Super-strong waterproof multifunctional composite fabric and manufacturing method thereof
A technology of composite fabrics and production methods, applied in the field of textile fabrics, can solve problems such as limited waterproof ability, inability to solve wearing comfort, and inability to satisfy multi-functionality, comfort, high strength, and softness at the same time, and achieve good moisture permeability , good weather resistance, super waterproof effect
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[0074] As an optional embodiment, the preparation method of polyurethane acrylate prepolymer comprises:
[0075] Vacuumize the reaction kettle to remove moisture, add diisocyanate, heat up, and stir;
[0076] The temperature in the reaction kettle rises to 50-150°C, and polyol is passed into the kettle, and the reaction is carried out for 10-180 minutes; the polyol is polyether-containing polyol or polyester polyol, and the molar ratio of diisocyanate to polyol is 2:1~8:1;
[0077] Add hydroxyalkyl acrylate or hydroxyalkyl methacrylate into the reaction kettle to completely react with unreacted isocyanate by hydroxyalkyl groups. The reaction temperature is maintained at 50-150°C, and the reaction is carried out for 10-180 minutes. The urethane acrylate prepolymer can be obtained; wherein, the molar number of added hydroxyalkyl acrylate or hydroxyalkyl methacrylate is greater than or equal to the molar number of unreacted isocyanate.
[0078] As an optional embodiment, in com...
Embodiment 1
[0101] High molecular weight polytetrafluoroethylene copolymer dispersion resin
[0102] It is prepared from tetrafluoroethylene and perfluoroethyl vinyl ether as polymerization monomers and ammonium sulfate as initiator. The preparation method includes: firstly add 500L of deionized water, 20Kg of high-purity paraffin wax with a melting point of 50°C to 85°C, and 180g of perfluorooctanoic acid ammonium in a horizontal high-pressure reactor with a volume of about 1,000 liters, and vacuum the inside of the kettle to exhaust oxygen. Heat up and stir until the oxygen content is less than 20ppm; when the temperature in the kettle rises to about 70°C, feed tetrafluoroethylene gas with a purity greater than 99.999% into the kettle to make the pressure in the kettle reach about 2.2MPa; then put 300g of tetrafluoroethylene gas with a purity greater than 98 % perfluoroethyl vinyl ether C 2 f 5 -OCF=CF 2 As a comonomer, it is added to the reactor at a rate of 10g / min, and at the same...
Embodiment 2
[0108] Referring to the method of Example 1, component A2 was prepared, wherein the ratio of fluorine-containing ion exchange resin to high molecular weight polytetrafluoroethylene copolymer was 5:100.
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