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Easy-to-clean mildew-proof PP composite material and preparation method thereof

A composite material and easy-to-clean technology, applied in the field of PP composite materials, can solve problems such as good antistatic and antibacterial properties, and unknown easy-to-clean effect

Active Publication Date: 2021-04-30
上海日之升科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Patent CN 103910997 A discloses "a permanent antistatic and antibacterial polyamide 6 / polypropylene composite material", which improves the antistatic performance and antibacterial performance of polyamide 6 / polypropylene alloy through permanent antistatic and antibacterial agents, and also The water absorption of PA6 and the wear resistance and heat resistance of PP are improved. The permanent antistatic and antibacterial polyamide 6 / polypropylene composite material prepared by this patent has good antistatic and antibacterial properties, but the effect of easy cleaning is unknown

Method used

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  • Easy-to-clean mildew-proof PP composite material and preparation method thereof
  • Easy-to-clean mildew-proof PP composite material and preparation method thereof
  • Easy-to-clean mildew-proof PP composite material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] A method for preparing an easy-to-clean anti-mold PP composite material, the specific process is as follows:

[0036] (1) Prepare raw materials by the following parts by weight:

[0037] 100 parts of PP resin;

[0038] MKC TM Silicate 8 parts;

[0039] 10 parts of water absorbent;

[0040] Zinc antifungal agent 0.5 parts;

[0041] High activity coupling dispersant YY-703 0.4 part;

[0042] 0.5 part of antioxidant;

[0043] Compatibilizer 3 parts.

[0044] Wherein, the water-absorbing agent is PA6 with a terminal amino group content of 55 mmol / kg.

[0045] The PP resin is a homopolymerized polypropylene resin with a melt index of 10g / 10min (230°C*2.16kg).

[0046] The compatibilizer is PP-g-MAH.

[0047] The active ingredient of the zinc-based antifungal agent is zinc pyrithione antifungal agent.

[0048] The antioxidant is a mixture of antioxidant 1010 and antioxidant 168 with a mass ratio of 1:1.

[0049] (2) According to the above parts by weight, add PP resi...

Embodiment 2

[0052] A method for preparing an easy-to-clean anti-mold PP composite material, the specific process is as follows:

[0053] (1) Prepare raw materials by the following parts by weight:

[0054] 100 parts of PP resin;

[0055] MKC TM Silicate 2 parts;

[0056] 50 parts of water absorbent;

[0057] Zinc antifungal agent 1 part;

[0058] High activity coupling dispersant YY-703 0.3 part;

[0059] Antioxidant 0.3 part;

[0060] 8 parts of compatibilizer.

[0061] Wherein, the water-absorbing agent is PA66 with a terminal amino group content of 50 mmol / kg.

[0062] The PP resin is a block copolymerized polypropylene resin with a melt index of 20g / 10min (230°C*2.16kg).

[0063] The compatibilizer is POE-g-MAH.

[0064] The active ingredient of the zinc-based antifungal agent is zinc pyrithione antifungal agent.

[0065] The antioxidant is a mixture of antioxidant 1010 and antioxidant 168 at a mass ratio of 2:1.

[0066] (2) Add PP resin, silicate oligomer, water-absorbing...

Embodiment 3

[0069] A method for preparing an easy-to-clean anti-mold PP composite material, the specific process is as follows:

[0070] (1) Prepare raw materials by the following parts by weight:

[0071] 100 parts of PP resin;

[0072] MKC TM Silicate 5 parts;

[0073] 15 parts of water absorbent;

[0074] Zinc antifungal agent 0.2 parts;

[0075] High activity coupling dispersant YY-703 0.2 parts;

[0076] Antioxidant 0.4 part;

[0077] 5 parts of compatibilizer.

[0078] Wherein, the water-absorbing agent is PA11 with a terminal amino group content of 54 mmol / kg.

[0079] The PP resin is a random copolymerized polypropylene resin with a melt index of 60g / 10min (230°C*2.16kg).

[0080] The compatibilizer is LLDPE-g-MAH.

[0081] The active ingredient of the zinc-based antifungal agent is zinc pyrithione antifungal agent.

[0082] The antioxidant is a mixture of antioxidant 1010 and antioxidant 168 at a mass ratio of 1:2.

[0083] (2) According to the above parts by weight, a...

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Abstract

The invention relates to an easy-to-clean mildew-proof PP composite material and a preparation method thereof. The method includes: adding PP resin, silicate oligomer, a water absorbent, a compatilizer, a mildew-proof aid, a compatibilizing dispersant and an antioxidant into a high-speed mixer, mixing for 6-10min at the speed of 240-500r / min to form a premix, and putting the mixed premix into a main feed port of a double-screw extruder for granulation, and preparing the easy-to-clean mildew-proof PP composite material. The water contact angle of the prepared easy-to-clean mildew-proof PP composite material is 65-80 degrees, and the mildew-proof grade is 0 grade. According to the invention, the silicate ester oligomer is easy to decompose to generate a silanol group after encountering water, and the silanol group migrates to the surface of the polypropylene composite material to greatly improve the hydrophilicity of the surface of the material, so that dust on the surface of the material is easier to wash away under the action of water, and an easy-to-clean effect is achieved.

Description

technical field [0001] The invention belongs to the technical field of PP composite materials, and relates to an easy-to-clean anti-mildew PP composite material and a preparation method thereof. Background technique [0002] Due to its non-toxicity, light weight, good chemical resistance, and excellent processing performance, polypropylene materials are gradually favored by the majority of automobiles, home appliances, smart homes, etc. Problems such as mold spots are generated, which limits its application in environments such as high humidity. [0003] At present, the research on the easy-to-clean and antibacterial and mildew-proof properties of polypropylene has been reported. Patent CN201710474610.9 discloses a high-performance antibacterial PP-PA6 composite material and its preparation method, using mica powder through polybutylacrylate (PBA) The grafting of PBA can form an organic coating layer of PBA on the surface of mica powder, which has a strong three-dimensional...

Claims

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Application Information

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IPC IPC(8): C08L23/12C08L23/14C08L53/00C08L77/02C08L77/06C08L83/02C08K13/06C08K9/12C08K5/378
CPCC08L23/12C08L23/14C08L53/00C08L2205/03C08L2205/035C08L77/02C08L83/02C08K9/12C08K5/378C08L77/06C08K13/06
Inventor 陈光伟侯江松阮静陈东詹鑫
Owner 上海日之升科技有限公司
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