Epoxysilane-modified nano-alumina and polymer cement-based waterproof coatings
A nano-alumina, epoxy silane technology, applied in cement coatings, dyed organosilicon compound treatment, coatings, etc., can solve the problem of uneven dispersion of polymer cement-based waterproof coatings, easy hydrolysis and self-polymerization failure nano-alumina, Easy phase separation and other problems, to achieve the effect of improving mechanical properties and chemical resistance, low cost, and enhancing adhesion
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Embodiment 1
[0120] This embodiment provides an epoxy silane-modified nano-alumina. The specific preparation method is as follows: in a 100ml beaker, add 30ml of a mixed solution of absolute ethanol and deionized water (the mass ratio of ethanol to water is 9:1), and then Weigh 0.4 g of epoxysilane into the solution, adjust the pH value to 3.8 with dilute hydrochloric acid, and stand at (23±2)° C. for 45 min. In a 1L three-necked flask, add 150mL of a mixed solution of absolute ethanol and deionized water (the mass ratio of ethanol and water is 9:1), connect a reflux condenser, and slowly add 20g of nano-alumina while stirring. At this time, the stirring speed is controlled at 120r / min, the temperature is controlled at 25 ℃, so that the nano-alumina is fully dispersed in the solution. After uniform dispersion, the stirring rate was increased to 200 r / min, the temperature was increased to 85 °C, the above epoxysilane solution was added, and then the pH was adjusted to 3.8 with dilute hydroc...
Embodiment 2
[0122] This embodiment provides an epoxy silane-modified nano-alumina, which is different from Example 1 in that the amount of epoxy silane added is 0.8 g, and the rest of the methods and steps are the same as those in Example 1, which will not be repeated here. .
Embodiment 3
[0124] This embodiment provides an epoxy silane-modified nano-alumina, which is different from Embodiment 1 in that the amount of epoxy silane added is 1.2 g, and the rest of the methods and steps are the same as those in Embodiment 1, which will not be repeated here. .
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