Negative ion functional chip, preparation method and negative ion sanitary napkin
A negative ion and chip technology, applied in sanitary napkins, medical science, bandages, etc., can solve the problems of antibacterial performance, negative ion release performance, and durability to be improved.
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[0059] The preparation method of carboxylated calcium lignosulfonate in the embodiment is the same as the preparation method of carboxylated calcium lignosulfonate in Example 1 of patent application CN201711381045.8. The raw material calcium lignosulfonate is calcium lignosulfonate of model MG-3 provided by Shanghai Yunzhe New Material Technology Co., Ltd.
[0060] In the examples, sharp-state nano-titanium dioxide, CAS number: 1317-80-2. Provided by Xuancheng Jingrui New Material Co., Ltd., model: VK-TA18, purity > 99.8%, particle size: 20nm, specific surface area: 80m 2 / g.
[0061] In the embodiment, the reduced graphene oxide is provided by Shanghai Heditong Nano Technology Co., Ltd., the manufacturer: Graphene Supermarket, the product number: HDT0345, the purity is 98%, and the specific surface area is 400m 2 / g.
[0062] Bismuth tungstate in the examples, CAS number: 13595-87-4.
[0063] Lead acetate (trihydrate) in the examples, CAS number: 6080-56-4.
[0064] Hydr...
Embodiment 1
[0067] (1) Ultrasonic dispersion of anatase nano-titanium dioxide and reduced graphene oxide in deionized water at a mass ratio of 100:6, with a solid-to-liquid mass ratio of 1:80, stirred evenly, and heated at 100°C for 5 hours for water Thermal reaction, natural cooling after the reaction, vacuum filtration, washing to neutrality, drying, grinding, titanium dioxide composite material can be obtained.
[0068] (2) 5 parts of tourmaline powder, 4 parts of medical stone powder, 1 part of Carbomer 940, 10 parts of calcium carboxylated lignosulfonate, 0.07 part of copper citrate, 0.03 part of silver citrate, 0.4 Add 90 parts of titanium dioxide composite material to 90 parts of deionized water and stir for 10 minutes at a speed of 300 r / min, and mix evenly to obtain a negative ion finishing solution.
[0069] (3) Dip the chip in an anion finishing solution at 45°C, the mass ratio of the chip to the anion finishing solution is 1:5, the dipping time is 30min, and dry at 50°C for 3h...
Embodiment 2
[0072] (1) Ultrasonic dispersion of anatase nano-sized titanium dioxide and bismuth tungstate in deionized water with a mass ratio of 100:6, with a solid-to-liquid mass ratio of 1:80, stirred evenly, and heated at 100°C for 5 hours for hydrothermal After the reaction is completed, cool naturally, vacuum filter, wash until neutral, dry, and grind to obtain a titanium dioxide composite material.
[0073](2) 5 parts of tourmaline powder, 4 parts of medical stone powder, 1 part of Carbomer 940, 10 parts of calcium carboxylated lignosulfonate, 0.07 part of copper citrate, 0.03 part of silver citrate, 0.4 Add 90 parts of titanium dioxide composite material to 90 parts of deionized water and stir for 10 minutes at a speed of 300 r / min, and mix evenly to obtain a negative ion finishing solution.
[0074] (3) Dip the chip in an anion finishing solution at 45°C, the mass ratio of the chip to the anion finishing solution is 1:5, the dipping time is 30min, and dry at 50°C for 3h to obtain...
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