Dried granules for catalyst production, catalyst, and compound production method

A technology for drying particles and catalysts, applied in the direction of preparation of organic compounds, carbon-based compounds, heterogeneous catalyst chemical elements, etc., to achieve the effect of cheap yield

Pending Publication Date: 2021-11-05
NIPPON KAYAKU CO LTD
View PDF4 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

As mentioned above, no research has been seen in the prior art to improve the total yield of unsaturated aldehydes and / or unsaturated carboxylic acids in the process of producing the corresponding unsaturated aldehydes and / or unsaturated carboxylic acids from olefins (hereinafter, described as "effective yield") itself, and even in the reaction under the condition of a high load, the reaction bath temperature is suppressed low and the effective yield that has been improved is stably produced

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Dried granules for catalyst production, catalyst, and compound production method
  • Dried granules for catalyst production, catalyst, and compound production method
  • Dried granules for catalyst production, catalyst, and compound production method

Examples

Experimental program
Comparison scheme
Effect test

manufacture example 1

[0128] 800 parts by weight of ammonium heptamolybdate tetrahydrate was completely dissolved in 3040 parts by weight of pure water heated to 60°C. Next, 5.59 parts by weight of potassium nitrate was dissolved in 55 mL of pure water, and added to the above solution. Next, 274.6 parts by weight of iron nitrate nonahydrate, 571.5 parts by weight of cobalt nitrate hexahydrate, and 307.4 parts by weight of nickel nitrate hexahydrate were dissolved in 611 mL of pure water heated to 60°C. These solutions were mixed slowly while stirring. Next, 311.4 parts by weight of bismuth nitrate was added to an aqueous solution of nitric acid obtained by adding 79.3 parts by weight of nitric acid (60% by weight) to 330 mL of pure water, and the solution obtained by completely dissolving it was added to the above solution and carried out. Stir to combine. The slurry was dried by disc spray drying, and the obtained dry powder was precalcined while maintaining the maximum temperature of 440° C. fo...

manufacture example 2

[0134] 800 parts by weight of ammonium heptamolybdate tetrahydrate was completely dissolved in 3040 parts by weight of pure water heated to 60°C. Next, 11.0 parts by weight of cesium nitrate was dissolved in 100 mL of pure water, and added to the above solution. Next, 259.3 parts by weight of iron nitrate nonahydrate, 791.3 parts by weight of cobalt nitrate hexahydrate, and 109.8 parts by weight of nickel nitrate hexahydrate were dissolved in 615 mL of pure water heated to 60°C. These solutions were mixed slowly while stirring. Next, 311.4 parts by weight of bismuth nitrate was added to an aqueous solution of nitric acid obtained by adding 79.3 parts by weight of nitric acid (60% by weight) to 330 mL of pure water, and the solution obtained by completely dissolving it was added to the above solution and carried out. Stir to combine. The slurry was dried by disc spray drying, and the obtained dry powder was precalcined while maintaining the maximum temperature of 440° C. for ...

manufacture example 3

[0140] 800 parts by weight of ammonium heptamolybdate tetrahydrate was completely dissolved in 3040 parts by weight of pure water heated to 60°C. Next, 11.0 parts by weight of cesium nitrate was dissolved in 100 mL of pure water, and added to the above solution. Next, 259.3 parts by weight of iron nitrate nonahydrate, 769.3 parts by weight of cobalt nitrate hexahydrate, and 109.8 parts by weight of nickel nitrate hexahydrate were dissolved in 615 mL of pure water heated to 60°C. These solutions were mixed slowly while stirring. Next, 274.8 parts by weight of bismuth nitrate was added to an aqueous solution of nitric acid obtained by adding 70.0 parts by weight of nitric acid (60% by weight) to 300 mL of pure water, and the solution obtained by completely dissolving it was added to the above solution and carried out. Stir to combine. The slurry was dried by disc spray drying, and the obtained dry powder was precalcined while maintaining the maximum temperature of 440° C. for ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
particle diameteraaaaaaaaaa
particle diameteraaaaaaaaaa
particle sizeaaaaaaaaaa
Login to view more

Abstract

A catalyst, wherein when a scanning electron microscope (SEM) with an accelerating voltage of 15 kV is used to obtain an SEM image of the catalyst at a magnification such that the maximum length of one particle in the vertical direction in the SEM image occupies 90% or more of the vertical length of the SEM image and the maximum length of one particle in the horizontal direction in the SEM image occupies 90% or more of the horizontal length of the SEM image, the concentration of bismuth (Bi) in white areas when the SEM image is binarized into black and white is larger than the value obtained by adding 2.5 times the value of the standard deviation [sigma]1 of the Bi concentration in the black areas to the Bi concentration in the black areas.

Description

technical field [0001] The present invention relates to a novel catalyst capable of obtaining a target product with high activity and a high yield, and particularly relates to a catalyst capable of being stable even in a region where the catalyst activity is high when producing an unsaturated aldehyde, an unsaturated carboxylic acid, or a conjugated diene by oxidation. A catalyst and a method for producing the same can be produced with a high yield. Background technique [0002] Methods for producing corresponding unsaturated aldehydes and unsaturated carboxylic acids using propylene, isobutene, t-butanol, etc. as raw materials, and gas-phase catalytic oxidation methods for producing 1,3-butadiene from butenes are widely practiced industrially. In particular, many reports have been made on methods of producing corresponding unsaturated aldehydes and unsaturated carboxylic acids using propylene, isobutylene, tert-butanol, etc. as raw materials as means to increase their yield...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/887C01G53/00C07B61/00C07C45/35C07C47/22C07C51/25C07C57/05
CPCB01J23/887C07C45/35B01J23/18B01J2523/00B01J35/023C07C51/252C01P2004/61C01P2004/62C01P2004/03C01G53/40C01P2004/60C01P2004/32B01J35/002B01J35/026B01J37/0045B01J37/0072B01J37/038B01J35/08B01J37/0221B01J37/0219B01J37/088B01J23/883B01J27/192B01J35/0066B01J2523/13B01J2523/54B01J2523/68B01J2523/842B01J2523/845B01J2523/847B01J2523/15C07C47/22C07C57/04
Inventor 平冈良太福永诚一郎
Owner NIPPON KAYAKU CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products