Electrolyte and lithium ion battery

A lithium-ion battery, electrolyte technology, applied in secondary batteries, secondary battery repair/maintenance, circuits, etc., can solve the problems of hindering the continued decomposition of solvents, low cycle efficiency, uneven film formation, etc., to suppress gas production, The effect of improving cycle performance and improving production efficiency

Active Publication Date: 2021-06-04
宁德国泰华荣新材料有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004]As an excellent negative electrode film-forming additive, vinylene carbonate decomposes to form a solid film layer on the surface of the negative electrode material prior to the electrolyte solvent, and this solid film can It effectively hinders the continued decomposition of the solvent on the surface of the material, so vinylene carbonate has the potential to inhibit gas pro...

Method used

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  • Electrolyte and lithium ion battery
  • Electrolyte and lithium ion battery

Examples

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Effect test

Embodiment 1

[0045] Lithium-ion battery electrolyte consists of: lithium hexafluorophosphate with a concentration of 1mol / L as lithium salt, a mixture of ethylene carbonate, ethyl methyl carbonate and dimethyl carbonate (1:1:1 by weight) as an organic solvent, additives It consists of vinylene carbonate, lithium bisoxalate borate, tris(trimethylsilane) phosphate, adiponitrile and succinonitrile in a weight ratio of 0.5:1:1:0.5:0.5.

Embodiment 2

[0047] Lithium-ion battery electrolyte consists of: lithium hexafluorophosphate with a concentration of 1mol / L as lithium salt, a mixture of ethylene carbonate, ethyl methyl carbonate and dimethyl carbonate (1:1:1 by weight) as an organic solvent, additives It is composed of vinylene carbonate, lithium bisoxalate borate, fluoroethylene carbonate, adiponitrile and succinonitrile in a weight ratio of 0.5:1:2:0.5:0.5.

Embodiment 3

[0049] Lithium-ion battery electrolyte consists of: lithium hexafluorophosphate with a concentration of 1mol / L as lithium salt, a mixture of ethylene carbonate, ethyl methyl carbonate and dimethyl carbonate (1:1:1 by weight) as an organic solvent, additives It consists of vinylene carbonate, lithium bisoxalate borate, tris(trimethylsilane) phosphate, fluoroethylene carbonate, adiponitrile and succinonitrile in a weight ratio of 0.5:1:1:2:0.5:0.5.

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Abstract

The invention relates to an electrolyte, and the electrolyte contains an organic solvent, a lithium salt and an additive;, the additive comprises a gas production inhibition additive, a negative electrode film-forming additive, a positive electrode film-forming additive and a low-impedance additive, and the gas production inhibition additive is vinylene carbonate; the negative electrode film-forming additive is fluoroethylene carbonate and/or tris (trimethylsilane) phosphite ester; the positive electrode film-forming additive is adiponitrile and/or butanedinitrile; the low-impedance additive is one or more of lithium bis (oxalato) borate, lithium difluoro (oxalato) borate, lithium difluoro (oxalato) phosphate and lithium tetrafluoro (oxalato) phosphate. Through the coordination effect of the additive, the gas production rate of the electrolyte in the pre-charging process can be effectively inhibited, the cycle performance of the battery at high temperature is improved, and the production efficiency of the lithium ion battery is improved.

Description

technical field [0001] The invention belongs to the technical field of lithium ion batteries, and in particular relates to an electrolyte and a lithium ion battery. Background technique [0002] Under the current situation that a large amount of non-renewable energy is consumed and environmental conditions continue to deteriorate, lithium-ion secondary batteries, as a green and sustainable new energy technology, are widely used in portable devices, electric vehicles and energy storage; in recent years, although lithium Ion secondary batteries have made significant progress in the field of high-energy batteries, but their energy density is still difficult to meet the growing needs of consumer products; there are generally two ways to increase the energy density of batteries: choosing materials with high capacity and high compaction density and increasing the working voltage of batteries way. [0003] Graphite materials are one of the most common anode materials for lithium-i...

Claims

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Application Information

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IPC IPC(8): H01M10/0567H01M10/42H01M10/0525
CPCH01M10/0567H01M10/4235H01M10/0525Y02E60/10
Inventor 刘春彦秦虎顾名遥甘朝伦赵世勇
Owner 宁德国泰华荣新材料有限公司
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