Photonic crystal structure chromogenic fabric and preparation method thereof

A technology of photonic crystals and structural coloration, applied in textiles and papermaking, fiber treatment, fiber types, etc., can solve the problems of restricting large-scale industrial applications, high investment in equipment at one time, complicated preparation process, etc., to avoid VOCs pollution problems, Reduced energy waste and the effect of excellent optical properties

Active Publication Date: 2021-02-05
ZHEJIANG SCI-TECH UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But hollow SiO 2 The preparation process of nanospheres is complicated, which limits the large-scale industrial application of this method in the textile field
Similarly, the method of encapsulating photonic crystals by photocuring to improve their structural stability will also affect the optical properties of photonic crystals (CN201810127322.0)
In addition, some researchers have tried to prepare soft nano-microspheres as structural units for assembling photonic crystals, and the preparation of flexible photonic crystal structure chromogenic films by external force shear-induced self-assembly technology can also achieve the effect of enhancing the stability of photonic crystal structures. However, the preparation process of flexible nanospheres is complicated, and external shear-induced self-assembly requires high processing temperature and complex special equipment, resulting in high energy consumption and high equipment investment (Zhao Q, Finlayson C E, Snowwell D R E , et al. Large-scale ordering of nanoparticles using viscoelastic shearprocessing[J]. Nature communications, 2016, 7(1): 1-10. CN201610329842.0)
The method of using polar small molecule additives to improve the stability of the photonic crystal structure is also mentioned (CN201910967023.2), but the structural stability and flexibility of the photonic crystal prepared by this method cannot meet the conventional application requirements in the textile field

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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  • Photonic crystal structure chromogenic fabric and preparation method thereof
  • Photonic crystal structure chromogenic fabric and preparation method thereof
  • Photonic crystal structure chromogenic fabric and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] A method for preparing a photonic crystal structure color-producing fabric, the specific steps of the method are:

[0039] (1) Prepare a dispersion of 0.5% photonic crystal structure unit 290nm PS nanospheres, and construct a photonic crystal structure on the surface of polyester textile substrate by impregnation method at a temperature of 50°C and a humidity of 50%;

[0040] (2) Prepare a water-based polyurethane PUE1401 solution and apply it on the surface of the photonic crystal structure chromogenic fabric, the mass fraction of the water-based polyurethane solution is 0.5%;

[0041] (3) Put the color-producing fabric with photonic crystal structure coated with encapsulant in a drying device for drying and curing. The drying temperature was set at 50°C.

Embodiment 2

[0043] A method for preparing a photonic crystal structure color-producing fabric, the specific steps of the method are:

[0044] (1) Prepare 1% photonic crystal structure unit 240nm SiO 2 Dispersion of nano-microspheres, and build a photonic crystal structure on the surface of polyester textile substrate by impregnation method, temperature 60 ℃, humidity 60%;

[0045] (2) Prepare a water-based acrylate solution and apply it on the surface of the photonic crystal structure chromogenic fabric, the mass fraction of the water-based acrylate solution is 1%;

[0046] (3) Put the color-producing fabric with photonic crystal structure coated with encapsulant in a drying device for drying and curing. The drying temperature was set at 60°C.

Embodiment 3

[0048] A method for preparing a photonic crystal structure color-producing fabric, the specific steps of the method are:

[0049] (1) Prepare a 200nm PMMA nanosphere dispersion liquid with 28% photonic crystal structure unit, and build a photonic crystal structure on the surface of polyester textile substrate by scraping method at a temperature of 70°C and a humidity of 70%;

[0050] (2) Prepare a water-based silicone solution and apply it on the surface of the photonic crystal structure color-producing fabric. The massfraction of aqueous organic silicon solution is 2%;

[0051] (3) Put the color-producing fabric with photonic crystal structure coated with encapsulant in a drying device for drying and curing. The drying temperature was set at 70°C.

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Abstract

The invention relates to a photonic crystal structure chromogenic fabric and a preparation method thereof, and belongs to the field of photonic crystal structure chromogenesis. The preparation methodof the photonic crystal structure chromogenic fabric comprises the following steps that (1), dispersion liquid of photonic crystal structure primitive nano microspheres is prepared, a photonic crystalstructure is constructed on the surface of a textile base material, and the photonic crystal structure chromogenic fabric is obtained; (2), an encapsulant solution is prepared, and the surface of thephotonic crystal structure chromogenic fabric is coated with the encapsulant solution, the mass fraction of an encapsulant in the encapsulant solution is 0.1-10%, and the encapsulant is selected fromone or a mixture of more of waterborne polyurethane, waterborne acrylate, waterborne urethane acrylate or waterborne organic silicon; and (3), the photonic crystal structure chromogenic fabric obtained in the step (2) is dried and cured in a drying device to obtain the photonic crystal structure chromogenic fabric.

Description

technical field [0001] The invention relates to a photonic crystal structure color-producing fabric and a preparation method thereof, belonging to the field of photonic crystal structure color-producing fabric. Background technique [0002] Textiles are usually colored with chemical colorants such as dyes or pigments. This traditional printing and dyeing technology usually has a large amount of water, alkali and salt, and it is difficult to treat wastewater in the later stage, resulting in serious waste of water resources and serious pollution problems. In nature, many organisms have brilliant and colorful structural colors, such as chameleons, opals, and peacock feathers. The colors are produced by the physical effects (diffraction, scattering, interference, etc.) of the organism's own special micro-nano structure and visible light. Yes, photonic crystal structure color is one of the important manifestations. A photonic crystal is a nanomaterial with a periodic dielectric ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M15/233D06M11/79D06M15/263D06M15/37D06N3/14D06N3/04D06N3/12D06M101/32
CPCD06M15/233D06M11/79D06M15/263D06M15/37D06N3/14D06N3/042D06N3/128D06M2101/32
Inventor 邵建中王晓辉赵倩李义臣王少杰
Owner ZHEJIANG SCI-TECH UNIV
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