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Positive photoresist composition

A technology of positive photoresist and composition, which is applied in the field of photoresist, and can solve problems such as substrate edge collapse, poor peripheral circuit area loss, and circuit defects, etc.

Pending Publication Date: 2022-01-18
BEIJNG ASAHI ELECTRONICS MATERIAL CO LTD +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

As the size of the panel increases, in the production process, cutting and edging are inevitable. However, due to the problem of edge embrittlement, the edge of the substrate will collapse during edging, which will lead to the lack of peripheral circuit areas (that is, the peripheral circuit Collapsing defects during edging), forming circuit defects
The photoresist composition currently used in the market is generally not high in heat resistance, and the pattern (patten) morphology will change at high temperature, and when used in peripheral circuits, it may sometimes collapse during the edging process.

Method used

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  • Positive photoresist composition
  • Positive photoresist composition
  • Positive photoresist composition

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Take phenolic resin 15g, photosensitive compound 5g, crosslinking agent 5g, leveling agent 0.05g, adhesion promoter 0.09, solvent 74.86g, phenolic resin, photosensitive compound, crosslinking agent, leveling agent, adhesion promoter The agent is dissolved in a solvent to obtain a positive photoresist composition.

[0037] Phenolic resin, structural formula as shown in formula I, n 1 =170;

[0038] Photosensitive compound, the structural formula is shown in formula II, R 1 , R 2 , R 3 is a compound of structural formula III, R 4 is hydrogen;

[0039] Cross-linking agent, the structural formula is shown in formula VI;

[0040] Leveling agent, perfluorooctane sulfonyl fluoride;

[0041] Adhesion promoter, polymethyl vinyl ether;

[0042] Solvent, propylene glycol methyl ether acetate.

Embodiment 2-5

[0044] The phenolic resin, photosensitive compound, crosslinking agent, leveling agent, adhesion promoter, solvent, and preparation method are the same as those in Example 1, and the changes of relevant preparation parameters are shown in Table 1.

Embodiment 6

[0046] Phenolic resin, structural formula as shown in formula I, n 1 =85;

[0047] Photosensitive compound, the structural formula is shown in formula II, R 2 , R 3 , R 4 Is the compound of structural formula IV, R 1 is hydrogen;

[0048] Solvent: N-methylpyrrolidone;

[0049] The crosslinking agent, leveling agent, adhesion promoter, and preparation method are the same as in Example 1, and the changes of relevant preparation parameters are shown in Table 1.

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Abstract

The invention provides a positive photoresist composition which is prepared from the following components based on the total weight of the positive photoresist composition: 10-20 wt% of phenolic resin, 4-6 wt% of a photosensitive compound, 5-10 wt% of a cross-linking agent, 0.05-0.10 wt% of a flatting agent, 0.05-0.10 wt% of an adhesion promoter and 65-80 wt% of a solvent, wherein the phenolic resin is linear phenolic resin, the structural formula of the phenolic resin is shown as a formula I in the description, n1 is a natural number, and n1 is greater than or equal to 85 and less than or equal to 170. The positive photoresist composition provided by the invention has the characteristic of high heat resistance, the heat-resistant temperature can reach 230-250 DEG C, the positive photoresist composition can be used for a production process with a high-temperature process, and a good pattern morphology can be formed in an exposure process. Meanwhile, the positive photoresist composition has good uniformity, and when the positive photoresist composition is used for a peripheral circuit, the occurrence of disintegration during edge grinding can be effectively reduced.

Description

technical field [0001] The present application relates to the field of photoresist technology, in particular to a positive photoresist composition. Background technique [0002] Thin film transistor liquid crystal display (TFT-LCD) is a large-scale semiconductor full integrated circuit manufacturing technology using new materials and new processes, and is the basis of liquid crystal, inorganic and organic thin film electroluminescent flat panel displays. As the size of the panel increases, in the production process, cutting and edging are inevitable. However, due to the problem of edge embrittlement, the edge of the substrate will collapse during edging, which will lead to the lack of peripheral circuit areas (that is, the peripheral circuit Defective phenomenon of collapse during edging), forming circuit defects. The photoresist composition currently used in the market is generally not high in heat resistance, and the pattern (patten) morphology will change at high tempera...

Claims

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Application Information

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IPC IPC(8): G03F7/016G03F7/039
CPCG03F7/0163G03F7/0166G03F7/039
Inventor 何卿胡凡华朴大然卢克军张宁
Owner BEIJNG ASAHI ELECTRONICS MATERIAL CO LTD
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