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Shrink film and preparation method thereof

A technology of shrink film and sub-outer layer, which is applied in the field of shrink film and its preparation, can solve the problems of poor flexibility and inability to use, and achieve the goal of improving interlayer adhesion, excellent stretchability, and maintaining high toughness Effect

Active Publication Date: 2022-01-07
SOUTH CHINA UNIV OF TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, in some special fields, such as beverages or other rolling objects for packaging, the toughness requirements for the shrink film are relatively high. At present, the common shrink film cannot meet the toughness requirements. The movement of the object causes the shrink film to be pulled and deformed or even torn, making it unusable
At the same time, the shrink film is usually a multi-layer structure, which is usually a three-layer body or a five-layer body. It is formed by co-extrusion blow molding, and its flexibility is not strong. Stratification appears due to the impact, thus affecting its use

Method used

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  • Shrink film and preparation method thereof

Examples

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preparation example Construction

[0017] The shrink film of the present invention can be prepared by the following method. The preparation method includes: mixing the raw materials of the outermost layer, the second outer layer, the middle layer, the second inner layer and the innermost layer according to the formula ratio, and sending them to the five layers respectively. The extruder of the co-extrusion blown film unit can be obtained by blowing film, cooling, pulling, and coiling.

[0018] The following will introduce the shrink film of the present invention in detail through specific examples, but the implementation scope of the present invention is not limited thereto.

Embodiment 1

[0020] The shrink film includes the outermost layer, the second outer layer, the middle layer, the second inner layer and the innermost layer in turn. The total thickness of the shrink film is 47um. The performance parameters of each layer are as follows:

[0021] Outermost layer: 10um thick, composed of 20% LDPE and 80% mLLDPE;

[0022] Second outer layer: 1.5um in thickness, composed of 70% EVOH, 28% EVA, 1% sodium bicarbonate and 1% metaboric acid;

[0023] Middle layer: 24um thick, composed of 60% HDPE, 30% LDPE and 10% MDPE.

[0024] Sub-inner layer: 1.5um thick, composed of 70% EVOH, 28% EVA, 1% sodium bicarbonate and 1% metaboric acid;

[0025] Innermost layer: 10um thick, composed of 20% LDPE and 80% mLLDPE;

[0026] The parameters of the various materials are:

[0027] LDPE: Density 0.920g / cm 3 , the melt index is 0.28g / 10min;

[0028] HDPE: Density 0.950g / cm 3 , the melt index is 0.20g / 10min;

[0029] MDPE: density is 0.940g / cm 3 , the melt index is 0.7g / 10min;...

Embodiment 2

[0033] The shrink film includes the outermost layer, the second outer layer, the middle layer, the second inner layer and the innermost layer in turn. The total thickness of the shrink film is 47um. The performance parameters of each layer are as follows:

[0034] Outermost layer: 10um thick, composed of 20% LLDPE and 80% mLLDPE;

[0035] Second outer layer: 1.5um in thickness, composed of 70% EVOH, 28% EVA, 1% sodium bicarbonate and 1% metaboric acid;

[0036] Middle layer: 24um thick, composed of 60% HDPE, 30% LDPE and 10% MDPE.

[0037] Sub-inner layer: 1.5um thick, composed of 70% EVOH, 28% EVA, 1% sodium bicarbonate and 1% metaboric acid;

[0038] Innermost layer: 10um thick, composed of 20% LDPE and 80% mLLDPE;

[0039] The parameters of the various materials are:

[0040] LDPE: Density 0.920g / cm 3 , the melt index is 0.28g / 10min;

[0041] HDPE: Density 0.950g / cm 3 , the melt index is 0.20g / 10min;

[0042] MDPE: density is 0.940g / cm 3 , the melt index is 0.7g / 10m...

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Abstract

The invention provides a shrink film and a preparation method thereof. The shrink film comprises an outermost layer, a secondary outer layer, a middle layer, a secondary inner layer and an innermost layer which are arranged in sequence, wherein the outermost layer and the innermost layer as well as the secondary outer layer and the secondary inner layer are symmetrically distributed by taking the middle layer as an axis, the thickness ratio of the outermost layer to the secondary outer layer to the middle layer to the secondary inner layer to the innermost layer is (1.5-2.5): (0.3-0.7): (3-6): (0.3-0.7): (1.5-2.5); in percentage by weight, the outermost layer and the innermost layer are composed of 10-30% of LDPE or LLDPE and 70-90% of mLLDPE; the middle layer is composed of 45-70% of HDPE, 20-40% of LDPE and 10-15% of MDPE; and the secondary outer layer and the secondary inner layer are composed of 67-80% of ethylene-vinyl alcohol copolymer, 17-30% of ethylene-vinyl acetate or ethylene-propylene copolymer and 0.5-3% of tackifying additive. On the basis of EVOH, and by combining flexible resin EVA or EPM, the secondary inner layer and the secondary outer layer are clamped between the outermost layer / the innermost layer and the middle layer to serve as a thin buffer layer; and the interlayer cohesiveness is improved through a tackifying additive, so that the influence of external force on the high-toughness outermost layer and the high-toughness outer inner layer can be effectively relieved, and the high toughness of the shrink film can be effectively maintained.

Description

technical field [0001] The invention relates to the technical field of multilayer structures, in particular to a film, and more particularly to a shrink film and a preparation method thereof. Background technique [0002] As an industrial film product, shrink film has high tensile strength, high elongation, good self-adhesiveness, and high transparency. centralized packaging. It is particularly important that the stretch film packaging makes the packaged items evenly stressed and avoids damage to the items caused by uneven force, which cannot be achieved by traditional packaging methods (bundling, packaging, tape, etc.). At the same time, the product is wrapped and packaged with the help of the retracting force of the stretched film to form a compact unit that does not take up space, so that the pallets of the product are tightly wrapped together, which can effectively prevent the mutual dislocation of the product during transportation. And moving, at the same time, the ad...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B27/32B32B27/08B32B27/30B32B27/18B29D7/01
CPCB32B27/32B32B27/08B32B27/306B32B27/18B29D7/01B32B2250/246B32B2270/00B32B2307/56B32B2307/5825
Inventor 林城黄思淇杨连坚
Owner SOUTH CHINA UNIV OF TECH