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A method and product of sludge comprehensive disposal and phosphorus resource recovery

A phosphorus resource and sludge technology, applied in sludge treatment, water/sludge/sewage treatment, sludge treatment through temperature control, etc., can solve the problems of low phosphorus extraction efficiency and high energy consumption from sludge, and shorten production Cycle, optimization of reaction conditions, effects of avoiding obstruction

Active Publication Date: 2022-04-08
HUAZHONG UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] Aiming at the defects of the prior art, the object of the present invention is to provide a method and product for comprehensive sludge disposal and phosphorus resource recovery, aiming to solve the existing problems of low phosphorus extraction efficiency and high energy consumption from sludge

Method used

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  • A method and product of sludge comprehensive disposal and phosphorus resource recovery

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Comparison scheme
Effect test

Embodiment 1

[0044] Preparation of Phosphorus Accelerator: Select agricultural and forestry solid waste straw, bagasse, wood chips, bamboo materials and industrial grade cellulose and grind them into powder with a characteristic particle size below 150 mesh through a pulverizer. Prepare phosphorus accelerator A: straw powder, hemicellulose content 42%, cellulose content 44%; phosphorus accelerator B: mixture of straw powder and sawdust powder with a mass ratio of 1:3, hemicellulose content 20%, fiber Phosphorus accelerator C: a mixture of straw powder, bagasse powder and sawdust powder at a mass ratio of 1:2:2, with a hemicellulose content of 26% and a cellulose content of 20%; phosphorus accelerator D: cellulose powder , wood powder, bamboo powder mass ratio 3:1:3 mixture, hemicellulose content 37%, cellulose content 70%.

[0045] Phosphorus accelerator-assisted thermal hydrolysis treatment: Take municipal sludge with a moisture content of 99% and mix it with phosphorus accelerators A, B,...

Embodiment 2

[0055] Preparation of phosphorus accelerator: select bark, sawdust, and xylan and grind them into powders with a characteristic particle size below 250 mesh through a pulverizer. According to the bark, sawdust and xylan mass ratio of 4:1:3 mixed evenly to obtain a phosphorus accelerator with a hemicellulose content of 80% and a cellulose content of 23%.

[0056] Phosphorus accelerator assisted thermal hydrolysis treatment: Take oily sludge with a water content of 95% and mix it with phosphorus accelerator, the total dosage is 30% of the dry weight of the sludge, and stir evenly. Heat hydrolysis treatment at 60°C, 80°C, and 100°C for 20 minutes respectively to obtain thermally hydrolyzed sludge A, B, and C.

[0057] Cyclone separation: A solid-liquid cyclone separator with a rotating speed of 200r / min and a solid-solid cyclone separator with a rotating speed of 900r / min are used in sequence, and the combined separation takes 55 minutes to obtain sludge liquid phase, organic sol...

Embodiment 3

[0065] Preparation of phosphorus accelerator: select industrial-grade cellulose and wheat bran with a particle size of 250 mesh, and mix them uniformly at a mass ratio of 6:1 to obtain a phosphorus accelerator with a hemicellulose content of 10% and a cellulose content of 90%.

[0066] Thermal hydrolysis treatment: Take municipal sludge with a moisture content of 95%, and conduct thermal hydrolysis treatment at 120°C, 160°C, and 200°C for 25 minutes by electric heating to obtain thermally hydrolyzed sludge A, B, and C.

[0067] Cyclone separation: use a solid-liquid-gas three-phase cyclone separator to separate for 30 minutes at a speed of 1000r / min to obtain sludge liquid phase, organic solid phase, and inorganic solid phase.

[0068] The organic solid phase is dehydrated and heat-dried to obtain products I, II and III with low phosphorus and high organic matter.

[0069] Phosphorus leaching and purification of inorganic solid phase: Use 0.5M nitric acid to adjust the pH of t...

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Abstract

The invention provides a method and product for comprehensive disposal of sludge and recovery of phosphorus resources, belonging to the field of sludge treatment. The method comprises the following steps: adding a phosphorus accelerator to the sludge to be treated and performing thermal hydrolysis, so that organic phosphorus is converted into inorganic phosphorus, and then a thermal hydrolysis product is obtained, wherein the phosphorus accelerator is hemicellulose and / or contains hemicellulose Organic powder of cellulose; solid-liquid separation of thermal hydrolysis products to obtain liquid phase products, organic solid phase products and inorganic solid phase products; extraction and recovery of phosphorus in inorganic solid phase products to complete sludge comprehensive disposal and phosphorus resource recovery. The present invention can promote the conversion of total phosphorus to metal-complexed orthophosphate with higher thermal stability by coupling the phosphorus-accelerating agent with thermal hydrolysis conditioning, and unify the complex forms of phosphorus in the sludge into metal-bound inorganic orthophosphate. Furthermore, the dispersed phosphorus-containing compounds such as organic phosphorus are unified into the inorganic solid-phase product to realize the efficient recovery of phosphorus resources.

Description

technical field [0001] The invention belongs to the field of sludge treatment, and more specifically relates to a method and product for comprehensive sludge disposal and phosphorus resource recovery. Background technique [0002] Phosphorus participates in cell construction and bioenergy reactions, and is an indispensable nutrient element for all living organisms. However, because the natural phosphorus cycle is open-loop and the reserves of natural phosphate rock are limited, it faces the problem of shortage of phosphorus resources. In order to achieve a closed-loop phosphorus cycle, it is necessary to artificially recycle phosphorus from the sludge in the phosphorus cycle. Excluding the part lost into the ground with agricultural manure, more than 90% of the phosphorus in the natural phosphorus cycle is collected in animal manure and sewage sludge. Among them, sewage sludge is a by-product of sewage treatment, with a huge output and an average phosphorus content of 2.2%...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F11/00C02F11/18C02F101/10C02F101/30
CPCC02F11/00C02F11/18C02F2101/30C02F2101/105
Inventor 刘欢邓红苹金明灏肖涵汪家兴胡红云姚洪
Owner HUAZHONG UNIV OF SCI & TECH