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High-thermal-conductivity semi-cured adhesive film of metal substrate and preparation method of high-thermal-conductivity semi-cured adhesive film

A metal substrate, semi-curing technology, used in adhesives, epoxy resins, film/sheet adhesives, etc., can solve the problems of easy embrittlement, easy tearing, accelerated embrittlement, etc. Thermal conductivity, strong crosslinking, effect of improving thermal conductivity and toughness

Active Publication Date: 2021-09-03
SHENZHEN CHUANGHUI ALLIANCE TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The high thermal conductivity semi-cured adhesive film is composed of resin that provides bonding and inorganic fillers with high thermal conductivity, etc. Therefore, it is possible to make it into an insulating and heat-dissipating adhesive layer for the substrate, but because the adhesive film has no support reinforcement materials, and most of the existing ones use epoxy resin as the main body. The glue is easier to tear after forming a film, and it is more prone to embrittlement after being placed for more than a week after the film is formed. The degree of embrittlement accelerates with the increase of temperature.

Method used

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  • High-thermal-conductivity semi-cured adhesive film of metal substrate and preparation method of high-thermal-conductivity semi-cured adhesive film

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] A high thermal conductivity prepreg film for a metal substrate, calculated in parts by weight, includes the following parts by weight:

[0042] 100 parts of epoxy resin, 20 parts of thermally conductive filler, 35 parts of curing agent and 6 parts of curing agent accelerator;

[0043] Wherein, the thermally conductive filler is modified boron nitride / tantalum disilicide microspheres.

[0044] Described epoxy resin is the mixture of bisphenol A type epoxy resin, naphthalene ring epoxy resin and biphenyl epoxy resin, the weight ratio of bisphenol A type epoxy resin, naphthalene ring epoxy resin and biphenyl epoxy resin 30:8:15.

[0045] The curing agent is methyl tetrahydrophthalic anhydride.

[0046] The curing agent accelerator is 2,4,6-tris(dimethylaminomethyl)phenol.

[0047] The thermally conductive filler is treated boron nitride, and the treatment method of boron nitride is:

[0048] Step 1, treating boron nitride with acid solution, and then grafting with zinc...

Embodiment 2

[0067] A high thermal conductivity prepreg film for a metal substrate, calculated in parts by weight, includes the following parts by weight:

[0068] 100 parts of epoxy resin, 16 parts of thermally conductive filler, 20 parts of curing agent and 3 parts of curing agent accelerator;

[0069] Wherein, the thermally conductive filler is modified boron nitride / tantalum disilicide microspheres.

[0070] Described epoxy resin is the mixture of bisphenol A type epoxy resin, naphthalene ring epoxy resin and biphenyl epoxy resin, the weight ratio of bisphenol A type epoxy resin, naphthalene ring epoxy resin and biphenyl epoxy resin It is 25:5:10.

[0071] The curing agent is dimer acid-based polyamide.

[0072] The curing agent accelerator is N,N-dimethylbenzylamine.

[0073] The thermally conductive filler is treated boron nitride, and the treatment method of boron nitride is:

[0074] Step 1, treating boron nitride with acid solution, and then grafting with zinc phenolsulfonate ...

Embodiment 3

[0094] A high thermal conductivity prepreg film for a metal substrate, calculated in parts by weight, includes the following parts by weight:

[0095]100 parts of epoxy resin, 24 parts of thermally conductive filler, 50 parts of curing agent and 9 parts of curing agent accelerator;

[0096] Wherein, the thermally conductive filler is modified boron nitride / tantalum disilicide microspheres.

[0097] Described epoxy resin is the mixture of bisphenol A type epoxy resin, naphthalene ring epoxy resin and biphenyl epoxy resin, the weight ratio of bisphenol A type epoxy resin, naphthalene ring epoxy resin and biphenyl epoxy resin It is 45:10:20.

[0098] The curing agent is 4,4-diaminodiphenyl sulfone.

[0099] The curing agent accelerator is N,N-dimethylbenzylamine.

[0100] The thermally conductive filler is treated boron nitride, and the treatment method of boron nitride is:

[0101] Step 1, treating boron nitride with acid solution, and then grafting with zinc phenolsulfonate...

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Abstract

The invention discloses a high-thermal-conductivity semi-cured adhesive film of a metal substrate, which is characterized by comprising the following components in parts by weight: 100 parts of epoxy resin, 16-24 parts of heat-conducting filler, 20-50 parts of a curing agent and 3-9 parts of a curing agent accelerator, wherein the heat-conducting filler is modified boron nitride / tantalum disilicide microspheres. The semi-cured adhesive film is obtained by mixing the epoxy resin and the heat-conducting filler and then curing the mixture through a curing agent, wherein the heat-conducting filler uses boron nitride as a base material, modification is carried out on the basis of boron nitride, then the modified boron nitride and tantalum disilicide are combined to form microspheres, functional groups on the surface of the modified boron nitride and tantalum disilicide can generate microspheres under the action of a salt template and polyvinyl alcohol, the formed microspheres have larger specific surface area and certain flexibility, and the mechanical properties and toughness of the epoxy resin can be enhanced while the thermal conductivity of the epoxy resin is improved.

Description

technical field [0001] The invention relates to the field of metal substrates, in particular to a high thermal conductivity semi-cured adhesive film of a metal substrate and a preparation method thereof. Background technique [0002] With the development of electronic products in the direction of light, thin, short, small, high-density and multi-functional, the assembly density and integration of components on the circuit board are getting higher and higher, and the heat dissipation requirements of the substrate are becoming more and more urgent. In the traditional circuit board structure, due to the small number and power consumption of electronic components inserted on it, the heat generated by the electronic components can be dissipated through the copper foil layer on the circuit board, and the heat can be dissipated directly into the air. Convection controls the temperature of electronic components. The electronic components of today's circuit boards have high power and...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J163/00C09J11/04C09J7/30
CPCC09J163/00C09J11/04C09J7/30C08K2003/385C08L2205/03C08L2205/025C09J2463/00C08L63/00C08K9/04C08K9/02C08K7/18C08K9/12C08K3/38C08K3/34
Inventor 何新荣吴国庆江奎魏翠唐剑
Owner SHENZHEN CHUANGHUI ALLIANCE TECH
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