Preparation method of large-caliber columnar ceramic membrane support body and ceramic membrane product thereof
A ceramic membrane support and large-diameter technology, which is applied in the field of membrane separation, can solve the problems of unfavorable product quality control and large-diameter extrusion products, and achieve the effects of easy extrusion molding and control, reduced permeation resistance, and reduced process difficulty
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Embodiment 1
[0037] The preparation method of a large-diameter columnar ceramic membrane product in this embodiment is as follows: the separation membrane layer slurry is coated on the inner wall of the raw material liquid channel 3 of the large-diameter columnar ceramic membrane support to form a separation membrane layer, and a large-diameter columnar ceramic membrane product is obtained. Ceramic membrane products.
[0038] Wherein, the preparation method of large diameter columnar ceramic membrane support body is, as figure 1 As shown, the large-diameter (diameter is 60mm) columnar porous channel (180 channels) ceramic membrane is divided symmetrically along the axial direction to form 6 monomers, and each monomer is used as a support unit 1 (see figure 2 ), first adopt extrusion molding to prepare each support body unit 1 respectively, and then splicing and combining to form a columnar structure; the steps are as follows:
[0039] (1) Preparation of support unit 1
[0040] Mix 100kg...
Embodiment 2
[0049] The preparation method of a large-diameter columnar ceramic membrane product in this embodiment differs from Embodiment 1 in that:
[0050] The preparation of the separation membrane layer slurry in this embodiment is as follows: get 10g Dolapix CE-64 and dissolve it in 9kg water, add 1kg of alumina powder with an average particle diameter of 0.2 μm, and then add 30g of polyvinyl alcohol 1750 (polyvinyl alcohol needs to be prepared in advance into a solution with a concentration of 10% by weight), and mixed together under vigorous stirring conditions to obtain a stable suspension slurry.
[0051] In the preparation of the separation membrane layer in this example, the calcination temperature was 1350° C., and the holding time was 2 hours to obtain a separation membrane layer with an average pore diameter of 50 nm, that is, to produce a large-diameter columnar ceramic membrane product.
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