Novel high-temperature dechlorinating agent and preparation method thereof

A technology of dechlorination agent and dechlorination method, which is applied in separation methods, chemical instruments and methods, gas treatment, etc., can solve the problems of reforming catalyst hazards, unsatisfactory use, loss of active components, etc., and improve the use effect , reduce the effect of rapid loss and reduce usage

Pending Publication Date: 2022-01-07
昆山市精细化工研究所有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In order to solve the problems caused by the above dechlorination methods, a high-temperature dechlorination agent can be used to dechlorinate the regenerated flue gas. However, the dechlorination agents used at home and abroad are generally concentrated in the normal temperature or low temperature range, which leads to , its effect is poor and cannot meet the needs of use, and the performance of the active component is also a key factor determining the life of the dechlorination agent, and the loss of the active component of the current dechlorination agent will cause harm and influence on the reforming catalyst

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] The invention provides a novel high-temperature dechlorination agent, which is packed in a fixed-bed reactor, and the hydrogen chloride in the regenerated flue gas is purified and removed by a solid dechlorination method, and the dechlorination agent is composed of an active group component, carrier, pore forming agent, binder and reinforcing agent, and the parts by weight of each component are: 30 parts of active component, 20 parts of binder, 10 parts of carrier, 5 parts of pore forming agent and Enhancer 2 parts.

[0022] Specifically, the active components are ZnO, MnO 2 and CaO, and the mass ratio between them is 1:1:2.

[0023] Specifically, the binder is silicate, phosphate, dextrin and clay, and the mass ratio between silicate, phosphate, dextrin and clay is: 1:1:1:1.

[0024] Specifically, the carrier is silicon carbide, silicon emulsion, silicon surfactant and Al 2 o 3 , and silicon carbide, silicon emulsion, silicon surfactant and Al 2 o 3 The mass rati...

Embodiment 2

[0035] The invention provides a novel high-temperature dechlorination agent, which is packed in a fixed-bed reactor, and the hydrogen chloride in the regenerated flue gas is purified and removed by a solid dechlorination method, and the dechlorination agent is composed of an active group component, carrier, pore forming agent, binder and reinforcing agent, and the parts by weight of each component are: 42.5 parts of active component, 25 parts of binder, 13 parts of carrier, 8 parts of pore forming agent and reinforcing agent 3.5 servings.

[0036] Specifically, the active components are ZnO, CaCO 3 and Ca(HCO 3 ) 2 Three combinations, and the mass ratio among them is 1:1:2.

[0037] Specifically, the binder is silicate, phosphate, dextrin and clay, and the mass ratio between silicate, phosphate, dextrin and clay is: 2:2:1:1.

[0038] Specifically, the carrier is silicon carbide, silicon emulsion, silicon surfactant and Al 2 o 3 , and silicon carbide, silicon emulsion, si...

Embodiment 3

[0049] The invention provides a novel high-temperature dechlorination agent, which is packed in a fixed-bed reactor, and the hydrogen chloride in the regenerated flue gas is purified and removed by a solid dechlorination method, and the dechlorination agent is composed of an active group component, carrier, pore forming agent, binder and reinforcing agent, and the parts by weight of each component are: 55 parts of active component, 30 parts of binder, 15 parts of carrier, 10 parts of pore forming agent and reinforcing agent 5 servings.

[0050] Specifically, the active components are ZnO, CaCO 3 , Ca(HCO 3 ) 2 and Ca(OH) 2 Combination, and the mass ratio between them is 1:1:2.

[0051] Specifically, the binder is silicate, phosphate, dextrin and clay, and the mass ratio between silicate, phosphate, dextrin and clay is: 3:3:1:1.

[0052] Specifically, the carrier is silicon carbide, silicon emulsion, silicon surfactant and Al 2 o 3 , and silicon carbide, silicon emulsion...

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Abstract

The invention discloses a novel high-temperature dechlorinating agent and a preparation method thereof. The dechlorinating agent is filled in a fixed bed reactor, hydrogen chloride in regenerated flue gas is purified and removed through a solid dechlorinating method, and the dechlorinating agent is composed of an active component, a carrier, a pore-forming agent, a binder and a reinforcing agent, and specifically comprises the following components in parts by weight: 30-55 parts of the active component, 20-30 parts of the binder, 10-15 parts of the carrier, 5-10 parts of the pore-forming agent and 2-5 parts of the reinforcing agent. Through the use of the carrier and the binder, the prepared high-temperature dechlorinating agent has relatively high strength, relatively high water resistance, relatively high argillization resistance, relatively high temperature resistance, relatively high oxygen resistance and relatively high CO2 carbonation resistance; the penetrating chlorine capacity of the high-temperature dechlorinating agent reaches 40%, rapid loss of active components during use of the dechlorinating agent is reduced, harm and influence of loss of the active components of the dechlorinating agent on production of a reforming catalyst are reduced, and the dechlorinating agent which is stable to develop, high in chlorine capacity and long in service life is achieved.

Description

technical field [0001] The invention belongs to the technical field of dechlorination agents, and relates to a high-temperature dechlorination agent and a preparation method thereof, in particular to a novel high-temperature dechlorination agent and a preparation method thereof. Background technique [0002] During the catalytic reforming reaction, with the prolongation of the reaction time, the carbon area on the surface of the catalyst increases, and the platinum grains aggregate, resulting in a decrease in activity and requires regeneration to restore its activity. The continuous reforming unit is equipped with a continuous catalyst regeneration system, and the deactivated catalyst after the reaction can be regenerated in time to keep the catalyst highly active. During the operation of the catalytic reforming unit, the chlorine on the catalyst will gradually lose. In order to maintain a certain acidity of the catalyst, after the catalyst is regenerated and burnt, it must ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/68B01D53/81
CPCB01D53/68B01D53/81B01D2257/2025B01D2257/2045
Inventor 徐琦黄河苗树运夏小强
Owner 昆山市精细化工研究所有限公司
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