Manganese modified charcoal for reducing arsenic absorption of rice and application method thereof
A biochar, rice technology, applied in chemical instruments and methods, applications, fertilization devices, etc., can solve the problems of not providing a preparation method, and cannot effectively reduce the arsenic content of rice, so as to enhance the adsorption and fixation capacity, reduce the arsenic content of rice, The effect of high content of oxygen-containing functional groups
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Embodiment 1
[0039] The preparation method of the manganese-modified biochar that reduces rice arsenic absorption that the present embodiment provides, comprises the following steps:
[0040] (1) After crushing the chaff, place it in a vacuum box-type atmosphere furnace, fill it with nitrogen as a protective gas after vacuuming, raise the temperature to 600°C at a rate of 10°C per minute, and then carbonize it at a constant temperature for 2 hours, take it out after cooling, and crush it. Sieve (0.85mm aperture) to make biochar;
[0041] (2) Wash the biochar obtained in step (1) with deionized water to neutrality by suction filtration, and dry at 60° C. to obtain neutral biochar;
[0042] (3) Take 5 parts of neutral biochar prepared in step (2) and 1 part of potassium permanganate, put them in a crucible, add 40 parts of deionized water, mix them with ultrasonic waves for 2 hours, evaporate to dryness in a water bath at 95°C, and put Pyrolyze in a vacuum box-type atmosphere furnace at 600...
Embodiment 2
[0044] The present embodiment reduces the preparation method of the manganese-modified biochar that rice arsenic absorbs, comprises the following steps:
[0045] (1) After crushing the chaff, place it in a vacuum box-type atmosphere furnace, fill it with nitrogen as a protective gas after vacuuming, raise the temperature to 500°C at a rate of 10°C per minute, and then carbonize it at a constant temperature for 3 hours, take it out after cooling, and crush it. Sieve (0.85mm aperture) to make biochar;
[0046] (2) Wash the biochar obtained in step (1) with deionized water to neutrality by suction filtration, and dry at 80° C. to obtain neutral biochar;
[0047](3) Take 10 parts of neutral biochar prepared in step (2) and 1 part of potassium permanganate, put them in a crucible, add 120 parts of deionized water, mix with 40KHz ultrasonic frequency for 2.5h, and evaporate to dryness in a water bath at 80°C After that, put it into a vacuum box-type atmosphere furnace at 500°C unde...
Embodiment 3
[0049] The present embodiment reduces the preparation method of the manganese-modified biochar that rice arsenic absorbs, comprises the following steps:
[0050] (1) After crushing the chaff, put it in a vacuum box-type atmosphere furnace, fill it with nitrogen as a protective gas after vacuuming, carbonize at a constant temperature at 600°C for 3 hours, take it out after cooling, crush and sieve (0.85mm pore size), and obtain biological carbon;
[0051] (2) Wash the biochar obtained in step (1) with clear water to neutrality by suction filtration, and dry naturally to obtain neutral biochar;
[0052] (3) Take 5 parts of neutral biochar prepared in step (2) and 2 parts of potassium permanganate, put them in a crucible, add 40 parts of deionized water, mix with 120KHz ultrasonic frequency for 1.5h, and evaporate to dryness in a water bath at 90°C After that, put it into a vacuum box-type atmosphere furnace at 600°C under the protection of nitrogen for 0.4h of pyrolysis, and co...
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