Electrochemiluminescence sensor for detecting synthetic cannabinoid RCS-4 as well as preparation method and applying of electrochemical luminescence sensor
An RCS-4, electrochemical technology, applied in the direction of chemiluminescence/bioluminescence, electrochemical variables of materials, analysis by making materials undergo chemical reactions, etc., to achieve the effect of simple operation, good selectivity and high sensitivity
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Embodiment 1
[0033] (1) Assembly of PTCD-cys / Au-ZIF-67 / GCE sensor
[0034] (1) Preparation of PTCD-cys and Au-ZIF-67 materials:
[0035] Accurately weigh 0.0716g of perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA), 0.1602g of L-cysteine (L-cys) and 6.0034g of imidazole in a three-necked flask, under argon Heated at 100°C for 6h under gas protection. The reaction mixture was cooled to room temperature and dispersed in 25 mL of ethanol, then 125 mL of hydrochloric acid solution (1M) was added. The mixture was stirred overnight. The resulting red solid was filtered and washed with water until the filtrate became neutral. The filter cake was vacuum-dried, and the resulting red solid was PTCD-cys, which was stored at 4°C.
[0036] Accurately weigh 0.2912g Co(NO 3 ) 2 ·6H 2 O and 0.6608 g of 2-methylimidazole were dissolved in 30 mL of methanol. After stirring at room temperature for 24 h, it was centrifuged and washed with methanol three times, and dried in vacuum at 80° C. for 4...
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