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Binder with high adhesion performance for water-based ink

A technology of adhesion performance, water-based ink, applied in the direction of ink, application, household appliances, etc., can solve the problems of odor, volatile, color pattern damage, etc., to improve high temperature resistance, increase the degree of polymerization, and improve the effect of adhesion.

Pending Publication Date: 2021-04-20
岳若兰
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The ink is usually fixed by adding a binder during the preparation process. The printing ink applied to the surface of the can generally uses polyester resin as the binder, and the solvent used in it is organic, and the solvent is easy to volatilize during the printing and baking process , produces odor, and has certain toxicity, so it is imperative to develop a water-soluble binder, and the water-soluble binder can be dissolved in water, but at the same time, the performance of the water-soluble binder is unstable in high-temperature water, making Ink peels off easily, causing damage to color patterns

Method used

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  • Binder with high adhesion performance for water-based ink

Examples

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Effect test

Embodiment 1

[0050] A kind of preparation process of the binder for water-based ink with high adhesion performance is as follows:

[0051] In the first step, add 1kg of the above-mentioned double-ended keto-dibasic acid monomer, 920g of the above-mentioned prepared double-ended keto-dibasic alcohol monomer and 2g dibutyltin dilaurate to the reactor in a nitrogen atmosphere, Raise the temperature to 160°C and stir slowly, heat the reaction for 1 hour, then raise the temperature by 20°C every 2 hours until the temperature of the system rises to 220°C, then keep the temperature unchanged for 3 hours until the acid value of the system drops below 10mgKOH / g, then cool down to 130°C and add Diethylene glycol ether acetate, adjust the solid content of the product to be 30%, add acetone to it after cooling to room temperature, wherein the acetone addition is half of diethylene glycol ether acetate, then continue to cool down to 5 ° C Add 530g of methyl bromide, seal the reaction tank, raise the te...

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PUM

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Abstract

The invention discloses a binder with high adhesion performance for water-based ink. A preparation process of the binder comprises the following steps: adding water-soluble polyester resin and water into a reaction tank for dissolving, then adding a cross-linking adhesion enhancer and a sodium hydroxide solution, conducting reacting for 8-10 hours, conducting cooling, crystallizing and filtering, stirring and reacting the filter cake in a methanol solution at 40 DEG C for 1 hour, and then conducting cooling and rotary evaporation to obtain a primary binding material; and simultaneously adding the primary binding material, octanediamine, sodium hydroxide and water into a reaction tank, and conducting stirring, dissolving and reacting for 7-8 hours to obtain the water-soluble binder. According to the binder, the water-soluble polyester resin is used as a matrix, and quaternary ammonium salt groups are introduced into the water-soluble polyester resin, so that the binder can be well dissolved in water, and even if the water-soluble polyester resin is crosslinked for multiple times, although the polymerization degree of the water-soluble polyester resin is enhanced and hydrophobic alkyl is introduced into the water-soluble polyester resin, the prepared binder still can be dissolved in water at 50 DEG C, an organic solvent does not need to be additionally added and the environment-friendly performance is realized.

Description

technical field [0001] The invention belongs to the field of ink preparation and relates to a binder for water-based ink with high adhesion performance. Background technique [0002] The ink is usually fixed by adding a binder during the preparation process. The printing ink applied to the surface of the can generally uses polyester resin as the binder, and the solvent used in it is organic, and the solvent is easy to volatilize during the printing and baking process , produces odor, and has certain toxicity, so it is imperative to develop a water-soluble binder, and the water-soluble binder can be dissolved in water, but at the same time, the performance of the water-soluble binder is unstable in high-temperature water, making The ink is easy to peel off, causing damage to the color pattern. Contents of the invention [0003] The purpose of the present invention is to provide a binder for water-based ink with high adhesion performance. Re-crosslinking between the enhanc...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D11/104C08G63/91
Inventor 岳若兰李长鹏
Owner 岳若兰
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