Embodiment 3

[0048] Sl, first weighed 4 g silicon quaternary ammonium salt, and then sprayed onto 1000 ml three-neck flask with a propeller stirrer with nitrogen protected by a nebulizer, previously added 12 g of titanium dioxide in the porous three-necked flask, starting stirring propeller, sufficiently stirred after a uniform, 11 g of citric acid was added, uniformly mixed;

[0049] S2, stand for 1 hour, filtered off with suction, and dried in vacuo to give after trituration organosilicon quaternary ammonium antibacterial agent powder;

[0050] S3, the 55 parts of a polylactic acid, 13 g of polypropylene, organosilanes 6 grams, 2 grams plasticizers, chain extender 7 g mixed uniformly melted, and then the organic antibacterial silicone powder is added; after uniformly mixed by , at 170 ℃ ~ 230 ℃ by compression molding injection molding machine, to prepare readily degradable antibacterial plastic bottle caps.

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PUM

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Abstract

The invention discloses an antibacterial easily-degradable plastic bottle cap and a preparation method thereof. The antibacterial easily-degradable plastic bottle cap is prepared from the following raw materials in parts by weight: 50-70 parts of polylactic acid; 10-20 parts of polypropylene; 5-10 parts of a dispersing agent; 1-3 parts of a plasticizer; 6-10 parts of a chain extender; 3-8 parts ofsilicon quaternary ammonium salt; 10 to 15 parts of citric acid; 10 to 15 parts of porous titanium dioxide; and 3-8 parts of organosilicon quaternary ammonium salt. Compared with the prior art, the antibacterial easily-degradable plastic bottle cap disclosed by the invention can be quickly decomposed and absorbed by microorganisms in soil, causes little pollution to the environment, and has better environmental benefits; the efficient and long-acting antibacterial property is realized, the antibacterial effect is obvious, and the preservation of the product is better facilitated; injection molding is carried out through a conventional processing technology, so that the preparation method is simple and flexible, and the processing molding performance is good.

Description

Technical field [0001] The present invention relates to the field of plastic caps and preparation method, particularly to a plastic bottle cap easily degradable antibacterial preparation method thereof. Background technique [0002] With the popularity of plastic bottles, the problems it brings more and more significant, because of its good corrosion resistance, and some can not be recycled waste plastic bottles back to nature difficult to break down, resulting in the accumulation of waste plastic this is what we often say "white pollution." [0003] Currently, the most commonly used method is to re-use plastic bottle recycling process. However, due to the relatively small plastic bottle caps, plastic bottle caps typically occurs with plastic bottles isolated phenomenon, which also caused difficult to recycle plastic bottle caps. In addition, for some packaged beverage or food plastic bottles, the caps play a protective effect on the food and beverage plastic bottle, plastic bott...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/04C08L23/12C08L83/08C08K13/04C08K7/24C08K5/092C08K5/544C08K5/06
CPCC08L67/04C08L2201/06C08L2201/08C08L23/12C08L83/08C08K13/04C08K7/24C08K5/092C08K5/12C08K5/06C08K5/544
Inventor 张福国樊凯范学龙
Owner 焦作可屹隆瓶业有限责任公司
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