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Ultrahigh molecular weight polyethylene fiber reinforced material and preparation method thereof

An ultra-high molecular weight, polyethylene fiber technology, applied in the field of materials, can solve the problems of lack of active chemical groups in ultra-high molecular weight polyethylene fibers, difficult to achieve interface mechanical properties, and poor interface bonding properties.

Active Publication Date: 2022-01-21
ANHUI HUAYE ADVANCED MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, the lack of active chemical groups on the surface of ultra-high molecular weight polyethylene fibers leads to poor interfacial bonding performance, and it is difficult to achieve the interfacial mechanical properties applied in working conditions.

Method used

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  • Ultrahigh molecular weight polyethylene fiber reinforced material and preparation method thereof
  • Ultrahigh molecular weight polyethylene fiber reinforced material and preparation method thereof
  • Ultrahigh molecular weight polyethylene fiber reinforced material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0055] A method for preparing an ultra-high molecular weight polyethylene fiber reinforced material, comprising dipping in three baths, using the first bath dipping solution, the second bath dipping solution and the third bath dipping solution for dipping treatment respectively;

[0056] The total mass concentration of the first bath dipping is 4%, and the pH value is 5;

[0057]The total mass concentration of the second bath dipping glue is 18%, and the pH value is 9;

[0058] The total mass concentration of the dipping in the third bath is 16%, and the pH value is 9.

[0059] First bath dipping comprises following mass parts raw material:

[0060]

[0061] The preparation method of the first bath dipping solution: according to parts by weight, first put 1000 parts of deionized water in the reaction kettle, add bis(triethanolamine) diisopropyl titanate, stir rapidly, and the stirring speed is 150 rpm / min, stirring for 10 minutes, then adding CrO 3 , Mn 2 o 7 , stirr...

Embodiment 2

[0083] A method for preparing an ultra-high molecular weight polyethylene fiber reinforced material, comprising dipping in three baths, using the first bath dipping solution, the second bath dipping solution and the third bath dipping solution for dipping treatment respectively;

[0084] The total mass concentration of the first bath dipping is 5.5%, and the pH value is 5;

[0085] The total mass concentration of the second bath dipping is 20%, and the pH value is 9.5;

[0086] The total mass concentration of the dipping in the third bath is 18%, and the pH value is 9.0.

[0087] First bath dipping comprises following mass parts raw material:

[0088]

[0089] The preparation method of the first bath dipping liquid: first put 1000 parts of deionized water in the reaction kettle, add bis(triethanolamine) diisopropyl titanate, stir rapidly, the stirring speed is 150 rpm, stir 10 minutes, followed by the addition of CrO 3 , Mn 2 o 7 , stirring continuously for 1 hour. Th...

Embodiment 3

[0107] A method for preparing an ultra-high molecular weight polyethylene fiber reinforced material, comprising dipping in three baths, using the first bath dipping solution, the second bath dipping solution and the third bath dipping solution for dipping treatment respectively;

[0108] The total mass concentration of the first bath dipping is 3%, and the pH value is 4;

[0109] The total mass concentration of the dipping glue in the second bath is 16%, and the pH value is 8.5;

[0110] The total mass concentration of the dipping in the third bath is 14%, and the pH value is 8.5.

[0111] First bath dipping comprises following mass parts raw material:

[0112]

[0113] The preparation method of the first bath dipping liquid: first put 1000 parts of deionized water in the reaction kettle, add bis(triethanolamine) diisopropyl titanate, stir rapidly, the stirring speed is 150 rpm, stir 10 minutes, followed by the addition of CrO 3 , Mn 2 o 7 , stirring continuously for 1...

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Abstract

The invention provides an ultra-high molecular weight polyethylene reinforced material and a preparation method thereof. The preparation method comprises the following steps of carrying out three-bath process impregnation, namely carrying out impregnation treatment by using a first-bath impregnation solution, a second-bath impregnation solution and a third-bath impregnation solution. Water-based epoxy resin, dimethyl pyrazole blocked isocyanate and an acidic metal oxidation catalyst are adopted as the first-bath impregnation solution, and a water-based mixture of zinc methacrylate or zinc acrylate and the like is adopted as the second-bath impregnation solution. The second-bath impregnation solution is a mixed solution of an aqueous solution of RF resin produced through condensation polymerization of resorcinol and furfural and one or more latexes in VPL, NRL, CRL and SBRL. According to ultra-high molecular weight polyethylene fibers treated by the method, the interface bonding performance of the fibers and rubber is enhanced after treatment.

Description

technical field [0001] The invention belongs to the field of materials, and in particular relates to an ultra-high molecular weight polyethylene fiber reinforced material and a preparation method thereof. Background technique [0002] The three high-performance fibers in the world today are: aramid fiber, carbon fiber, and ultra-high molecular weight polyethylene fiber. At present, aramid fiber is only produced in a small amount due to technical problems; carbon fiber is still in the stage of testing and primary production, and the product can only be used in wear-resistant Filling and other fields; ultra-high molecular weight polyethylene fiber has high specific strength and high specific modulus, and its specific strength is more than ten times that of steel wire with the same cross section. , including mooring ropes in offshore oil fields to high-performance lightweight composite materials, have shown great advantages, and play a pivotal role in modern warfare and aviatio...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M15/564D06M15/53D06M13/203D06M15/41D06M15/693C08J5/06C08L7/00C08L23/06D06M101/20
CPCD06M15/564D06M15/53D06M13/203D06M15/41D06M15/693C08J5/06D06M2101/20C08J2307/00C08J2423/06
Inventor 石杰张玉柱方祥
Owner ANHUI HUAYE ADVANCED MATERIALS CO LTD
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