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A kind of high strength and toughness magnesium alloy and preparation method thereof

A magnesium alloy, high-strength technology, applied in the field of magnesium alloys, can solve the problems of mismatch of strength and plasticity, description of mechanical properties of heat treatment process, less than 10%, etc., and achieve the effects of improved strength and toughness, small size, and improved strength.

Active Publication Date: 2022-06-28
CHINA WEAPON SCI ACADEMY NINGBO BRANCH +1
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The patent (CN105088038A) proposes a high thermal conductivity and corrosion-resistant Mg-1.5~6%Sm-0.001~1.2%Ca-0.5~3.0%Zn-0.3~2.5%Mn alloy, and its extrusion deformation process is: the ingot is cast in 350-420°C for 2-24h homogenization treatment, extrusion speed 0.1-6mm / s, extrusion ratio 14-30, water quenching after extrusion, but no heat treatment process after extrusion deformation and mechanics after extrusion deformation The performance is explained; Guan Kai et al obtained fine dynamic recrystallization grains (~0.47m) by extrusion of Mg-3.5Sm-0.6Zn-0.5Zr alloy, and after further T5 aging treatment, the yield of the alloy The strength reached ~416MPa, and the elongation was ~5.1%. The patent (CN111485453.A) proposed a deformed magnesium alloy containing neodymium, samarium, light rare earth elements and high Mn content and its preparation method. The mass composition ratio is: calcium: 0.3-1.9%; aluminum: 0.3-1.5%; zinc: 0.2-1.7%; manganese: 0.3-2.8%; light rare earth (neodymium or samarium): 0.3-3.0%, the material can The tensile strength reaches 368-435MPa, and the elongation is 4-13%, but the disadvantage of this alloy is that the elongation of the patented alloy is less than 10% when the tensile strength reaches above 390MPa, showing obvious Mismatch of strength and plasticity
[0005] At present, high strength and low elongation at break are common problems in high-strength wrought magnesium alloy materials, which greatly limits its application. Therefore, the development of high strength and high elongation at break is of great significance to promote the application of magnesium alloy materials.

Method used

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  • A kind of high strength and toughness magnesium alloy and preparation method thereof
  • A kind of high strength and toughness magnesium alloy and preparation method thereof
  • A kind of high strength and toughness magnesium alloy and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0031] The mass percentage composition of the high-strength and tough magnesium alloy in this embodiment is: Sm: 2.0%, Mn: 0.8%, Ca: 0.6%, Zn: 0.5%, and the balance is Mg and inevitable impurities.

[0032] The preparation of the high-strength and tough magnesium alloy of the present embodiment includes the following steps:

[0033] 1) Preparation of magnesium alloy cast rods:

[0034] a) According to the alloy composition of the magnesium alloy, calculate the respective weights of the required Mg ingots, Zn ingots, Mg-25Sm master alloys, Mg-10Mn master alloys, and Mg-25Ca master alloys, prepare the materials, and dry them at 300°C. time 1.5h;

[0035] b) in SF 6 +CO 2 Under gas protection, put the dried pure Mg ingot into a crucible that has been preheated to 550°C, and the furnace temperature rises to 730°C until Mg is completely melted;

[0036] c) at 730°C, add the dried pure Zn ingot and Mg-10Mn master alloy into the magnesium melt, and fully stir until melting;

[0...

Embodiment 2

[0045] The difference between Example 2 and Example 1 is that the casting speed of the semi-continuous ingot is 150mm / min, the cooling water flow rate is 90L / min, and the peeled cast rod and extrusion die are preheated in a resistance furnace at 270°C for 1.5h , the extruder is preheated to 270 ° C, the extrusion ratio is 16:1, and the extrusion deformed magnesium alloy extruded bar is annealed at 300 ° C for 15 minutes.

Embodiment 3

[0047] The difference between this example and Example 1 is that the mass percentage composition of the magnesium alloy is Sm: 1.7%, Mn: 0.8%, Ca: 0.5%, Zn: 0.5%, and the balance is Mg and inevitable impurities. After peeling The cast bar and extrusion die were preheated in a resistance furnace at 270°C for 2h, the extrusion speed was 1mm / s, and the extruded magnesium alloy extruded bar was annealed at 350°C for 15 minutes.

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Abstract

The invention discloses a high-strength and tough magnesium alloy, which is characterized in that the mass percentage composition of the magnesium alloy is Sm: 1.7wt%-2.5wt%, Mn: 0.4wt%-0.8wt%, Ca: 0.2wt%-0.6wt% %, Zn: 0.2wt% to 0.6wt%, the balance being Mg and unavoidable impurities. In the present invention, by controlling the addition amount of Sm, Mg, Zn, Ca, and Mn, on the one hand: the rare earth Sm forms a large amount of MgZnCaSm and MgZnSm nanophases with Mg, Zn, and Ca, and there are also a large amount of α-Mn nanophases in the alloy structure , these nanophases play the role of strengthening the magnesium matrix, improving the strength of the alloy, and the size of the nanophase is small, can be dispersed on the magnesium alloy matrix, has little effect on the elongation of the matrix, and can realize the tensile strength of the magnesium alloy The strength is 400MPa-450MPa, the yield strength is 390MPa-420MPa, and the elongation is above 15%.

Description

technical field [0001] The invention belongs to the technical field of magnesium alloys, and in particular relates to a high-strength and toughness magnesium alloy and a preparation method thereof. Background technique [0002] As the lightest metal structural material, magnesium alloy has a series of advantages such as low density, high specific strength, good thermal conductivity and excellent damping and shock absorption performance. It has a wide range of application prospects in aerospace, transportation and mobile communications. However, the strength of traditional magnesium alloys is not high, leading to some challenges in practical applications. At present, researchers mainly control the microstructure of magnesium alloys by alloying, plastic deformation and heat treatment, in order to obtain new magnesium alloys with excellent comprehensive mechanical properties, and then meet the needs of practical applications. [0003] Studies have shown that adding rare earth ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C23/06C22C1/03B21C23/04C22F1/06
CPCC22C23/06C22C1/03B21C23/04C22F1/06
Inventor 王军张景怀曹召勋何玉莹王茹张志谢金书徐永东朱秀荣
Owner CHINA WEAPON SCI ACADEMY NINGBO BRANCH
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