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Iron-loaded activated carbon capable of synchronously and efficiently removing As (III) and Cr (VI) in water, and preparation method and application thereof

A technology for iron-loaded activated carbon and water removal, applied in chemical instruments and methods, water pollutants, and other chemical processes, etc., can solve problems such as blockage of pipelines or equipment in structures, large head loss, and difficulty in solid-liquid separation, and achieve carbon loss. The effect of small rate, optimized adsorption efficiency and low cost

Pending Publication Date: 2021-11-23
ANHUI UNIVERSITY OF TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to innovatively load the in-situ-generated iron oxide onto the surface of activated carbon and its interior, and solve the problem that the extremely fine hydrated iron oxide particle size in the adsorption method leads to excessive head loss in practical applications , solid-liquid separation is difficult, and it is easy to cause blockage of structure pipelines or equipment, which limits its industrial application. A kind of iron-loaded activated carbon, preparation method and application of synchronous and efficient removal of As(III) and Cr(VI) in water are provided.

Method used

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  • Iron-loaded activated carbon capable of synchronously and efficiently removing As (III) and Cr (VI) in water, and preparation method and application thereof
  • Iron-loaded activated carbon capable of synchronously and efficiently removing As (III) and Cr (VI) in water, and preparation method and application thereof
  • Iron-loaded activated carbon capable of synchronously and efficiently removing As (III) and Cr (VI) in water, and preparation method and application thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0024] (1) Select the activated carbon whose purity is analytically pure, the particle size is about 200 mesh, the iodine value is 1000mg / g; the methylene blue value is 120mg / g; the particle size exceeds 200 mesh, accounting for 90%; the moisture content is 10%, and the ash content is 9%. pink. Clean the activated carbon powder with ultra-pure water for more than 3 times at room temperature, fully stir and soak during the cleaning process to reduce its alkalinity, remove the ash and impurities on the surface of the activated carbon powder, and place the cleaned activated carbon powder in a vacuum at 60°C after filtering Dry it in a drying oven for 10 hours, and record the sample PAC after grinding as the first sample, and set it aside;

[0025] (2) At room temperature, take about 10 g of activated carbon powder PAC obtained in step (1), use dilute nitric acid with a concentration of 0.1 mol / L and a pH of about 1, and fully impregnate it for 24 hours under the condition of unif...

Embodiment 2

[0030] (1) Select the activated carbon whose purity is analytically pure, the particle size is about 200 mesh, the iodine value is 1000mg / g; the methylene blue value is 120mg / g; the particle size exceeds 200 mesh, accounting for 90%; the moisture content is 10%, and the ash content is 9%. pink. Clean the activated carbon powder with ultra-pure water for more than 3 times at room temperature, fully stir and soak during the cleaning process to reduce its alkalinity, remove the ash and impurities on the surface of the activated carbon powder, and place the cleaned activated carbon powder in a vacuum at 60°C after filtering Dry it in a drying oven for 10 hours, and record the sample PAC after grinding as the first sample, and set it aside;

[0031] (2) Under normal temperature, get about 10g of activated carbon powder PAC obtained in the step (1), with a concentration of 0.1mol / L, a dilute nitric acid with a pH of about 1, fully impregnated for 24h under 100r / min mechanical unifor...

Embodiment 3

[0036] (1) Select the activated carbon whose purity is analytically pure, the particle size is about 200 mesh, the iodine value is 1000mg / g; the methylene blue value is 120mg / g; the particle size exceeds 200 mesh, accounting for 90%; the moisture content is 10%, and the ash content is 9%. pink. Clean the activated carbon powder with ultra-pure water for more than 3 times at room temperature, fully stir and soak during the cleaning process to reduce its alkalinity, remove the ash and impurities on the surface of the activated carbon powder, and place the cleaned activated carbon powder in a vacuum at 60°C after filtering Dry it in a drying oven for 10 hours, and record the sample PAC after grinding as the first sample, and set it aside;

[0037] (2) At room temperature, take about 10 g of activated carbon powder PAC obtained in step (1), use dilute nitric acid with a concentration of 0.1 mol / L and a pH of about 1, and fully impregnate it for 24 hours under the condition of unif...

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Abstract

The invention relates to the technical field of water treatment, and concretely relates to an iron-loaded activated carbon capable of synchronously and efficiently removing As (III) and Cr (VI) in water, and a preparation method and application thereof. A constant-temperature infiltration method is adopted, proper activated carbon powder is selected as a raw material, and the iron-loaded activated carbon is prepared by the following steps: pretreating with dilute nitric acid, fully impregnating with an iron salt solution for 12 hours, adding a certain amount of a potassium ferrate buffer solution, continuously oscillating for 12 hours, carrying out solid-liquid separation, cleaning the obtained solid, curing at a proper temperature, grinding, and creatively generating rich iron oxide on the surface and inside of the activated carbon in situ through chemical reaction of iron salts with different valence states in the activated carbon modified iron loading process. The As (III) and Cr (VI) removal effect is substantially improved, the As (III) and Cr (VI) can be repeatedly used after the recovery treatment, the synchronous and efficient removal of As (III) and Cr (VI) can be improved, and the problems of large head loss, difficult solid-liquid separation, easy building pipeline or equipment blockage, and industrial application limitationin the practical application due to the extremely fine particle size of the active carbon in the adsorption method, can be solved.

Description

technical field [0001] The invention relates to the technical field of water treatment, in particular to an iron-loaded activated carbon for synchronously and efficiently removing As(III) and Cr(VI) in water, a preparation method and an application thereof. Background technique [0002] Arsenic and arsenic compounds (As) are carcinogens recognized by many authoritative organizations. Long-term exposure to and drinking water with excessive arsenic will cause various acute and chronic poisonings, and even face the risk of skin cancer, bladder cancer and other diseases. Arsenic in source water generally exists in two valence states of trivalent arsenic As(III) and pentavalent arsenic As(V), among which As(III) is about 60 times more toxic than As(V). The main sources of chromium (Cr) wastewater include leather tanning, electroplating, textile printing and dyeing, atomic power plants, metallurgical mining and many other industrial industries. Cr mostly exists in the state of ox...

Claims

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Application Information

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IPC IPC(8): B01J20/20B01J20/30C02F1/28C02F101/10C02F101/22
CPCB01J20/20B01J20/06C02F1/283C02F1/281C02F2101/103C02F2101/22
Inventor 孔艳丽黄智研马雅倩储航宇马江雅丁磊陈昊刘甜
Owner ANHUI UNIVERSITY OF TECHNOLOGY