Film-like adhesive, adhesive sheet and semiconductor device
A technology for semiconductors and adhesives, which is applied in the manufacture of film/sheet adhesives, semiconductor devices, semiconductor/solid-state devices, etc., and can solve problems such as inability to obtain sufficient HAST resistance, high probability, and electrical signal loss
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[0047] The solvent used in the preparation of the adhesive varnish is not limited as long as it can dissolve, knead or disperse the components uniformly, and conventionally known solvents can be used. Examples of such solvents include ketone solvents such as acetone, methyl ethyl ketone, methyl ethyl ketone, and cyclohexanone, dimethylformamide, dimethylacetamide, N-methyl-2- Pyrrolidone, toluene, xylene, etc. The solvent may be methyl ethyl ketone, cyclohexanone or the like from the viewpoint of fast drying speed and low price.
[0048] As a method of applying the adhesive varnish to the support film, a known method can be used, for example, a knife coating method, a roll coating method, a spray coating method, a gravure coating method, a bar coating method, a curtain coating method, etc. . The conditions of heat drying are not particularly limited as long as the solvent used can be sufficiently volatilized, and it can be performed by heating at 50 to 150° C. for 1 to 30 mi...
Embodiment 1、 Embodiment 2 and comparative example 1
[0089] [Production of film adhesive]
[0090]
[0091] The acrylic rubber solutions shown in Table 1 were used as adhesive varnishes. In addition, the numerical value shown in Table 1 means the mass part of the solid content of an acrylic rubber solution.
[0092] (A) Ingredient: Acrylic rubber
[0093] (A1) Acrylic rubber A: SG-P3 solvent-modified product (substance obtained by changing the solvent of SG-P3 (trade name, manufactured by Nagase Chemtex Corporation, methyl ethyl ketone solution of acrylic rubber)), derived from acrylonitrile Constituent unit: yes, weight average molecular weight: 700,000, measured Tg: 12°C, solvent: cyclohexanone
[0094] (A2) Acrylic rubber B: structural unit derived from acrylonitrile: yes, weight average molecular weight: 700,000, measured Tg: 22°C, solvent: cyclohexanone
[0095] (A3) Acrylic rubber C: structural unit derived from acrylonitrile: none, weight average molecular weight: 500,000, measured Tg: 20°C, solvent: cyclohexanone
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