Method for preparing lithium battery electrode by using supercritical current collector and electrode

A lithium battery and supercritical technology, applied in the field of materials, can solve the problems of increased drying rate, high manufacturing cost, and reduced adhesive force, and achieve the effect of reducing the introduction of impurities, reducing cost and pollution, and enhancing adhesive performance

A lithium battery and supercritical technology, applied in the field of materials, can solve the problems of increased drying rate, high manufacturing cost, and reduced adhesive force, and achieve the effect of reducing the introduction of impurities, reducing cost and pollution, and enhancing adhesive performance

CN112103475AInactive Publication Date: 2020-12-18TIANMU LAKE INST OF ADVANCED ENERGY STORAGE TECH CO LTD

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  • Method for preparing lithium battery electrode by using supercritical current collector and electrode
  • Method for preparing lithium battery electrode by using supercritical current collector and electrode
  • Method for preparing lithium battery electrode by using supercritical current collector and electrode

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preparation example Construction

[0049] The lithium battery electrode material obtained by the preparation method of the invention has good cycle stability, storage life, high temperature performance, safety performance and rate performance.

[0050] In order to better understand the technical solutions provided by the present invention, the following specific examples illustrate the specific process of preparing lithium battery electrodes by applying the methods provided in the above embodiments of the present invention, as well as the methods and battery characteristics of applying them to lithium batteries .

Embodiment 1

[0052] This embodiment provides a method for preparing a lithium battery electrode using a supercritical current collector, comprising the following steps:

[0053] Under the conditions of 120°C and 20MPa, put the graphite negative electrode material, conductive carbon black, styrene-butadiene rubber and sodium carboxymethyl cellulose (CMC) into the autoclave according to the mass ratio of 90:5:2.5:2.5, and pour into the autoclave Add high-pressure supercritical CO 2 For fluid, the closed system of the high-pressure reactor was stirred continuously at 120°C and 20MPa at a speed of 1500rpm for 20 hours, and then the pressure was released. After drying, the obtained material was hot-pressed to obtain a negative electrode sheet.

Embodiment 2

[0065] This embodiment provides a method for preparing a lithium battery electrode using a supercritical current collector, comprising the following steps:

[0066] Under the conditions of 115°C and 15MPa, put the silicon-oxygen negative electrode material, conductive carbon black, styrene-butadiene rubber and CMC into the autoclave according to the mass ratio of 88:6:3:3, and add high-pressure supercritical CO to the autoclave. 2 For the fluid, the closed system of the high-pressure reactor was stirred continuously at a speed of 1200 rpm for 10 hours at 115°C and 15 MPa, and then the pressure was released. After drying, hot pressing was performed to obtain a negative electrode sheet.

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Abstract

The invention relates to a method for preparing a lithium battery electrode by using a supercritical current collector and the electrode. The method comprises the following steps: putting an electrodematerial, a conductive agent and an adhesive into a high-pressure reaction kettle according to a required ratio; adding a supercritical CO2 fluid into a high-pressure reaction kettle, stirring the mixture for 1-20 hours in a high-temperature and high-pressure closed environment at 100-150 DEG C for 1-20 MPa, and forming a uniformly distributed electrode system by the electrode material, the conductive agent and the adhesive under the action of the supercritical CO2 fluid; after stirring is completed, relieving the pressure, wherein in the pressure relief process, the supercritical CO2 fluid is converted into gaseous CO2 to be discharged out of the high-pressure reaction kettle; and after pressure relief is completed, drying and hot-pressing a product in the high-pressure reaction kettle to obtain the lithium battery electrode.

Description

technical field [0001] The invention relates to the technical field of materials, in particular to a method for preparing lithium battery electrodes by using a supercritical current collector and the electrodes. Background technique [0002] With the rapid development of modern social economy and technology, the performance of traditional lithium-ion batteries can no longer meet the current energy demand. The rapid development of electric vehicles, intelligent consumer electronics and other fields are in urgent need of lithium-ion batteries with higher energy density, long cycle life, low cost, and high safety. [0003] At present, in terms of positive and negative electrodes, while the requirements for material capacity are getting higher and higher, higher requirements are also put forward for the stability and consistency of the positive and negative electrodes. At present, the R&D focus of domestic enterprises and research institutes is mainly on the development of NCM8...

Claims

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Application Information

Patent Timeline
18 Dec 2020
Publication
CN112103475A
IPC
H01M4/139; H01M4/04; H01M4/13; H01M10/052; H01M10/0525
CPC
H01M4/04; H01M4/0404; H01M4/13; H01M4/139; H01M10/052; H01M10/0525; Y02E60/10
Inventors
毛泽民; 桂鲁哲