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Recycling device for hydrogen fluoride in tail gas of uranium dioxide hydrofluorination process

A uranium dioxide and chemical process technology, which is applied in the field of uranium conversion production, can solve problems such as difficulty in handling and dispose of secondary wastes of lime slag, and achieve the effects of being beneficial to environmental protection, improving economy, and reducing the amount of production

Pending Publication Date: 2021-08-10
THE 404 COMPANY LIMITED CHINA NAT NUCLEAR
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] At present, the tail gas treatment method of uranium conversion hydrofluorination process is treated by lime neutralization after condensation, which produces a large amount of lime slag secondary waste that is difficult to dispose of.

Method used

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  • Recycling device for hydrogen fluoride in tail gas of uranium dioxide hydrofluorination process
  • Recycling device for hydrogen fluoride in tail gas of uranium dioxide hydrofluorination process
  • Recycling device for hydrogen fluoride in tail gas of uranium dioxide hydrofluorination process

Examples

Experimental program
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Effect test

specific Embodiment approach 1

[0049] refer to figure 1 As shown, this embodiment provides a hydrogen fluoride reuse device in the tail gas of the uranium dioxide hydrofluorination process, including a feed hopper 1, a feed screw conveyor 2, a moving bed 3 and a discharge screw conveyor 4. The feeding screw conveyor 2 sends the material in the feeding hopper 1 into the moving bed 3 , and the discharging screw conveyor 4 discharges the material in the moving bed 3 .

[0050] In this example, according to the actual operation of the uranium dioxide hydrofluorination process in the field of uranium conversion production, the recovery of hydrogen fluoride in the tail gas of the uranium dioxide hydrofluorination process was carried out, and a test system for the recovery of hydrogen fluoride in the tail gas of the uranium dioxide hydrofluorination process was established. Applied in production practice, so as to realize the recovery and reuse rate of hydrogen fluoride in the tail gas of the hydrofluorination pro...

specific Embodiment approach 2

[0053] refer to figure 1 , figure 2 and Figure 4 As shown, this embodiment provides a hydrogen fluoride reuse device in the tail gas of the uranium dioxide hydrofluorination process, including a feed hopper 1, a feed screw conveyor 2, a moving bed 3 and a discharge screw conveyor 4. The feeding screw conveyor 2 sends the material in the feeding hopper 1 into the moving bed 3 , and the discharging screw conveyor 4 discharges the material in the moving bed 3 . Wherein the moving bed 3 is arranged in a vertical direction, and the top of the moving bed 3 is connected with a feeding screw conveyor 2, and the feeding screw conveyor 2 sends the material in the feeding hopper 1 into the moving bed 3, and the moving bed 3 The bottom of the bed is connected with a discharge screw conveyor 4, and the discharge screw conveyor 4 discharges the fully contacted uranium dioxide and hydrogen fluoride materials in the moving bed 3.

specific Embodiment approach 3

[0055] refer to figure 2 , image 3 As shown, a φ265mm inner hole and a 50mm high feed inlet are set in the center of the top of the feed hopper 1, and a DN40 exhaust gas outlet (with matching flange and bellows joint) is set on the side; a discharge port is set at the bottom of the feed hopper 1. mouth, the diameter of the discharge port of the feed hopper 1 is docked with the screw conveyor silo of the feed screw conveyor 2;

[0056] Feed screw conveyor 2 includes feed motor 23 (frequency conversion, local and remote control), coupling 24, bearing box 25, silo stirring shaft 26, stuffing box 27, screw conveying shaft 28, casing 29 And connect the spring box 30, the feed motor 23, the bearing box 25 and the stuffing box 27 are installed on the first base 32 in turn, and the screw conveying shaft 28 is installed in the bearing box 25, and the screw conveying shaft 28 is connected with the feeder through the coupling 24. The material motor 23 establishes the installation rel...

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Abstract

The invention discloses a recycling device for hydrogen fluoride in tail gas of a uranium dioxide hydrofluorination process, belongs to the technical field of uranium conversion production, and aims to improve the utilization rate of hydrogen fluoride in the tail gas of the hydrofluorination process and reduce the generation rate of fluorine-containing wastes in the preparation process of uranium tetrafluoride. The device comprises a feeding hopper, a feeding spiral conveyor, a moving bed and a discharging spiral conveyor, the feeding spiral conveyor feeds materials in the feeding hopper into the moving bed, and the discharging spiral conveyor discharges the materials in the moving bed. The uranium dioxide material is fed into the moving bed through the feeding spiral conveyor, and hydrogen fluoride in the tail gas of the uranium dioxide hydrofluorination process is introduced into the moving bed in a countercurrent manner so that the hydrogen fluoride is in full contact with uranium dioxide, and the absorption rate of the uranium dioxide and the hydrogen fluoride in the tail gas is increased.

Description

technical field [0001] The invention relates to a device for reusing hydrogen fluoride in tail gas of uranium dioxide hydrofluorination process, and belongs to the technical field of uranium conversion production. Background technique [0002] In the field of uranium conversion and energy production, in the production process of uranium tetrafluoride prepared by uranium dioxide hydrofluorination method, the measure of excess hydrogen fluoride is adopted to improve the utilization rate of metal uranium. An important indicator for testing the pros and cons of hydrofluorination (hydrofluorination refers to the process in which uranium dioxide reacts with anhydrous hydrogen fluoride to form uranium tetrafluoride) and equipment is: while obtaining high-quality uranium tetrafluoride products at high yields, , make full use of hydrogen fluoride. [0003] At present, there are mainly three types of hydrogen fluoride recovery devices: [0004] The first device is a distillation tow...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/68B01D53/83
CPCB01D53/685B01D53/83B01D2258/02B01D2251/602B01D2257/2047Y02C20/30
Inventor 马治军魏刚孙玉鹤薛彦成田红安武斌任先锋曹山黄灼升马礼平王多明强斌刘建车孙成龙张亚森
Owner THE 404 COMPANY LIMITED CHINA NAT NUCLEAR