Wear-resistant and stain-resistant ultraviolet curing PVC (polyvinyl chloride) floor coating

An ultraviolet light and floor technology, which is used in polyurea/polyurethane coatings, coatings, chemical industries, etc., can solve the problems of easy migration of antifouling additives and reduced antifouling effect, and achieve good antifouling effect of coatings and reduce Curing shrinkage rate and effect of increasing crosslinking density

Active Publication Date: 2022-01-07
JIANGNAN UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The addition of anti-fouling additives can effectively improve the anti-fouling performance of the coating in the short term, but there is still the problem of easy migration of fluorine-containing anti-fouling additives, and its anti-fouling effect will be greatly reduced as the use time increases

Method used

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  • Wear-resistant and stain-resistant ultraviolet curing PVC (polyvinyl chloride) floor coating
  • Wear-resistant and stain-resistant ultraviolet curing PVC (polyvinyl chloride) floor coating
  • Wear-resistant and stain-resistant ultraviolet curing PVC (polyvinyl chloride) floor coating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] A kind of UV curing PVC floor coating, the preparation method is:

[0035] First, use 5 parts of reactive diluent HDDA, 20 parts of reactive diluent PETA, 0.5 parts of defoamer BYK-066, 0.5 parts of leveling agent BYK-306 and 1 part of wetting and dispersing agent BYK-2009 The high-speed disperser stirs for 10 minutes at the speed of 2000r / min to make the dispersion even.

[0036] Next, add 3 parts of fluorine-containing hyperbranched polythiourethane and 15 parts of matte powder E-1011 in batches, and stir for 30 minutes at a speed of 3500 r / min.

[0037] Finally, add 20 parts of difunctional aliphatic urethane acrylate, 30 parts of hexafunctional aliphatic urethane acrylate, and 5 parts of photoinitiator 1173, and stir evenly at a speed of 2500r / min to obtain a UV-curable PVC floor coating .

[0038] The preparation method of described fluorine-containing hyperbranched polythiourethane is:

[0039] 3.986 g (10 mmol) of trimethylolpropane tris(3-mercaptopropionate),...

Embodiment 2

[0043] A kind of UV curing PVC floor coating, the preparation method is:

[0044]First, use 5 parts of reactive diluent HDDA, 20 parts of reactive diluent PETA, 0.5 parts of defoamer BYK-066, 0.5 parts of leveling agent BYK-306 and 1 part of wetting and dispersing agent BYK-2009 The high-speed disperser stirs for 10 minutes at the speed of 2000r / min to make the dispersion even.

[0045] Next, add 3 parts of fluorine-containing hyperbranched polythiourethane and 15 parts of matte powder E-1011 in batches, and stir for 30 minutes at a speed of 3500 r / min.

[0046] Finally, add 20 parts of difunctional aliphatic urethane acrylate, 30 parts of hexafunctional aliphatic urethane acrylate, and 5 parts of photoinitiator 1173, and stir evenly at a speed of 2500r / min to obtain a UV-curable PVC floor coating .

[0047] The preparation method of described fluorine-containing hyperbranched polythiourethane is:

[0048] 3.986 g (10 mmol) of trimethylolpropane tris(3-mercaptopropionate), ...

Embodiment 3

[0052] A kind of UV curing PVC floor coating, the preparation method is:

[0053] First, use 5 parts of reactive diluent HDDA, 20 parts of reactive diluent PETA, 0.5 parts of defoamer BYK-066, 0.5 parts of leveling agent BYK-306 and 1 part of wetting and dispersing agent BYK-2009 The high-speed disperser stirs for 10 minutes at the speed of 2000r / min to make the dispersion even.

[0054] Next, add 3 parts of fluorine-containing hyperbranched polythiourethane and 15 parts of matte powder E-1011 in batches, and stir for 30 minutes at a speed of 3500 r / min.

[0055] Finally, add 20 parts of difunctional aliphatic urethane acrylate, 30 parts of hexafunctional aliphatic urethane acrylate, and 5 parts of photoinitiator 1173, and stir evenly at a speed of 2500r / min to obtain a UV-curable PVC floor coating .

[0056] The preparation method of described fluorine-containing hyperbranched polythiourethane is:

[0057] 3.986 g (10 mmol) of trimethylolpropane tris(3-mercaptopropionate),...

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PUM

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Abstract

The invention discloses a wear-resistant and stain-resistant ultraviolet curing PVC (polyvinyl chloride) floor coating. The coating is prepared from the following raw materials in parts by weight: 50 to 70 parts of polyurethane acrylate oligomer, 20 to 50 parts of reactive diluent, 10 to 15 parts of matt powder, 1 to 5 parts of photoinitiator, 0.3 to 5 parts of fluorine-containing hyperbranched polythionocarbamate and 1 to 2 parts of additive. The fluorine-containing hyperbranched polythionocarbamate added in the invention not only reduces the internal stress and curing shrinkage of a system and enhances the adhesive force with a base material, but also improves the crosslinking density, hardness and wear resistance of the coating by introducing a rigid polythionocarbamate structure.

Description

technical field [0001] The application of the present invention relates to the technical field of light-cured coatings, in particular to a wear-resistant and anti-fouling UV-cured PVC floor coating. Background technique [0002] Ultraviolet curing (UV) coatings are a new type of environmentally friendly coatings. Compared with traditional heat curing, UV light curing technology has the "5E" characteristics of high efficiency, fast speed, environmental protection, energy saving and wide adaptability. Urethane acrylate is an important light-curable oligomer because of the diversity of its structure selection, which can synthesize oligomers with set properties through molecular design. In recent years, with the continuous improvement of people's living standards, wear-resistant and anti-fouling UV-curable PVC floor coatings have received extensive attention. [0003] At present, the application of PVC floor coatings in China is gradually becoming popular, and it is widely use...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D175/14C09D7/65
CPCC09D175/14C09D7/65C08L2205/025C08L75/14Y02P20/10
Inventor 李小杰胡增顾正明徐健刘晓亚
Owner JIANGNAN UNIV
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