Preparation method of mushroom bran-doped sludge-based biochar

A technology of biochar and sludge, applied in chemical instruments and methods, water/sludge/sewage treatment, water/sewage treatment, etc., to save cost and improve quality

Pending Publication Date: 2021-11-16
SHENYANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The purpose of the present invention is to provide a method for preparing sludge-based biochar doped with fungus chaff, so as to solve the problems of reduction, recycling and harmless treatment of excess sludge and agricultural waste in sewage treatment plants, And obtained a sludge-based biochar adsorption material with excellent performance

Method used

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  • Preparation method of mushroom bran-doped sludge-based biochar
  • Preparation method of mushroom bran-doped sludge-based biochar
  • Preparation method of mushroom bran-doped sludge-based biochar

Examples

Experimental program
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Effect test

Embodiment 1

[0028] Air-dried the sludge and fungus chaff respectively, put them into a pulverizer and crushed them through a 60-mesh sieve, mixed them according to the proportion of sludge accounting for 50% of the total amount of sludge and fungus chaff, put them into a muffle furnace, and pyrolyzed them at 500°C for 4 hours , to obtain sludge-bacteria chaff composite biochar samples.

[0029] The yield of the biochar sample prepared by the steps of this example is 53.55%; the methylene blue adsorption value is 25.17mg / g; the adsorption rate is 83.90%. figure 1 The SEM image of the biochar sample prepared in this example is provided, and it can be seen from the figure that the biochar presents a regular long tube-like porous structure, and the pore structure is rich, clear and relatively developed.

Embodiment 2

[0031] Air-dried the sludge and fungus chaff respectively, put them into a pulverizer and crushed them through a 60-mesh sieve, mixed them according to the proportion of sludge accounting for 50% of the total amount of sludge and fungus chaff, put them into a muffle furnace, and pyrolyzed them at 600°C for 2 hours , to obtain sludge-bacteria chaff composite biochar samples.

[0032] The yield of the biochar sample prepared by the steps of this example is 53.65%; the methylene blue adsorption value is 23.12mg / g; the adsorption rate is 77.07%. figure 2 The SEM image of the biochar sample prepared in this example is provided. From the figure, it can be seen that the surface of the biochar is relatively rough, with a relatively obvious graininess, a thin sheet structure, a large pore size, and the overall appearance is looser and more wrinkled. many.

Embodiment 3

[0034] Air-dry the sludge and fungus chaff respectively, put them into a pulverizer and crush them through a 60-mesh sieve, mix them evenly according to the proportion that the sludge accounts for 50% of the total amount of sludge and fungus chaff, put them in a muffle furnace, and pyrolyze them at 700°C After 2 hours, the sludge-bacteria chaff composite biochar sample was obtained.

[0035] The yield of the biochar sample prepared by the steps of this example is 51.6%; the methylene blue adsorption value is 22.04mg / g; the adsorption rate is 73.47%. image 3 The SEM image of the biochar sample prepared in this example is provided. It can be seen from the image that the surface of the biochar is very rough, with a relatively obvious grainy feel, and the pores are distributed in disorder, showing an irregular pinhole structure with different sizes.

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Abstract

The invention relates to the field of research, development and application of environmental remediation materials, and discloses a preparation method of mushroom bran-doped sludge-based biochar, which comprises the following process steps: respectively and naturally air-drying sludge and mushroom bran; respectively putting the air-dried sludge and mushroom bran into a crusher, crushing, and sieving with a 60-mesh sieve; uniformly mixing the sludge and the mushroom bran; and putting the sludge and the mushroom bran into a muffle furnace according to a certain raw material ratio, and pyrolyzing for a certain time under a certain temperature condition to obtain the sludge-mushroom bran composite biochar. The yield of the biochar is 51-60%, the methylene blue adsorption value is 18-25 mg / g, and the adsorption rate is 61-84%. The sludge-mushroom residue composite biochar adsorption material is developed by taking two solid wastes, namely dewatered sludge of an urban sewage treatment plant and mushroom residue of an edible mushroom production waste material, as raw materials and adopting an oxygen-limited pyrolysis technology, so that the cost can be saved, the quality of sludge carbon can be improved, and a new material is provided for environmental remediation and treatment; and reduction, recycling and innocent treatment of the two can be realized.

Description

technical field [0001] The invention relates to the field of research and development and application of environmental restoration materials, in particular to a method for preparing sludge-based biochar doped with bacterial chaff. Background technique [0002] In recent years, with the acceleration of the urbanization process and the improvement of the level of industrialization, people have produced a large amount of domestic and industrial sewage in their production and life. The Chinese government has continuously strengthened environmental protection, and the urban sewage treatment rate has continued to increase. The urban sewage treatment plant The amount of excess sludge discharged has also increased rapidly. [0003] The composition of sludge is complex and changeable. In addition to being rich in nitrogen, phosphorus, potassium, and various nutrients and trace elements, it may also be concentrated in cadmium (Cd), lead (Pb), copper (Cu), and zinc (Zn). , nickel (Ni)...

Claims

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Application Information

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Patent Type & AuthorityApplications(China)
IPC IPC(8): B01J20/20B01J20/30C02F1/28
CPCB01J20/20C02F1/283B01J2220/4887B01J2220/4875
Inventor李玉双徐硕魏建兵侯永侠宋雪英杨嘉鑫
OwnerSHENYANG UNIV