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High-thermal-conductivity organosilicone gel sheet and preparation method thereof

A silicone gel sheet and high thermal conductivity technology, applied in the field of high thermal conductivity silicone gel sheet and its preparation, can solve the problems of insufficient strength, reduced thermal conductivity, increased production cost, etc., to ensure quality and performance stability, Efficient thermal conductivity and long service life

Active Publication Date: 2021-03-26
广德祥源新材科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, when commercially available products are prepared, the inorganic fillers used are often dispersed in the silicone oil or gel layer through mechanical dispersion. Due to the effect of gravity and electrostatic accumulation, the fillers are difficult to disperse evenly.
If used for a long time, it is prone to adverse phenomena such as reduced sheet strength, local hardening and cracking, stickiness, and uneven heat conduction.
As a result, the thermal conductivity is reduced, or even the thermal conductivity is lost.
[0004] On the other hand, commercially available silicone gel heat conduction sheet products have the problem of insufficient strength. In the process of electronic surface lamination and rework and repaste, the gel layer is easily broken or difficult to construct. It is used for a long time because the interface is mechanically squeezed. , the gel layer is easily broken
The conventional solution is to add MQ resin for reinforcement, or increase the content of thermally conductive fillers, which will cause problems such as spilled oil, small molecule residues, and increased production costs.

Method used

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  • High-thermal-conductivity organosilicone gel sheet and preparation method thereof

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preparation example Construction

[0052] The embodiment of the present invention also provides a method for preparing a high thermal conductivity silicone gel sheet, which is characterized in that it includes the following steps:

[0053] 1) Preparation of side chain polysiloxane containing silicon hydrogen group loaded with thermally conductive filler

[0054] 1.1) Pour the thermally conductive filler into toluene, stir under heating in an oil bath at 50°C to 80°C; then add side-chain vinyl polysiloxane coupling agent and stir; then add deionized water and stir to initiate side-chain vinyl polysiloxane The oxane coupling agent is hydrolyzed and coated on the surface of the thermally conductive filler; after the hydrolysis is completed, filter, and take the filtered particles of the side chain vinyl polysiloxane coupling agent coated with the thermally conductive filler, and wash them with deionized water and absolute ethanol in turn. Washing, and then placing the particles in a blast drying oven for blast dry...

Embodiment 1

[0067] The preparation of silicone gel sheet comprises the following specific steps:

[0068] 1) Preparation of side chain polysiloxane containing silicon hydrogen group loaded with thermally conductive filler

[0069] 1.1) Weigh 13g of thermally conductive filler, pour it into 100mL of toluene, heat it in an oil bath at 60°C, and stir it with a high-speed stirrer at a speed of 1200rpm / min for 3min; then add 10g of side chain vinyl polysiloxane coupling agent and stir 5min; then, add 1.8g of deionized water and stir for 8min to initiate the hydrolysis of the side chain vinyl polysiloxane coupling agent, thereby forming a coating on the surface of the thermally conductive filler. After the reaction, filter, and take the obtained side-chain vinyl polysiloxane-coated thermally conductive filler particles and wash them three times with 30 ml of deionized water, and then three times with 30 ml of ethanol. Subsequently, the particles were placed in a blast drying oven at 60° C. for...

Embodiment 2

[0082] The preparation of silicone gel sheet comprises the following specific steps:

[0083] 1) Preparation of side chain polysiloxane containing silicon hydrogen group loaded with thermally conductive filler

[0084] 1.1) Weigh 18g of thermally conductive filler, pour it into 100mL of toluene, heat it in an oil bath at 80°C, and stir it with a high-speed stirrer at a speed of 1000rpm / min for 5min; then add 10g of side chain vinyl polysiloxane coupling agent and stir 5min; then, add 1.8g of deionized water and stir for 10min to initiate the hydrolysis of the side chain vinyl polysiloxane coupling agent, thereby forming a coating on the surface of the thermally conductive filler. After the reaction, filter, and take the obtained side-chain vinyl polysiloxane-coated thermally conductive filler particles and wash them three times with 30 ml of deionized water, and then three times with 30 ml of ethanol. Then the particles were air-dried in a 70° C. air-drying oven for 12 hours....

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Abstract

The invention discloses a high-thermal-conductivity organosilicone gel sheet which comprises a substrate and a composition, the composition comprises a component A and a component B, the component A comprises vinyl-terminated polysiloxane, by weight, the component B comprises 10 to 20 parts of heat conduction filler, 3 to 10 parts of side chain vinyl polysiloxane coupling agent, 75 to 85 parts ofpolysiloxane with a side chain containing a silicon hydrogen group, 0.05 to 0.2 part of catalyst and 0.05 to 0.2 part of inhibitor; and the composition is formed on the substrate through coating, calendering and thermocuring in sequence. According to the high-thermal-conductivity organosilicone gel sheet, the heat conduction filler is uniformly distributed in the gel molecular grid and is fixed instructure, and the organosilicone gel sheet has efficient and uniform thermal conductivity, relatively long service life and relatively high strength, and is easy to strip, adhere, rework and re-adhere.

Description

technical field [0001] The invention belongs to the field of thermally conductive interface materials, and more specifically relates to a high thermally conductive silicone gel sheet and a preparation method thereof. Background technique [0002] Electronic components of electronic computers and smartphones, such as CPUs, integrated circuit packaging chips, lithium-ion polymer batteries, etc., often use radiators such as metal heat pipes and fans to conduct heat. In order to achieve a good fit between the radiator and the surface of the component, thermal interface materials such as thermal conductive silicone grease, silica gel sheet, and silicone gel sheet are often added between the two interfaces to assist in heat conduction. [0003] At present, when commercially available products are prepared, the inorganic fillers used are often dispersed in the silicone oil or gel layer through mechanical dispersion. Due to the effects of gravity and electrostatic accumulation, it i...

Claims

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Application Information

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IPC IPC(8): C08L83/05C08L83/07C08K9/10C08K9/12C08K3/22C08K3/04C08K7/06C08K3/14C08K3/34C08J5/18
CPCC08J5/18C08J2383/05C08J2483/07C08J2383/07C08J2483/05C08K9/10C08K9/12C08K2003/2227C08K2003/2224C08K3/04C08K3/042C08K3/041C08K7/06C08K3/14C08K3/34Y02E60/10
Inventor 方凯魏琼魏志祥
Owner 广德祥源新材科技有限公司