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Separation method for recycled aggregate of waste flat plate type denitration catalyst

A technology for denitrification catalyst and aggregate recovery, which is applied in the field of waste flat denitrification catalyst recovery aggregate separation, can solve the problems of inability to obtain pure and highly active paste, difficulty in fully separating paste, lack of deep ash cleaning treatment, etc., to achieve Avoid the inconvenience of separation, reduce mechanical disturbance, and ensure the effect of activity

Pending Publication Date: 2021-03-26
南京碧林环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This process is easy to crush the stainless steel metal mesh, so that the components of the metal mesh are mixed into the paste, and a pure and highly active paste cannot be obtained; and it is difficult to fully separate the paste in the mesh and folds, so the recovery rate is not high
In addition, due to the lack of deep ash removal treatment, fly ash remains on the surface of the catalyst and in the micropores, resulting in low activity of the separated and recovered catalyst paste

Method used

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  • Separation method for recycled aggregate of waste flat plate type denitration catalyst

Examples

Experimental program
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Effect test

Embodiment 1

[0036] Such as figure 1 As shown, the waste flat plate denitrification catalyst recycling aggregate separation method includes the following steps:

[0037] S1, mechanical cleaning

[0038] The waste flat denitrification catalyst first enters the dust removal device for mechanical soot blowing to remove the fly ash on the surface of the catalyst, so that the aggregate of the catalyst is fully exposed; for the thicker part of the catalyst surface, it is manually cleaned with a spatula and other tools before mechanical cleaning. soot blowing;

[0039] S2, ultrasonic cleaning

[0040] Put the mechanically cleaned catalyst in the deionized water cleaning tank, and use the energy penetration of ultrasonic waves to clean for 2 hours, so as to enhance the exchange effect between the blockages in the micropores on the surface of the catalyst and the external solute molecules, and achieve the effect of cleaning the poisons in the micropores , so that the microstructure of the spent ...

Embodiment 2

[0052] Such as figure 1 As shown, the waste flat plate denitrification catalyst recycling aggregate separation method includes the following steps:

[0053] S1, mechanical cleaning

[0054] The waste flat denitrification catalyst first enters the dust removal device for mechanical soot blowing to remove the fly ash on the surface of the catalyst, so that the aggregate of the catalyst is fully exposed; for the thicker part of the catalyst surface, it is manually cleaned with a spatula and other tools before mechanical cleaning. soot blowing;

[0055] S2, ultrasonic cleaning

[0056] Put the mechanically cleaned catalyst in the deionized water cleaning tank, and use ultrasonic energy to penetrate for 3 hours to enhance the exchange effect between the blockage in the micropores on the surface of the catalyst and the external solute molecules, and achieve the effect of cleaning the poison in the micropores , so that the microstructure of the spent catalyst is effectively restor...

Embodiment 3

[0068] Such as figure 1 As shown, the waste flat plate denitrification catalyst recycling aggregate separation method includes the following steps:

[0069] S1, mechanical cleaning

[0070] The waste flat denitrification catalyst first enters the dust removal device for mechanical soot blowing to remove the fly ash on the surface of the catalyst, so that the aggregate of the catalyst is fully exposed; for the thicker part of the catalyst surface, it is manually cleaned with a spatula and other tools before mechanical cleaning. soot blowing;

[0071] S2, ultrasonic cleaning

[0072] Put the mechanically cleaned catalyst in the deionized water cleaning pool, and use ultrasonic energy to penetrate for 4 hours to enhance the exchange effect between the blockages in the micropores on the surface of the catalyst and the external solute molecules, and achieve the effect of cleaning the poisons in the micropores , so that the microstructure of the spent catalyst is effectively rest...

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Abstract

The invention belongs to the technical field of waste denitration catalysts, and particularly relates to a separation method for recycled aggregate of a waste flat plate type denitration catalyst. Themethod comprises the following steps: mechanical ash removal, ultrasonic cleaning, softening treatment, ultrahigh-pressure washing, precipitation and filtration, drying, and roasting. By adopting themethod for separation, catalyst paste is more thoroughly separated, and a recovery rate is high; the degree of damage to the structure of the catalyst is small, the inconvenience in separation causedby wrinkles during mechanical stripping can be effectively avoided, mechanical disturbance to a stainless steel metal net in the flat plate type catalyst is reduced, and the influence on the qualityof the catalyst paste due to mixing of components in the metal net into the paste is reduced; the effect of removing fly ash and toxic ions adsorbed on the surface of the catalyst is obvious; and meanwhile, surface micropore clogging can be deeply removed, and the activity of the separated and recycled catalyst paste is guaranteed.

Description

technical field [0001] The invention belongs to the technical field of waste denitration catalysts, and in particular relates to a method for separating recycled aggregates from waste flat denitration catalysts. Background technique [0002] Nitrogen oxides (NOx) are one of the main pollutants in the atmospheric environment. 70% of nitrogen oxide emissions in my country come from coal-fired thermal power generation. Since my country tightened the emission standards of nitrogen oxides in coal-fired power plants in 2011, vanadium-titanium selective catalytic reduction denitrification technology has been widely used in the flue gas of coal-fired power plants in my country due to its high denitrification efficiency (up to 90%) and mature technology. During the denitrification process. The vanadium-titanium SCR denitration catalyst is the core of this technology, which has the characteristics of short life and toxic heavy metals. The frequent replacement of vanadium-titanium SCR...

Claims

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Application Information

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IPC IPC(8): B01J37/00B01J37/08
CPCB01J37/00B01J37/08
Inventor 卢作基姜树伟钟学进刘琪孙楠楠
Owner 南京碧林环保科技有限公司