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Dry desulfurization agent with good dispersibility and preparation method thereof

A technology of dry desulfurization and desulfurization agent, which is applied in the direction of separation methods, chemical instruments and methods, and separation of dispersed particles, can solve the problems of low efficiency of dry desulfurization agents, and achieve simple and easy desulfurization methods, low desulfurization temperature, and easy Handle the effect of regeneration

Pending Publication Date: 2021-04-30
安徽京科环境发展有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0006] In order to solve the problem of low efficiency of dry desulfurization agents in the prior art, the present invention provides a dry desulfurization agent with good dispersibility and a preparation method thereof. Activated carbon and magnesium oxide are added to the dry desulfurization agent to improve contact time so that the desulfurization efficiency is greatly increased

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  • Dry desulfurization agent with good dispersibility and preparation method thereof

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[0023] The invention provides a dry desulfurizing agent with good dispersibility and a preparation method thereof. The dry desulfurizing agent comprises the following components in weight percent: 30-50% of baking soda, 20-40% of adsorbent, 5-5% of magnesium oxide 25%, urea 5-8%, iron oxide 5-8%, talcum powder 0.5-2%. Preferably, the mass fraction of baking soda is 35-45%, the mass fraction of adsorbent is 25-35%, the mass fraction of magnesium oxide is 10-20%, the mass fraction of urea is 6-7%, and the mass fraction of iron oxide The mass fraction of talcum powder is 1-1.5%.

[0024] Wherein, the adsorbent can be one or more of activated carbon, activated coke or activated carbon fiber. The activated carbon component can be obtained by carbonizing or activating one or more of biomass semi-cokes such as sawdust and fruit shells, lignite and sub-bituminous coal semi-cokes, and petroleum coke activated coke. Activated carbon and magnesium oxide are added to the dry desulfurize...

Embodiment 1

[0033] A dry desulfurizer with good dispersibility, comprising the following components in weight percentage: 45.5% by mass of baking soda, 35% by mass of activated carbon, 5% by mass of magnesium oxide, and 7% by mass of urea %, the mass fraction of iron oxide is 6%, and the mass fraction of talcum powder is 1.5%.

[0034] The preparation method of above-mentioned dry method desulfurizer, comprises the steps:

[0035] Step 1: Coarsely grind baking soda, adsorbent, magnesium oxide, urea, iron oxide and talcum powder to 40-200 μm;

[0036] Step 2: Mix baking soda, adsorbent, magnesium oxide, urea, iron oxide and talcum powder according to the above ratio, and stir evenly;

[0037] Step 3: Finely grind the mixture obtained in Step 2 to ensure that each component is fully mixed and reacted, and sieve the mixture with a particle size of 10-40 μm, which is the desulfurizer. When the particle size is 20-30 μm, the desulfurization effect of the dry desulfurizer is better.

Embodiment 2

[0039] A dry desulfurizer with good dispersibility, comprising the following components by weight percentage: 50% by mass of baking soda, 25% by mass of activated carbon, 10% by mass of magnesium oxide, and 8% by mass of urea %, the mass fraction of iron oxide is 5%, and the mass fraction of talcum powder is 2%.

[0040] The preparation method of above-mentioned dry method desulfurizer, comprises the steps:

[0041]Step 1: Coarsely grind baking soda, adsorbent, magnesium oxide, urea, iron oxide and talcum powder to 40-200 μm;

[0042] Step 2: Mix baking soda, adsorbent, magnesium oxide, urea, iron oxide and talcum powder according to the above ratio, and stir evenly;

[0043] Step 3: Finely grind the mixture obtained in Step 2 to ensure that each component is fully mixed and reacted, and sieve the mixture with a particle size of 10-40 μm, which is the desulfurizer. When the particle size is 20-30 μm, the desulfurization effect of the dry desulfurizer is better.

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Abstract

The present invention particularly relates to a dry desulfurization agent with good dispersibility and a preparation method thereof. The dry desulfurization agent comprises the following components by weight: 30-50% of baking soda, 20-40% of an adsorbent, 5-25% of magnesium oxide, 5-8% of urea, 5-8% of iron oxide, and 0.5-2% of talc powder, wherein the adsorbent is one or more of active carbon, active coke or active carbon fiber. The preparation method of the dry desulfurization agent comprises the following steps: respectively carrying out coarse grinding on the raw materials, and grinding the raw materials to 40-200 [mu]m; mixing the raw materials in proportion, and performing uniform stirring; and carrying out fine grinding, and screening the mixture with the particle size of 10-40 [mu]m to obtain the desulfurization agent. The activated carbon and the magnesium oxide are added into the dry desulfurization agent, so that the contact time is prolonged, the desulfurization efficiency is greatly improved, the composition is simple, various components are cheap and easy to obtain, the preparation process is simple, and the industrial popularization and application are relatively strong.

Description

technical field [0001] The invention belongs to the technical field of environmental protection, and in particular relates to a dry desulfurizer with good dispersibility and a preparation method thereof. Background technique [0002] The current desulfurization methods are roughly divided into three categories: one is the wet method, that is, washing with a liquid absorbent such as water or alkaline solution; the other is the semi-dry method, which uses the sensible heat of the flue gas to evaporate the water in the lime slurry, and at the same time It reacts with SO2 to form dry powdered calcium sulfite, which has the characteristics of both wet and dry methods; the other is dry method, which uses powdery or granular absorbents, adsorbents or catalysts to remove SO2 in flue gas. Wet desulfurization technology is relatively mature and has a history of commercial application for decades, but there are complex processes, huge equipment, large land occupation, high infrastructu...

Claims

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Application Information

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IPC IPC(8): B01D53/81B01D53/50B01D53/56B01D53/60
CPCB01D53/508B01D53/565B01D53/60B01D53/81
Inventor 王中原李玲密赵德宽王建郭海宾
Owner 安徽京科环境发展有限公司